Stabilization of 3:1 site-differentiated cubane-type clusters in the [Fe(4)S(4)](1+) core oxidation state by tertiary phosphine ligation: synthesis, core structural diversity, and S = 1/2 ground states.

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Stabilization of 3:1 site-differentiated cubane-type clusters in the [Fe(4)S(4)](1+) core oxidation state by tertiary phosphine ligation: synthesis, core structural diversity, and S = 1/2 ground states. is …
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scholarly articleQ13442814

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P356DOI10.1021/IC101702B
P932PMC publication ID3057479
P698PubMed publication ID21038882

P50authorLiang DengQ52990326
P2093author name stringR H Holm
Wayne Lo
Amit Majumdar
P2860cites workSynthetic analogues of the active sites of iron-sulfur proteinsQ35660859
Stabilization of fully reduced iron-sulfur clusters by carbene ligation: the [FenSn]0 oxidation levels (n = 4, 8).Q41885670
Single- and double-cubane clusters in the multiple oxidation states [VFe(3)S(4)](3+,2+,1+).Q43919252
Synthesis and reactions of cubane-type iron-sulfur-phosphine clusters, including soluble clusters of nuclearities 8 and 16.Q44269785
Reactions of site-differentiated [Fe4S4]2+,1+ clusters with sulfonium cations: reactivity analogues of biotin synthase and other members of the S-adenosylmethionine enzyme familyQ44597855
Ground spin state variability in [Fe4S4(SR)4]3-. Synthetic analogs of the reduced clusters in ferredoxins and other iron-sulfur proteins: cases of extreme sensitivity of electronic state and structure to extrinsic factorsQ47746727
Synthetic analogs of the active sites of iron-sulfur proteins. VII. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2- and the structure of ((CH3)4N)2(Fe4S4(SC6H5)4).Q47836251
Cyclotriveratrylene models for [4Fe–4S] proteins: 3∶1 subsite differentiation and modulation of the redox potentialQ61646922
Subsite-Specific Reactions of a Cyclotriveratrylene [4Fe-4S] Cluster ComplexQ61646943
Novel Subsite-Differentiated [4Fe-4S] Clusters Based on CyclotriveratryleneQ61647039
The circumsphere as a tool to assess distortion in [4Fe-4S] atom clustersQ73114490
Synthesis and structures of bis(dithiolene)tungsten(IV,VI) thiolate and selenolate complexes: approaches to the active sites of molybdenum and tungsten formate dehydrogenasesQ80155419
P433issue23
P407language of work or nameEnglishQ1860
P304page(s)11118-11126
P577publication date2010-11-01
P1433published inInorganic ChemistryQ902828
P1476titleStabilization of 3:1 site-differentiated cubane-type clusters in the [Fe(4)S(4)](1+) core oxidation state by tertiary phosphine ligation: synthesis, core structural diversity, and S = 1/2 ground states
P478volume49

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cites work (P2860)
Q58099398A heterometallic (Fe6Na8) cage-like silsesquioxane: synthesis, structure, spin glass behavior and high catalytic activity
Q39075253Cubane-type Fe4S4 clusters with chiral thiolate ligation: formation by ligand substitution, detection of intermediates by 1H NMR, and solid state structures including spontaneous resolution upon crystallization
Q37696184Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters
Q54782602New biologically active hydrogen sulfide donors.
Q50707206Synthesis and characterization of potassium aryl- and alkyl-substituted silylchalcogenolate ligands.
Q50109354Synthesis and reactivity of thiolate-bridged multi-iron complexes supported by cyclic (alkyl)(amino)carbene.
Q35149741Synthetic analogues of [Fe4S4(Cys)3(His)] in hydrogenases and [Fe4S4(Cys)4] in HiPIP derived from all-ferric [Fe4S4{N(SiMe3)2}4].
Q35176941The [MoFe3S4]2+ oxidation state: synthesis, substitution reactions, and structures of phosphine-ligated cubane-type clusters with the S=2 ground state

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