Proton-coupled electron transfer of ruthenium(III)-pterin complexes: a mechanistic insight

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Proton-coupled electron transfer of ruthenium(III)-pterin complexes: a mechanistic insight is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1021/JA904386R
P932PMC publication ID3201791
P698PubMed publication ID19722655
P5875ResearchGate publication ID26782271

P50authorShunichi FukuzumiQ67623707
P2093author name stringJames M Mayer
Takahiko Kojima
Soushi Miyazaki
P2860cites workIron-only hydrogenase mimics. Thermodynamic aspects of the use of electrochemistry to evaluate catalytic efficiency for hydrogen generation.Q51109273
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Hydrogen atom abstraction by a mononuclear ferric hydroxide complex: insights into the reactivity of lipoxygenaseQ79909315
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Proton-coupled electron transferQ24597113
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Structures of tetrahydrobiopterin binding-site mutants of inducible nitric oxide synthase oxygenase dimer and implicated roles of Trp457Q27635495
High resolution crystal structures of the catalytic domain of human phenylalanine hydroxylase in its catalytically active Fe(II) form and binary complex with tetrahydrobiopterinQ27636351
Crystal structure of the ternary complex of the catalytic domain of human phenylalanine hydroxylase with tetrahydrobiopterin and 3-(2-thienyl)-L-alanine, and its implications for the mechanism of catalysis and substrate activationQ27639386
Structure of nitric oxide synthase oxygenase dimer with pterin and substrateQ27748968
Crystal structure of constitutive endothelial nitric oxide synthase: a paradigm for pterin function involving a novel metal centerQ27766420
Identification of the proton pathway in bacterial reaction centers: replacement of Asp-M17 and Asp-L210 with asn reduces the proton transfer rate in the presence of Cd2+.Q31514386
Proton-coupled electron transfer: a unifying mechanism for biological charge transport, amino acid radical initiation and propagation, and bond making/breaking reactions of water and oxygenQ33202052
Radical initiation in the class I ribonucleotide reductase: long-range proton-coupled electron transfer?Q35150156
Thermodynamics and kinetics of proton-coupled electron transfer: stepwise vs. concerted pathwaysQ35752083
Proton-coupled electron transfer: a reaction chemist's viewQ35760233
New frontiers in structural flavoenzymologyQ36637131
Concerted proton-electron transfer in the oxidation of hydrogen-bonded phenolsQ36841408
Large ground-state entropy changes for hydrogen atom transfer reactions of iron complexesQ37066966
Hydrogen atom transfer reactions of a ruthenium imidazole complex: hydrogen tunneling and the applicability of the Marcus cross relationQ37077988
Control of redox reactivity of flavin and pterin coenzymes by metal ion coordination and hydrogen bondingQ37083297
Trends in ground-state entropies for transition metal based hydrogen atom transfer reactionsQ37297520
Slow hydrogen atom transfer reactions of oxo- and hydroxo-vanadium compounds: the importance of intrinsic barriers.Q37326366
Predicting the activity of phenolic antioxidants: theoretical method, analysis of substituent effects, and application to major families of antioxidantsQ43677191
C-H bond activation by a ferric methoxide complex: modeling the rate-determining step in the mechanism of lipoxygenaseQ43780949
Application of the Marcus cross relation to hydrogen atom transfer reactionsQ43830313
Kinetics and mechanisms of the oxidation of phenols by a trans-dioxoruthenium(VI) complexQ44316425
A ruthenium pterin complex showing proton-coupled electron transfer: synthesis and characterizationQ44632657
Nonheme FeIVO complexes that can oxidize the C-H bonds of cyclohexane at room temperature.Q44726269
Hydrogen atom transfer from iron(II)-tris[2,2'-bi(tetrahydropyrimidine)] to TEMPO: a negative enthalpy of activation predicted by the Marcus equationQ44957445
Mechanistic insights from reactions between copper(II)-phenoxyl complexes and substrates with activated C-H bonds.Q46022239
Reaction of phenols with the 2,2-diphenyl-1-picrylhydrazyl radical. Kinetics and DFT calculations applied to determine ArO-H bond dissociation enthalpies and reaction mechanismQ46259016
Proton-coupled electron transfer in ruthenium(II)-pterin complexes: formation of ruthenium-coordinated pterin radicals and their electronic structuresQ46875449
Proton shift upon one-electron reduction in ruthenium(II)-coordinated pterinsQ47250326
Proton-coupled electron transfer in soybean lipoxygenaseQ47654421
P433issue32
P407language of work or nameEnglishQ1860
P921main subjectrutheniumQ1086
P304page(s)11615-11624
P577publication date2009-08-01
P1433published inJournal of the American Chemical SocietyQ898902
P1476titleProton-coupled electron transfer of ruthenium(III)-pterin complexes: a mechanistic insight
P478volume131

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cites work (P2860)
Q43492747A combined experimental and DFT/TDDFT investigation of structural, electronic, and pH-induced tuning of photophysical and redox properties of osmium(II) mixed-chelates derived from imidazole-4,5-dicarboxylic acid and 2,2'-bipyridine
Q43158574Bond-weakening catalysis: conjugate aminations enabled by the soft homolysis of strong N-H bonds.
Q46471979Characteristics and reactivity of ruthenium-oxo complexes
Q37138342Effects of Methyl Substitution in Ruthenium Tris(2-pyridylmethyl)amine Photocaging Groups for Nitriles
Q38010986Mechanisms of metal ion-coupled electron transfer.
Q58227399Mechanistic Insights into Photochromic Behavior of a Ruthenium(II)-Pterin Complex
Q42738967Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex
Q38940267Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities.
Q24597113Proton-coupled electron transfer
Q30426365Proton-coupled electron transfer at modified electrodes by multiple pathways.
Q34994479Pterin chemistry and its relationship to the molybdenum cofactor
Q38749805Reactivity of the copper(iii)-hydroxide unit with phenols
Q40734630Study of molybdenum(4+) quinoxalyldithiolenes as models for the noninnocent pyranopterin in the molybdenum cofactor
Q40968660pH-Induced processes in wire-like multichromophoric homo- and heterotrimetallic complexes of Fe(II), Ru(II), and Os(II).

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