Selective intermolecular amination of C-H bonds at tertiary carbon centers

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Selective intermolecular amination of C-H bonds at tertiary carbon centers is …
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scholarly articleQ13442814

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P356DOI10.1002/ANIE.201304238
P932PMC publication ID5483380
P698PubMed publication ID24000186

P50authorJennifer L. RoizenQ39051458
P2093author name stringJ Du Bois
David N Zalatan
P2860cites workDiastereotopos-Differentiation in the Rh-Catalyzed Amination of Benzylic Methylene Groups in the α-Position to a Stereogenic CenterQ64218202
Acyclic Stereocontrol in the Catalytic C−H Amination of Benzylic Methylene GroupsQ64218253
Structure-anti-Parkinson activity relationships in the aminoadamantanes. Influence of bridgehead substitutionQ64780315
Copper-nitrene complexes in catalytic C-H aminationQ82641043
Evidence for a one-electron mechanistic regime in dirhodium-catalyzed intermolecular C-H aminationQ83908744
Nitrene chemistry in organic synthesis: still in its infancy?Q84450966
Intermolecular C-H amination of complex molecules: insights into the factors governing the selectivityQ84793352
A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to OxazolidinonesQ88522085
Metal-catalyzed nitrogen-atom transfer methods for the oxidation of aliphatic C-H bondsQ33831365
A predictably selective aliphatic C-H oxidation reaction for complex molecule synthesisQ34708270
Capturing fleeting intermediates in a catalytic C-H amination reaction cycleQ36389521
Coinage metal catalyzed C-H bond functionalization of hydrocarbons.Q37242591
Catalytic carbene insertion into C-H bondsQ37604359
Catalytic C-H amination: recent progress and future directionsQ37744545
Understanding the differential performance of Rh2(esp)2 as a catalyst for C-H aminationQ39221084
Strain release in C-H bond activation?Q40832116
A chiral rhodium carboxamidate catalyst for enantioselective C-H aminationQ41142047
Studies in catalytic C-H amination involving nitrene C-H insertionQ42866100
[Fe(III)(F(20)-tpp)Cl] is an effective catalyst for nitrene transfer reactions and amination of saturated hydrocarbons with sulfonyl and aryl azides as nitrogen source under thermal and microwave-assisted conditionsQ42963101
Rh(II)-catalyzed intermolecular oxidative sulfamidation of aldehydes: a mild efficient synthesis of N-sulfonylcarboxamidesQ43860940
A diruthenium catalyst for selective, intramolecular allylic C-H amination: reaction development and mechanistic insight gained through experiment and theoryQ43971646
A unique and highly efficient method for catalytic olefin aziridinationQ44215921
Complex N-heterocycle synthesis via iron-catalyzed, direct C-H bond aminationQ45137871
Expanding the scope of C-H amination through catalyst designQ45162229
Catalytic intermolecular amination of C-H bonds: method development and mechanistic insightsQ46051033
N-tosyloxycarbamates as reagents in rhodium-catalyzed C-H amination reactionsQ46567520
Imido transfer from bis(imido)ruthenium(VI) porphyrins to hydrocarbons: effect of imido substituents, C-H bond dissociation energies, and Ru(VI/V) reduction potentialsQ46817681
Toward a synthetically useful stereoselective C-H amination of hydrocarbonsQ46855838
A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones We thank Professors Brauman, Stack, Trost, and Wender for many helpful discussions. C.G.E. is the recipient of an NSF Predoctoral Fellowship. J.D.B. gQ48370443
Highly regioselective amination of unactivated alkanes by hypervalent sulfonylimino-λ³-bromane.Q54183085
C–H Functionalization in organic synthesisQ60020969
P433issue43
P407language of work or nameEnglishQ1860
P304page(s)11343-11346
P577publication date2013-09-02
P1433published inAngewandte Chemie International EditionQ62023953
P1476titleSelective intermolecular amination of C-H bonds at tertiary carbon centers
P478volume52

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cites work (P2860)
Q42705936A unified photoredox-catalysis strategy for C(sp3)-H hydroxylation and amidation using hypervalent iodine
Q41009551Alkylation of Sulfonamides with Trichloroacetimidates under Thermal Conditions
Q39045158Analyzing site selectivity in Rh2(esp)2-catalyzed intermolecular C-H amination reactions
Q41852247Application of diazene-directed fragment assembly to the total synthesis and stereochemical assignment of (+)-desmethyl-meso-chimonanthine and related heterodimeric alkaloids
Q39350547Applications of Nonenzymatic Catalysts to the Alteration of Natural Products
Q59809029ChemInform Abstract: Selective Intermolecular Amination of C-H Bonds at Tertiary Carbon Centers
Q49466223Cobalt catalyzed sp3 C-H amination utilizing aryl azides
Q41991910Collective Approach to Advancing C-H Functionalization.
Q48147092Concise Synthesis of (-)-Hodgkinsine, (-)-Calycosidine, (-)-Hodgkinsine B, (-)-Quadrigemine C, and (-)-Psycholeine via Convergent and Directed Modular Assembly of Cyclotryptamines
Q41935986Convergent and Biomimetic Enantioselective Total Synthesis of (-)-Communesin F.
Q47875445Copper-Catalyzed Amination of Congested and Functionalized α-Bromocarboxamides with either Amines or Ammonia at Room Temperature.
Q48180171Iron-Catalyzed Intramolecular Aminations of C(sp3 )-H Bonds in Alkylaryl Azides.
Q92044333Ligand Redox Noninnocence in [CoIII(TAML)]0/- Complexes Affects Nitrene Formation
Q52715388Manganese-catalysed benzylic C(sp3)-H amination for late-stage functionalization.
Q43025057Mechanism and Dynamics of Intramolecular C-H Insertion Reactions of 1-Aza-2-azoniaallene Salts
Q35029999Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
Q52328497Organocatalytic nitrenoid transfer: metal-free selective intermolecular C(sp3)-H amination catalyzed by an iminium salt.
Q60024025Recent Applications of Rh- and Pd-Catalyzed C(sp3 )-H Functionalization in Natural Product Total Synthesis
Q46389659Rhodium-Catalyzed Stereospecific C-H Amination for the Construction of Spiroaminal Cores: Reactivity Difference between Nitrenoid and Carbenoid Species against Amide Functionality
Q51114800Ritter-type amination of C-H bonds at tertiary carbon centers using iodic acid as an oxidant.
Q51708898Ru(II)-catalyzed amidation reactions of 8-methylquinolines with azides via C(sp(3))-H activation.
Q48374886Sulfamate Esters Guide Selective Radical-Mediated Chlorination of Aliphatic C-H Bonds
Q48184302Transition metal-catalyzed iodine(iii)-mediated nitrene transfer reactions: efficient tools for challenging syntheses.
Q46558355Transition-Metal-Catalyzed Selective Functionalization of C(sp3)-H Bonds in Natural Products
Q26746442Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities

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