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P50 | author | David Crich | Q74971587 |
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Automated solid-phase synthesis of protected oligosaccharides containing beta-mannosidic linkages | Q46695629 | ||
Unusual conformational behavior of trisaccharides containing N-acetylglucosamine | Q46768404 | ||
First synthesis of the beta-D-rhamnosylated trisaccharide repeating unit of the O-antigen from Xanthomonas campestris pv. campestris 8004. | Q46796162 | ||
Pre-activation protocol leading to highly stereoselectivity-controllable glycosylations of oxazolidinone protected glucosamines | Q46798217 | ||
NMR evidence for the participation of triflated ionic liquids in glycosylation reaction mechanisms | Q46985010 | ||
Stereoselective synthesis of oligo-alpha-(2,8)-sialic acids. | Q51190585 | ||
Endocyclic cleavage in glycosides with 2,3-trans cyclic protecting groups. | Q53260558 | ||
Unique reactions of glycosyl iodides with oxa- and thiocycloalkane acceptors. | Q53847137 | ||
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Practical Approach for the Stereoselective Introduction of β-Arabinofuranosides | Q57242482 | ||
Recent Advances inO-Sialylation | Q57242589 | ||
Ethyl 2-acetamido-4,6-di-O-benzyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-d-glycopyranoside as a versatile GlcNAc donor | Q62056622 | ||
Stereospecific Synthesis of 1,2-cisGlycosides by Vinyl-Mediated IAD | Q62233264 | ||
Synthesis of the Docosanasaccharide Arabinan Domain of Mycobacterial Arabinogalactan and a Proposed Octadecasaccharide Biosynthetic Precursor | Q63361050 | ||
Indirect cation-flow method: flash generation of alkoxycarbenium ions and studies on the stability of glycosyl cations. | Q64895858 | ||
Improved syntheses of aldosterone | Q67720024 | ||
Direct synthesis of the beta-l-rhamnopyranosides | Q73046796 | ||
Oxazolidinone Protection of N-Acetylglucosamine Confers High Reactivity on the 4-Hydroxy Group in Glycosylation | Q73252298 | ||
S-(4-methoxyphenyl) benzenethiosulfinate (MPBT)/trifluoromethanesulfonic anhydride: a convenient system for the generation of glycosyl triflates from thioglycosides | Q73287628 | ||
Ph2SO/Tf2O: a Powerful Promotor System in Chemoselective Glycosylations Using Thioglycosides | Q73313916 | ||
The 4,6-O-[alpha-(2-(2- iodophenyl)ethylthiocarbonyl)benzylidene] protecting group: stereoselective glycosylation, reductive radical fragmentation, and synthesis of beta-D-rhamnopyranosides and other deoxy sugars | Q73488218 | ||
Glycosylation of N-acetylglucosamine: imidate formation and unexpected conformation | Q73685611 | ||
Highly diastereoselective alpha-mannopyranosylation in the absence of participating protecting groups | Q73798991 | ||
Solvolyses of 2-Deoxy-alpha- and beta-D-Glucopyranosyl 4'-Bromoisoquinolinium Tetrafluoroborates | Q73983130 | ||
The Thioglycoside and Glycosyl Phosphite of 5-Azido Sialic Acid: Excellent Donors for the alpha-Glycosylation of Primary Hydroxy Groups This research was supported by Academia Sinica (Taipei) and the NIH (USA) | Q74357200 | ||
Stereoselective alpha-Sialylation with Sialyl Xanthate and Phenylsulfenyl Triflate as a Promotor | Q74822576 | ||
Substrate distortion by a beta-mannanase: snapshots of the Michaelis and covalent-intermediate complexes suggest a B(2,5) conformation for the transition state | Q27639558 | ||
Mechanistic insights into a Ca2+-dependent family of α-mannosidases in a human gut symbiont | Q27659017 | ||
Mechanistic studies on the stereoselective formation of beta-mannosides from mannosyl iodides using alpha-deuterium kinetic isotope effects | Q28211929 | ||
Is donor-acceptor hydrogen bonding necessary for 4,6-O-benzylidene-directed beta-mannopyranosylation? Stereoselective synthesis of beta-C-mannopyranosides and alpha-C-glucopyranosides | Q30437944 | ||
Studies on the stereoselective synthesis of C-allyl glycosides | Q30447007 | ||
Efficient, diastereoselective chemical synthesis of a beta-mannopyranosyl phosphoisoprenoid | Q31644422 | ||
A synthetic antithrombin III binding pentasaccharide is now a drug! What comes next? | Q33361287 | ||
Why are the hydroxy groups of partially protected N-acetylglucosamine derivatives such poor glycosyl acceptors, and what can be done about it? A comparative study of the reactivity of N-acetyl-, N-phthalimido-, and 2-azido-2-deoxy-glucosamine deriva | Q33423429 | ||
Chiral-auxiliary-mediated 1,2-cis-glycosylations for the solid-supported synthesis of a biologically important branched alpha-glucan | Q33613575 | ||
Correlations between nucleophilicities and selectivities in the substitutions of tetrahydropyran acetals | Q33683347 | ||
Erosion of stereochemical control with increasing nucleophilicity: O-glycosylation at the diffusion limit | Q33727064 | ||
Borinic acid-catalyzed regioselective acylation of carbohydrate derivatives. | Q34167167 | ||
Regioselective alkylation of carbohydrate derivatives catalyzed by a diarylborinic acid derivative | Q34185785 | ||
The 4-(tert-butyldiphenylsiloxy)-3-fluorobenzyl group: a new alcohol protecting group, fully orthogonal with the p-methoxybenzyl group and removable under desilylation conditions | Q35007946 | ||
Thioglycosides in sequential glycosylation strategies | Q36229467 | ||
The use of cyclic bifunctional protecting groups in oligosaccharide synthesis--an overview | Q36606411 | ||
Oversulfated chondroitin sulfate: impact of a heparin impurity, associated with adverse clinical events, on low-molecular-weight heparin preparation | Q37071056 | ||
The chemical neurobiology of carbohydrates | Q37152815 | ||
C-5 modifications in N-acetyl-neuraminic acid: scope and limitations | Q37153070 | ||
The effect of electrostatic interactions on conformational equilibria of multiply substituted tetrahydropyran oxocarbenium ions | Q37171066 | ||
Intramolecular aglycon delivery | Q37183226 | ||
Stereocontrolled synthesis of D- and L-beta-rhamnopyranosides with 4-O-6-S-alpha-cyanobenzylidene-protected 6-thiorhamnopyranosyl thioglycosides | Q37228308 | ||
Pre-activation-based one-pot synthesis of an alpha-(2,3)-sialylated core-fucosylated complex type bi-antennary N-glycan dodecasaccharide. | Q37322664 | ||
Formation of beta-Mannopyranosides of Primary Alcohols Using the Sulfoxide Method | Q74823657 | ||
Stereospecific Synthesis of beta-D-Fructofuranosides Using the Internal Aglycon Delivery Approach | Q74823667 | ||
Chemistry of 1-Alkoxy-1-glycosyl Radicals: Formation of beta-Mannopyranosides by Radical Decarboxylation and Decarbonylation of manno-Heptulosonic Acid Glycoside Derivatives | Q74823870 | ||
N-(phenylthio)-epsilon-caprolactam: a new promoter for the activation of thioglycosides | Q76384648 | ||
Chemistry of 4,6-O-Benzylidene-D-glycopyranosyl Triflates: Contrasting Behavior between the Gluco and Manno Series | Q77051361 | ||
Intramolecular o-glycoside bond formation | Q77366942 | ||
Capsular polysaccharide of Streptococcus pneumoniae type 19F: synthesis of the repeating unit | Q77589869 | ||
Efficient Sialylation with Phenyltrifluoroacetimidates as Leaving Groups | Q79136609 | ||
A highly reactive and stereoselective beta-mannopyranosylation system: mannosyl 4-pentenoate/PhSeOTf | Q79236350 | ||
Stereoselective synthesis of a fragment of mycobacterial arabinan | Q79361416 | ||
N-benzyl-2,3-oxazolidinone as a glycosyl donor for selective alpha-glycosylation and one-pot oligosaccharide synthesis involving 1,2-cis-glycosylation | Q80117208 | ||
Benzylidene acetal fragmentation route to 6-deoxy sugars: direct reductive cleavage in the presence of ether protecting groups, permitting the efficient, highly stereocontrolled synthesis of beta-D-rhamnosides from D-mannosyl glycosyl donors. Total | Q80259797 | ||
Efficient installation of beta-mannosides using a dehydrative coupling strategy | Q80375351 | ||
Acceptor-dependent stereoselective glycosylation: 2'-CB glycoside-mediated direct beta-D-arabinofuranosylation and efficient synthesis of the octaarabinofuranoside in mycobacterial cell wall | Q80375355 | ||
Synthesis and glycosylation of a series of 6-mono-, di-, and trifluoro S-phenyl 2,3,4-tri-O-benzyl-thiorhamnopyranosides. Effect of the fluorine substituents on glycosylation stereoselectivity | Q80857913 | ||
Approximate H(5) Ring Conformation of 2,3-O-Carbonate Protected α- and β-L-Rhamnopyranosides as Confirmed by X-Ray Crystallography | Q81306556 | ||
A new, powerful glycosylation method: activation of thioglycosides with dimethyl disulfide-triflic anhydride | Q81384253 | ||
Deoxy sugars: occurrence and synthesis | Q81430383 | ||
2-O-propargyl ethers: readily cleavable, minimally intrusive protecting groups for beta-mannosyl donors | Q81759107 | ||
Mechanism of chemical O-glycosylation: from early studies to recent discoveries | Q82593878 | ||
Convergent total synthesis of (+)-TMC-151C by a vinylogous Mukaiyama aldol reaction and ring-closing metathesis | Q83174779 | ||
Chemistry and glycobiology | Q83899971 | ||
Regioselective activation of glycosyl acceptors by a diarylborinic acid-derived catalyst | Q84754582 | ||
Theoretical Investigation of Solvent Effects on Glycosylation Reactions: Stereoselectivity Controlled by Preferential Conformations of the Intermediate Oxacarbenium-Counterion Complex | Q86825563 | ||
Synthesis of β-Mannosides via Prearranged Glycosides | Q88520201 | ||
A stereoselective approach for the synthesis of alpha-sialosides | Q43695809 | ||
2-(Hydroxycarbonyl)benzyl glycosides: a novel type of glycosyl donors for highly efficient beta-mannopyranosylation and oligosaccharide synthesis by latent-active glycosylation | Q43721921 | ||
1-Benzenesulfinyl piperidine/trifluoromethanesulfonic anhydride: a potent combination of shelf-stable reagents for the low-temperature conversion of thioglycosides to glycosyl triflates and for the formation of diverse glycosidic linkages | Q43734476 | ||
Stereoselective synthesis of beta-L-rhamnopyranosides. | Q43821242 | ||
Confirmation of the connectivity of 4,8,12,16,20-pentamethylpentacosylphoshoryl beta-D-mannopyranoside, an unusual beta-mannosyl phosphoisoprenoid from Mycobacterium avium, through synthesis | Q43905716 | ||
Stereoselective formation of glycosyl sulfoxides and their subsequent equilibration: ring inversion of an alpha-xylopyranosyl sulfoxide dependent on the configuration at sulfur. | Q44001802 | ||
Solid-phase synthesis of beta-mannosides | Q44076642 | ||
Stereoselective synthesis of beta-D-mannopyranosides with reactive mannopyranosyl donors possessing a neighboring electron-withdrawing group | Q44119877 | ||
Deoxygenation of carbohydrates by thiol-catalysed radical-chain redox rearrangement of the derived benzylidene acetals | Q44556917 | ||
The 3,4-O-Carbonate Protecting Group as a β-Directing Group in Rhamnopyranosylation in Both Homogeneous and Heterogeneous Glycosylations As Compared to the Chameleon-like 2,3-O-Carbonates | Q44629731 | ||
Nucleophilic Additions to Fused Bicyclic Five-Membered Ring Oxocarbenium Ions: Evidence for Preferential Attack on the Inside Face | Q44644757 | ||
Electrostatic interactions in cations and their importance in biology and chemistry | Q44964854 | ||
The disarming effect of the 4,6-acetal group on glycoside reactivity: torsional or electronic? | Q44998762 | ||
Mechanism of 4,6-O-benzylidene-directed beta-mannosylation as determined by alpha-deuterium kinetic isotope effects | Q45093014 | ||
One-pot synthesis of sialo-containing glycosyl amino acids by use of an N-trichloroethoxycarbonyl-beta-thiophenyl sialoside | Q45174424 | ||
Structural evidence that alkoxy substituents adopt electronically preferred pseudoaxial orientations in six-membered ring dioxocarbenium ions | Q45190411 | ||
6-O-Benzyl- and 6-O-silyl-N-acetyl-2-amino-2-N,3-O-carbonyl-2-deoxyglucosides: effective glycosyl acceptors in the glucosamine 4-OH Series. effect of anomeric stereochemistry on the removal of the oxazolidinone group | Q45260461 | ||
Stereodirecting effect of the pyranosyl C-5 substituent in glycosylation reactions. | Q45986286 | ||
Stereoselective Synthesis of alpha(2,9) Di- to Tetrasialic Acids, Using a 5,4-N,O-Carbonyl Protected Thiosialoside. | Q46026799 | ||
Efficient dehydrative sialylation of C-4-aminated sialyl-hemiketal donors with Ph2SO/Tf2O. | Q46157903 | ||
The two-conformer hypothesis: 2,3,4,6-tetra-O-methyl-mannopyranosyl and -glucopyranosyl oxacarbenium ions | Q46393568 | ||
Investigations of glycosylation reactions with 2-N-acetyl-2N,3O-oxazolidinone-protected glucosamine donors | Q46422465 | ||
Factors affecting stereocontrol during glycosidation of 2,3-oxazolidinone-protected 1-tolylthio-N-acetyl-D-glucosamine | Q46474104 | ||
Reagent switchable stereoselective beta(1,2) mannoside mannosylation: OH-2 of mannose is a privileged acceptor | Q46479195 | ||
Stereoselective direct glycosylation with anomeric hydroxy sugars by activation with phthalic anhydride and trifluoromethanesulfonic anhydride involving glycosyl phthalate intermediates | Q46557702 | ||
Sialylation reactions with 5-N,7-O-carbonyl-protected sialyl donors: unusual stereoselectivity with nitrile solvent assistance | Q46576245 | ||
Probing the mechanism of sulfoxide-catalyzed hemiacetal activation in dehydrative glycosylation | Q46599682 | ||
New principles for glycoside-bond formation | Q37378687 | ||
Opportunities and challenges in synthetic oligosaccharide and glycoconjugate research | Q37477221 | ||
Computational studies of the role of glycopyranosyl oxacarbenium ions in glycobiology and glycochemistry | Q37510057 | ||
Stereocontrolled synthesis of mannans and rhamnans | Q37510066 | ||
Recent advances in the synthesis of 2-deoxy-glycosides | Q37588901 | ||
The repertoire of glycan determinants in the human glycome | Q37597905 | ||
Glycosidase inhibition: assessing mimicry of the transition state | Q37672358 | ||
The impact of oxacarbenium ion conformers on the stereochemical outcome of glycosylations. | Q37719987 | ||
Uronic acids in oligosaccharide and glycoconjugate synthesis. | Q37827441 | ||
Effect of electron-withdrawing protecting groups at remote positions of donors on glycosylation stereochemistry | Q37828097 | ||
Influence of protecting groups on the reactivity and selectivity of glycosylation: chemistry of the 4,6-o-benzylidene protected mannopyranosyl donors and related species | Q37829376 | ||
Carbohydrate chemistry in drug discovery | Q37853437 | ||
Synthesis of the beta-rhamnopyranosides and the 6-deoxy-beta-mannoheptopyranosides. | Q37862182 | ||
The First Total Synthesis of 6-Sulfo-de-N-acetylsialyl Lewis(x) Ganglioside: A Superior Ligand for Human L-Selectin | Q38330011 | ||
Aiming for the ideal synthesis | Q39864855 | ||
Acid-Catalyzed Hydrolysis of Glycosides | Q39980009 | ||
Benzyne arylation of oxathiane glycosyl donors | Q40587864 | ||
Imposing the trans/gauche conformation on a sialic acid donor with a 5-N,7-O-oxazinanone group: effect on glycosylation stereoselectivity | Q41276894 | ||
A stable, commercially available sulfenyl chloride for the activation of thioglycosides in conjunction with silver trifluoromethanesulfonate | Q41276957 | ||
Stereocontrolled synthesis of the D- and L-glycero-beta-D-manno-heptopyranosides and their 6-deoxy analogues. Synthesis of methyl alpha-l-rhamno-pyranosyl-(1-->3)-D-glycero-beta-D-manno-heptopyranosyl- (1-->3)-6-deoxy-glycero-beta-D-manno-heptopyran | Q41774744 | ||
On the influence of the C2-O2 and C3-O3 bonds in 4,6-O-benzylidene-directed beta-mannopyranosylation and alpha-glucopyranosylation | Q41828063 | ||
Stereoselective synthesis of alpha-keto-deoxy-D-glycero-D-galacto-nonulosonic acid glycosides by means of the 4,5-O-carbonate protecting group | Q41842610 | ||
On the use of 3,5-O-benzylidene and 3,5-O-(di-tert-butylsilylene)-2-O-benzylarabinothiofuranosides and their sulfoxides as glycosyl donors for the synthesis of beta-arabinofuranosides: importance of the activation method | Q41846658 | ||
Dimethylthexylsilyl 2-acetamido-3-O-allyl-2-deoxy-6-O-(4-methoxybenzyl)-beta-D-glucopyranoside, dimethylthexylsilyl 3,4,6-tri-O-benzyl-beta-D-mannopyranosyl-(1-->4)-2-acetamido-3-O-allyl-2-deoxy-6-O-(4-methoxybenzyl)-beta-D-glucopyranoside, and dime | Q41905748 | ||
Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane | Q41985350 | ||
alpha-selective sialylations at -78 degrees C in nitrile solvents with a 1-adamantanyl thiosialoside | Q42033416 | ||
1-naphthylpropargyl ether group: a readily cleaved and sterically minimal protecting system for stereoselective glycosylation | Q42118221 | ||
Application of the 4-trifluoromethylbenzenepropargyl ether group as an unhindered, electron deficient protecting group for stereoselective glycosylation | Q42142589 | ||
Dehydrative sialylation with C2-hemiketal sialyl donors | Q42166017 | ||
Electrochemical generation of glycosyl triflate pools | Q42632594 | ||
Influence of the O3 protecting group on stereoselectivity in the preparation of C-mannopyranosides with 4,6-O-benzylidene protected donors | Q42704172 | ||
Synthesis of a beta-(1-->3)-D-rhamnotetraose by a one-pot, multiple radical fragmentation | Q42734123 | ||
Computational study of the influence of cyclic protecting groups in stereoselectivity of glycosylation reactions | Q42975958 | ||
Recent advances in stereoselective glycosylation through intramolecular aglycon delivery. | Q43002750 | ||
Mechanism of a chemical glycosylation reaction | Q43055773 | ||
Stereoselective iterative one-pot synthesis of N-glycolylneuraminic acid-containing oligosaccharides | Q43069778 | ||
Does neighboring group participation by non-vicinal esters play a role in glycosylation reactions? Effective probes for the detection of bridging intermediates | Q43145506 | ||
4,6-O-[1-cyano-2-(2-iodophenyl)ethylidene] acetals. improved second-generation acetals for the stereoselective formation of beta-D-mannopyranosides and regioselective reductive radical fragmentation to beta-D-rhamnopyranosides. scope and limitations | Q43149036 | ||
Enhanced diastereoselectivity in beta-mannopyranosylation through the use of sterically minimal propargyl ether protecting groups | Q43149052 | ||
Highly alpha-selective sialyl phosphate donors for efficient preparation of natural sialosides | Q43196732 | ||
4,6-O-benzylidene-directed beta-mannopyranosylation and alpha-glucopyranosylation: the 2-deoxy-2-fluoro and 3-deoxy-3-fluoro series of donors and the importance of the O2-C2-C3-O3 interaction | Q43203297 | ||
Direct stereocontrolled synthesis of 3-amino-3-deoxy-beta-mannopyranosides: importance of the nitrogen protecting group on stereoselectivity | Q43203304 | ||
O-sialylation with N-acetyl-5-n,4-o-carbonyl-protected thiosialoside donors in dichloromethane: facile and selective cleavage of the oxazolidinone ring | Q43210893 | ||
Beta-directing effect of electron-withdrawing groups at O-3, O-4, and O-6 positions and alpha-directing effect by remote participation of 3-O-acyl and 6-O-acetyl groups of donors in mannopyranosylations | Q43243599 | ||
Stereoselective glycosylation using oxathiane glycosyl donors | Q43269969 | ||
Synthesis of potassium (2R)-2-O-alpha-d-glucopyranosyl-(1-->6)-alpha-d-glucopyranosyl-2,3-dihydroxypropanoate a natural compatible solute | Q43289617 | ||
Equatorial anomeric triflates from mannuronic acid esters | Q43296529 | ||
Direct stereoselective synthesis of beta-thiomannosides | Q43503122 | ||
P433 | issue | 22 | |
P407 | language of work or name | English | Q1860 |
P304 | page(s) | 9193-9209 | |
P577 | publication date | 2011-10-04 | |
P1433 | published in | Journal of Organic Chemistry | Q898967 |
P1476 | title | Methodology development and physical organic chemistry: a powerful combination for the advancement of glycochemistry | |
P478 | volume | 76 |
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