Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C-H activation

scientific article published on 23 September 2016

Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C-H activation is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1039/C6SC02587K
P932PMC publication ID5354047
P698PubMed publication ID28451239

P50authorRobert PatonQ19862676
Natthawat SemakulQ59549250
Tomislav RovisQ61052251
P2093author name stringKelvin E Jackson
P2860cites workRhodium(III)-catalyzed heterocycle synthesis using an internal oxidant: improved reactivity and mechanistic studiesQ83754838
Catalytic [2+2+1] cross-cyclotrimerization of silylacetylenes and two alkynyl esters to produce substituted silylfulvenesQ84953179
Rhodium(III)-catalyzed transannulation of cyclopropenes with N-phenoxyacetamides through C-H activationQ85651474
Asymmetric Copper-Catalyzed Carbozincation of Cyclopropenes en Route to the Formation of Diastereo- and Enantiomerically Enriched Polysubstituted CyclopropanesQ86837047
Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activationQ33645846
Catalytic enantioselective hydroboration of cyclopropenesQ34204594
Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C-H ActivationQ37179475
C-C, C-O and C-N bond formation via rhodium(III)-catalyzed oxidative C-H activation.Q37989310
Amide-directed tandem C-C/C-N bond formation through C-H activation.Q38001646
Rh(III)-catalyzed decarboxylative coupling of acrylic acids with unsaturated oxime esters: carboxylic acids serve as traceless activatorsQ38733110
Substrate activation strategies in rhodium(III)-catalyzed selective functionalization of arenesQ39021425
Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylic AcidQ41745955
Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of DihydroisoquinolonesQ41937966
Rh(III)-catalyzed cyclopropanation initiated by C-H activation: ligand development enables a diastereoselective [2 + 1] annulation of N-enoxyphthalimides and alkenesQ42054408
Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivityQ42321780
Enantioselective desymmetrization of cyclopropenes by hydroacylation.Q42845045
Rhodium(III)-Catalyzed C-H Activation Mediated Synthesis of Isoquinolones from Amides and CyclopropenesQ42957574
Rhodium(III)-catalyzed isoquinolone synthesis: the N-O bond as a handle for C-N bond formation and catalyst turnoverQ43078336
An Improved Catalyst Architecture for Rhodium (III) Catalyzed C-H Activation and its Application to Pyridone SynthesisQ43095444
Rhodium-catalysed syn-carboamination of alkenes via a transient directing groupQ43184824
Transition metal-catalyzed hydro-, sila-, and stannastannation of cyclopropenes: stereo- and regioselective approach toward multisubstituted cyclopropyl synthonsQ44150503
Computational Exploration of Rh(III)/Rh(V) and Rh(III)/Rh(I) Catalysis in Rhodium(III)-Catalyzed C-H Activation Reactions of N-Phenoxyacetamides with AlkynesQ46541108
Mechanistic Understanding of the Divergent Reactivity of Cyclopropenes in Rh(III)-Catalyzed C-H Activation/Cycloaddition Reactions of N-Phenoxyacetamide and N-PivaloxybenzamideQ46693924
Pyridine N-Oxide vs Pyridine Substrates for Rh(III)-Catalyzed Oxidative C-H Bond FunctionalizationQ46717498
Rh(V) -Nitrenoid as a Key Intermediate in Rh(III) -Catalyzed Heterocyclization by C-H Activation: A Computational Perspective on the Cycloaddition of Benzamide and Diazo CompoundsQ46727591
Enantioselective palladium(0)-catalyzed intramolecular cyclopropane functionalization: access to dihydroquinolones, dihydroisoquinolones and the BMS-791325 ring system.Q47137062
Rhodium(III)-catalyzed C-H activation/annulation with vinyl esters as an acetylene equivalent.Q52839005
Oxidative coupling of aromatic substrates with alkynes and alkenes under rhodium catalysis.Q53304057
Ligand-controlled regiodivergent pathways of rhodium(III)-catalyzed dihydroisoquinolone synthesis: experimental and computational studies of different cyclopentadienyl ligands.Q54035463
Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and VersatileQ57657367
Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C–H FunctionalizationQ59255939
Copper-Catalyzed Diastereo- and Enantioselective Desymmetrization of Cyclopropenes: Synthesis of CyclopropylboronatesQ61832438
Catalytic enantioselective hydrostannation of cyclopropenesQ79814213
Transition metal chemistry of cyclopropenes and cyclopropanesQ80592410
P433issue2
P921main subjectdiastereoselectivityQ64131393
P304page(s)1015-1020
P577publication date2016-09-23
P1433published inChemical ScienceQ2962267
P1476titleHeptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C-H activation
P478volume8

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cites work (P2860)
Q39035958Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study
Q48309011Directed RhI -Catalyzed Asymmetric Hydroboration of Prochiral 1-Arylcycloprop-2-Ene-1-Carboxylic Acid Derivatives.
Q48357839Efficient Synthesis of Arylated Furans by a Sequential Rh-Catalyzed Arylation and Cycloisomerization of Cyclopropenes
Q57656867Effiziente Synthese von arylierten Furanen durch sequentielle Rhodium-katalysierte Arylierung und Cycloisomerisierung von Cyclopropenen
Q48217953Fulvene Synthesis by Rhodium(I)-Catalyzed [2+2+1] Cycloaddition: Synthesis and Catalytic Activity of Tunable Cyclopentadienyl Rhodium(III) Complexes with Pendant Amides
Q48348732Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to γ- or δ-Lactams.
Q57404706Rhodium(III)-Catalyzed Annulation ofN-Methoxybenzamides with Heterobicyclic Alkenes by C-H Functionalization: Synthesis of Benzo[b]phenanthridinones
Q89941005Synthesis of bicyclo[3.1.0]hexanes by (3 + 2) annulation of cyclopropenes with aminocyclopropanes

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