The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation

scientific article (publication date: May 1976)

The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation is …
instance of (P31):
scholarly articleQ13442814

External links are
P356DOI10.1021/JA00426A033
P3181OpenCitations bibliographic resource ID5049422

P2093author name stringRobert E. Ireland
Alvin K. Willard
Richard H. Mueller
P433issue10
P407language of work or nameEnglishQ1860
P921main subjectstereoselectivityQ903429
P304page(s)2868-2877
P577publication date1976-05-01
P1433published inJournal of the American Chemical SocietyQ898902
P1476titleThe ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation
P478volume98

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cites work (P2860)
Q60672493A strategy for constructing C-sialosides based on Ireland-Claisen rearrangement and its application for synthesis of CF2-linked ganglioside GM4 analog
Q59439822A synthesis of the prelog-djerassi lactone using open-chain stereocontrol based on allylsilane chemistry
Q89602135A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group
Q77744211Alkylation of succinates: synthesis of Ro 32-3555
Q56288429An analysis of the diastereomeric transition state interactions for the kinetic deprotonation of acyclic carbonyl derivatives with lithium diisopropylamide
Q59739931Aromatic Claisen Rearrangements of Benzyl Ketene Acetals: Conversion of Benzylic Alcohols to (ortho-Tolyl)acetates
Q55968544Asymmetric Dihydroxylation of Alkenes
Q57958966Base or nucleophile? DFT finally elucidates the origin of the selectivity between the competitive reactions triggered by MeLi or LDA on propanal
Q57844372Binaphthol as a chiral auxiliary. Asymmetrical alkylation of arylacetic acid
Q59938840Chemical consequences of conformation in macrocyclic compounds
Q50164026Claisen rearrangements of benzyl vinyl ethers: theoretical investigation of mechanism, substituent effects, and regioselectivity.
Q57844365Complex-induced proximity effects in enolate formation. Highly diastereoselective α-methylation of binaphthyl esters of arylacetic acids
Q51757340Construction of the 1,2-dialkenylcyclohexane framework via Ireland-Claisen rearrangement and intramolecular Barbier reaction: application to the synthesis of (±)-Geijerone and a diastereoisomeric mixture with its 5-epimer.
Q26749672Contemporary Strategies for the Synthesis of Tetrahydropyran Derivatives: Application to Total Synthesis of Neopeltolide, a Marine Macrolide Natural Product
Q84769373Convergent Synthesis of TrisubstitutedZ-Allylic Esters by Wittig−Schlosser Reaction
Q48260031Copper Hydride Catalyzed Reductive Claisen Rearrangements.
Q54381513Directed hydrogenations and an ireland-claisen rearrangement linked to evans-tishchenko chemistry: the highly efficient total synthesis of the marine cyclodepsipeptide doliculide.
Q34019870Enantioselective synthesis of tatanans A-C and reinvestigation of their glucokinase-activating properties
Q53172445Formal Synthesis of Sarain A: Intramolecular Cycloaddition of an Eight-Membered Cyclic Nitrone to Construct the 2-Azabicyclo[3.3.1]nonane Framework.
Q56420967Hexamethylphosphoric Triamide
Q57973733High diastereoselectivity in lewis acid mediated aldol condensations using thioester silyl ketene acetals
Q31431867Highly stereoselective synthesis and biological properties of nucleoside analogues bearing a spiro inserted oxirane ring
Q34306364Intermolecular Michael Reactions: A Computational Investigation
Q58103725Investigation into the enantioselective protonation of enolate Schiff bases with (R)-pantolactone
Q47924886Investigation of quantitative structure-reactivity relationships in the aliphatic Claisen rearrangement of bis-vinyl ethers reveals a dipolar, dissociative mechanism
Q38188454Isolation, structural determination and synthetic approaches toward amphidinol 3.
Q56979078Lewis acid mediated aldol condensations using thioester silyl ketene acetals
Q56421053N,N,N′,N′-Tetramethylethylenediamine
Q56420943N,N′-Dimethylpropyleneurea
Q39168195Recent advances in the Overman rearrangement: synthesis of natural products and valuable compounds.
Q63386554Regiocontrolled nucleophilic additlon to the carbonyl and imino groups in the reaction of 2-arylamino-2-methoxy-1-phenylethanones with simple lithium ester enolates
Q56764571Regioselectivity in the iodolactonization of 1,6-heptadien-4-carboxylic acid derivatives
Q70380929Selective mono-Claisen rearrangement of carbohydrate glycals. A chemical consequence of the vinylogous anomeric effect
Q37112461Site-specific C-functionalization of free-(NH) peptides and glycine derivatives via direct C-H bond functionalization
Q40405679Stereochemical Studies of EnzymicC-Methylations
Q57844351Stereochemistry of the enolate from methyl phenylacetate
Q62581134Synthesis ofcis-Hedione® and Methyl Jasmonatevia CascadeBaylis-Hillman Reaction andClaisen Ortho Ester Rearrangement
Q57973491Synthetic studies on the sarcodictyins: synthesis of fully functionalized cyclization precursors
Q44685732The Ireland-Claisen rearrangement as a probe for the diastereoselectivity of nucleophilic attack on a double bond adjacent to a stereogenic centre carrying a silyl group
Q57482446The Orthoester Johnson-Claisen Rearrangement in the Synthesis of Bioactive Molecules, Natural Products, and Synthetic Intermediates - Recent Advances
Q56658596The ester enolate claisen rearrangement. Total synthesis of (±)-ethisolide
Q34546557Total synthesis of (±)-leuconolam: intramolecular allylic silane addition to a maleimide carbonyl group
Q34421372Total synthesis of jiadifenolide
Q61188644Total synthesis of the esterase inhibitor (±)-ebelactone a using an aldol-claisen strategy
Q64028630Tritylketone und Tritylenone. Beiträge zur sterisch erzwungenenMichael-Addition und zur diastereoselektiven Aldol-Addition
Q56698995t-Butyldimethylchlorosilane

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