Nickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon-boron bonds.

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Nickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon-boron bonds. is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1021/JA304068T
P932PMC publication ID3384763
P698PubMed publication ID22668072

P50authorAlexander S DudnikQ56501985
P2093author name stringGregory C Fu
P2860cites workAlkyl-alkyl suzuki cross-couplings of unactivated secondary alkyl halides at room temperatureQ24650794
Stereoconvergent amine-directed alkyl-alkyl Suzuki reactions of unactivated secondary alkyl chloridesQ33893047
Alkyl-alkyl Suzuki cross-coupling of unactivated secondary alkyl chloridesQ34775611
Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partnersQ34788016
Secondary alkyl halides in transition-metal-catalyzed cross-coupling reactions.Q34931084
Catalytic asymmetric γ-alkylation of carbonyl compounds via stereoconvergent Suzuki cross-couplingsQ35242174
Nickel-catalyzed enantioselective cross-couplings of racemic secondary electrophiles that bear an oxygen leaving groupQ35783298
New directing groups for metal-catalyzed asymmetric carbon-carbon bond-forming processes: stereoconvergent alkyl-alkyl Suzuki cross-couplings of unactivated electrophilesQ35905842
Nickel-catalysed Negishi cross-coupling reactions: scope and mechanismsQ37545422
BortezomibQ37674220
Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution ReactionsQ41917175
Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or ThioestersQ42017401
Density functional theory studies of negishi alkyl-alkyl cross-coupling reactions catalyzed by a methylterpyridyl-Ni(I) complexQ43649388
Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.Q46200288
Alkylboronic esters from copper-catalyzed borylation of primary and secondary alkyl halides and pseudohalides.Q50506698
Highly Enantioselective Synthesis of Tertiary Boronic Esters and their Stereospecific Conversion to other Functional Groups and Quaternary StereocentresQ57480759
Asymmetric Cross-Coupling of Non-Activated Secondary Alkyl HalidesQ57657428
Suzuki cross-couplings of unactivated secondary alkyl bromides and iodidesQ75399061
Ligand redox effects in the synthesis, electronic structure, and reactivity of an alkyl-alkyl cross-coupling catalystQ79180411
Cross-couplings of unactivated secondary alkyl halides: room-temperature nickel-catalyzed Negishi reactions of alkyl bromides and iodidesQ79326216
Ni-catalyzed cascade formation of C(sp3)--C(sp3) bonds by cyclization and cross-coupling reactions of iodoalkanes with alkyl zinc halidesQ81401160
Cross-coupling: The final frontierQ82640472
Amino alcohols as ligands for nickel-catalyzed suzuki reactions of unactivated alkyl halides, including secondary alkyl chlorides, with arylboronic acidsQ83166099
Copper(I)-catalyzed boryl substitution of unactivated alkyl halidesQ83283547
Synthesis of highly enantioenriched C-tertiary amines from boronic esters: application to the synthesis of igmesineQ83300517
Expanding the scope of transformations of organoboron species: carbon-carbon bond formation with retention of configurationQ84835913
Total synthesis of (+)-erogorgiaene using lithiation-borylation methodology, and stereoselective synthesis of each of its diastereoisomersQ84971212
The B-Alkyl Suzuki-Miyaura Cross-Coupling Reaction: Development, Mechanistic Study, and Applications in Natural Product Synthesis A list of abbreviations can be found at the end of the articleQ95391495
P433issue25
P407language of work or nameEnglishQ1860
P921main subjectboronQ618
nickelQ744
P304page(s)10693-10697
P577publication date2012-06-06
P1433published inJournal of the American Chemical SocietyQ898902
P1476titleNickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon-boron bonds
P478volume134

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cites work (P2860)
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