Stable cyclic carbenes and related species beyond diaminocarbenes

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Stable cyclic carbenes and related species beyond diaminocarbenes is …
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scholarly articleQ13442814

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P356DOI10.1002/ANIE.201000165
P932PMC publication ID3130005
P698PubMed publication ID20836099
P5875ResearchGate publication ID46221608

P50authorGuy BertrandQ5622094
Mohand MelaimiQ57557142
P2093author name stringMichèle Soleilhavoup
P2860cites workStable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic propertiesQ24650145
Recently reported crystalline isothiazole carbenes: myth or realityQ28238336
Catalytic Markovnikov and anti-Markovnikov functionalization of alkenes and alkynes: recent developments and trendsQ28268927
When and how do diaminocarbenes dimerize?Q28285455
Bis(diethylamino)carbene and the mechanism of dimerisation for simple diaminocarbenesQ28286429
New C-N and C-C bond forming reactions catalyzed by titanium complexesQ28299817
Gold-Catalyzed Organic TransformationsQ28314798
(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator SubstituentQ29039551
Palladium-Catalyzed α-Arylation of Carbonyl Compounds and NitrilesQ29040444
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the LaboratoryQ29999739
A Stable Thiazol-2-ylidene and Its DimerQ30051547
Synthesis and activity of a new generation of ruthenium-based olefin metathesis catalysts coordinated with 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ligandsQ30596579
Evidence for specific solvation of two halocarbene amidesQ31057273
Diaminocarbene- and Fischer-carbene complexes of palladium and nickel by oxidative insertion: preparation, structure, and catalytic activityQ31144230
Efficient C-F and C-C activation by a novel N-heterocyclic carbene-nickel(0) complexQ33433593
The development of L2X2Ru=CHR olefin metathesis catalysts: an organometallic success storyQ33932697
Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes.Q34298039
Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the differenceQ34439078
13C NMR spectroscopy of "Arduengo-type" carbenes and their derivativesQ34961600
Ruthenium-based olefin metathesis catalysts bearing N-heterocyclic carbene ligandsQ34987375
Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbeneQ35012021
Stable four-pi-electron, four-membered heterocyclic cations and carbenesQ35025122
Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenesQ35962898
Asymmetric transfer hydrogenation: chiral ligands and applicationsQ36408490
Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions.Q36408494
Tuning the nucleophilicity in cyclopropenylidenesQ36692938
Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspectiveQ36780905
Synthesis of substituted 1,2-dihydroquinolines and quinolines from aromatic amines and alkynes by gold(I)-catalyzed tandem hydroamination-hydroarylation under microwave-assisted conditionsQ80468643
Intramolecular C-N bond addition of amides to alkynes using platinum catalystQ80487750
Tuning the electronic properties of N-heterocyclic carbenesQ80527311
A singlet aryl-CF3 carbene: 2-benzothienyl(trifluoromethyl)carbene and interconversion with a strained cyclic alleneQ80610452
Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phosQ80660428
One-step assembly of a chiral palladium bis(acyclic diaminocarbene) complex and its unexpected oxidation to a bis(amidine) complexQ80716180
Divalent carbon(0) chemistry, part 2: Protonation and complexes with main group and transition metal Lewis acidsQ80814854
A general method for the direct alpha-arylation of aldehydes with aryl bromides and chloridesQ80849404
A stable chiral diaminocyclopropenylideneQ80867049
C6H4 valence bond isomers: a reactive bicyclopropenylideneQ80888332
Coordination chemistry of ene-1,1-diamines and a prototype "carbodicarbene"Q80891354
Gold catalysis: mild conditions for the synthesis of oxazoles from N-propargylcarboxamides and mechanistic aspectsQ80956583
Bis-phosphorus stabilised carbene complexesQ80998991
An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated "phosphaamidinate" anionQ81005385
Molecular electrostatic potentials of divalent carbon(0) compoundsQ81091083
Recent developments in enantioselective gold(I) catalysisQ81167230
Crystal structure of a silyl cation with no coordination to anion and distant coordination to solventQ81199482
Geometry and aromaticity in highly strained heterocyclic allenes: characterization of a 2,3-didehydro-2H-thiopyranQ81248823
Effective modulation of the donor properties of N-heterocyclic carbene ligands by "through-space" communication within a planar chiral scaffoldQ81384236
Discovering chemical terra incognita: unusual metallacycles and their reactionsQ81396593
A stable P-heterocyclic carbeneQ81403758
C(NHC)2: divalent carbon(0) compounds with N-heterocyclic carbene ligands-theoretical evidence for a class of molecules with promising chemical propertiesQ81412612
First and second proton affinities of carbon basesQ81479484
Heterolytic dihydrogen activation by a frustrated carbene-borane Lewis pairQ81717466
Abnormal coordination of Arduengo's carbene upon reaction with M(3)(CO)(12) (M = Ru, Os)Q81747582
Synthesis and ligand properties of a stable five-membered-ring vinylidenephosphoraneQ81786937
Carbenes stabilized by ylides: pushing the limitsQ82055090
Gold(III) porphyrin-catalyzed cycloisomerization of allenonesQ82246289
Acyclic diaminocarbenes: simple, versatile ligands for cross-coupling reactionsQ82423014
Cyclic carbodiphosphoranes: strongly nucleophilic sigma-donor ligandsQ82812786
Synthesis and structural characterization of stable organogold(I) compounds. Evidence for the mechanism of gold-catalyzed cyclizationsQ82832519
A novel ylide-stabilized carbene; formation and electron donating ability of an amino(sulfur-ylide)carbeneQ82965176
Gold-catalyzed intermolecular hydroamination of allenes with arylamines and resulting high chirality transferQ83163803
Computational study of carbon atom (3P and 1D) reaction with CH2O. Theoretical evaluation of 1B1 methylene production by C (1D)Q83275038
A carbocyclic carbene as an efficient catalyst ligand for C-C coupling reactionsQ83278432
Elementary steps of gold catalysis: NMR spectroscopy reveals the highly cationic character of a "gold carbenoid"Q83398915
Chemical bonding: Rethinking carbonQ83542689
Coinage metal-N-heterocyclic carbene complexesQ83636523
Stable noncyclic singlet carbenesQ83654369
Carbocyclic carbene metal complexesQ83850146
In situ generation of novel acyclic diaminocarbene-copper complexQ84076610
Do extremely bent allenes exist?Q84118789
A new route to acyclic diaminocarbenes via lithium-halogen exchangeQ84195007
On the electronic impact of abnormal C4-bonding in N-heterocyclic carbene complexesQ84349957
Divalent E(0) compounds (E = Si-Sn)Q84349971
N-heterocyclic carbenes: a new concept in organometallic catalysisQ84553836
Air-stable secondary phosphine oxide as preligand for palladium-catalyzed intramolecular alpha-arylations with chloroarenesQ84581695
A Neutral Three-Coordinate Alkylrhodium(I) Complex: Stabilization of a 14-Electron Species by gamma-C-H Agostic Interactions with a Saturated Hydrocarbon Group This work was supported by the Deutsche Forschungsgemeinschaft (SFB 247, Graduate CollegeQ95349068
A Homoleptic Carbene--Lithium Complex Homoleptic carbene complexes part 10. This work was supported by the Fonds der Chemischen Industrie, the Deutsche Forschungsgemeinschaft, and by the Studienstiftung des Deutschen Volkes. Part 9 ref. 14Q95350916
Catalytic C-C Bond Formation through Selective Activation of C-F Bonds N-Heterocyclic Carbenes, Part 30. This work was supported by the Deutsche Forschungsgemeinschaft (DFG), the Bayerischer Forschungsverbund Katalyse (FORKAT), and the Fonds der CheQ95352805
Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bondsQ95431960
Phosphinocarbene-phosphaalkene rearrangement and intramolecular Wittig-like reaction involving a phosphorus vinyl ylideQ95440245
Structure and reactivity of "unusual" N-heterocyclic carbene (NHC) palladium complexes synthesized from imidazolium saltsQ95816651
Basicity of nucleophilic carbenes in aqueous and nonaqueous solvents-theoretical predictions.Q44975947
Unusual reactivity of a nickel N-heterocyclic carbene complex: tert-butyl group cleavage and silicone grease activationQ45137640
Imidazo[1,5-a]pyridine: a versatile architecture for stable N-heterocyclic carbenesQ45310087
Exocyclic delocalization at the expense of aromaticity in 3,5-bis(pi-donor) substituted pyrazolium ions and corresponding cyclic bent allenes.Q45915048
Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center.Q46007374
Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts.Q46011334
Organocatalytic ring-opening polymerization.Q46030541
Theoretical analysis of bonding in N-heterocyclic carbene-rhodium complexes.Q46033471
A stable four-membered N-heterocyclic carbeneQ46045759
Carbene activation of P4 and subsequent derivatizationQ46097010
Divalent silicon(0) compoundsQ46116061
Ion pairing in cationic olefin-gold(I) complexesQ46120819
Beyond conventional N-heterocyclic carbenes: abnormal, remote, and other classes of NHC ligands with reduced heteroatom stabilizationQ46162157
Stable five-membered-ring allenes with second-row elements only: not allenes, but zwitterionsQ46175260
Isolation of bicyclopropenylidenes: derivatives of the smallest member of the fulvalene familyQ46203529
[IrCl(2)Cp*(NHC)] complexes as highly versatile efficient catalysts for the cross-coupling of alcohols and aminesQ46236579
Palladation of diimidazolium salts at the C4 position: access to remarkably electron-rich palladium(II) centersQ46263985
The existence of two short-bond isomers for bicyclo[1.1.0]butane derivatives based on boron and phosphorusQ46283808
Singlet diradicals: from transition states to crystalline compoundsQ46294786
Synthesis and ligand properties of a persistent, all-carbon four-membered-ring alleneQ46323371
Mechanism and activity of ruthenium olefin metathesis catalystsQ46357398
Catalytic synthesis of tricyclic quinoline derivatives from the regioselective hydroamination and C-H bond activation reaction of benzocyclic amines and alkynesQ46444968
Topological and orbital-based mechanisms of the electronic stabilization of bis(diisopropylamino)cyclopropenylideneQ46476569
Diaminocarbene and phosphonium ylide ligands: a systematic comparison of their donor character.Q46557694
NHC-mediated aggregation of P4: isolation of a P12 clusterQ46636269
Sigma-bond stretching: a static approach for a dynamic processQ46646113
A highly efficient and selective Au(I)-catalyzed tandem synthesis of diversely substituted pyrrolo[1,2-a]quinolines in aqueous media.Q46655214
Divalent carbon(0) chemistry, part 1: Parent compounds.Q46720192
Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligandQ46724794
Five-membered metallacyclic allenoids: synthesis and structure of remarkably stable strongly distorted cyclic allene derivativesQ46732318
Evidence for the coexistence of two bond-stretch isomers in solutionQ46781586
Reactions and applications of titanium imido complexesQ46802072
An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2.Q46803423
Roots: from carbenes to allenes and coordination polymers. Ever present never twice the sameQ46839786
Bonding analysis of N-heterocyclic carbene tautomers and phosphine ligands in transition-metal complexes: a theoretical studyQ46948581
Mechanism of the electronic stabilization of the 3MR and divalent carbon of bis(diisopropylamino)cyclopropenylideneQ46955621
Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elementsQ46988689
Cyclopropenylidene carbene ligands in palladium C-C coupling catalysis.Q50675447
Strain estimates for small-ring cyclic allenes and butatrienes.Q51937747
Alkene metathesis: the search for better catalysts.Q53188603
N-Heterocyclic carbenes/imidazolium salts as substrates in catalysis: the catalytic 2-substitution and annulation of heterocyclic compounds.Q53518736
Asymmetric lithium(I) and copper(II) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysis.Q53637106
A cyclic carbanionic valence isomer of a carbocation: diphosphino analogs of diaminocarbocationsQ53907401
F-Block N-Heterocyclic Carbene ComplexesQ54000792
Anionic Amido N-Heterocyclic Carbenes: Synthesis of Covalently Tethered Lanthanide–Carbene ComplexesQ54000951
Pyrazolidine-3,5-diones and 5-hydroxy-1H-pyrazol-3(2H)-ones, inhibitors of UDP-N-acetylenolpyruvyl glucosamine reductase.Q54454869
Cyclic carbodiphosphorane-diphosphinocarbene thermal interconversion.Q54489476
Divalent carbon(0) compoundsQ55882585
Aromaticity of Phosphorus HeterocyclesQ56456210
N-Heterocyclic Carbenes as OrganocatalystsQ56456827
Catalytic carbophilic activation: catalysis by platinum and gold pi acidsQ36788319
Chemical routes for the transformation of biomass into chemicalsQ36834278
The catalytic hydroamination of alkynesQ36895255
Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: a dramatic effect of counteranions on reaction efficiencyQ36897861
Organocatalysis by N-heterocyclic carbenesQ36979264
Scope and mechanistic study of the ruthenium-catalyzed ortho-C-H bond activation and cyclization reactions of arylamines with terminal alkynesQ36980300
Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.Q36994183
Anionic tethered N-heterocyclic carbene chemistryQ37063206
Heterocyclic carbenes: synthesis and coordination chemistry.Q37132936
Coinage metal-assisted synthesis of heterocycles.Q37210466
Alternative synthetic methods through new developments in catalysis by goldQ37225654
Ligand effects in homogeneous Au catalysisQ37225816
Development of palladium-carbene catalysts for telomerization and dimerization of 1,3-dienes: from basic research to industrial applicationsQ37235222
N-Heterocyclic carbene complexes of rhodium: structure, stability and reactivityQ37238352
Hydroamination: direct addition of amines to alkenes and alkynes.Q37252984
Broader, greener, and more efficient: recent advances in asymmetric transfer hydrogenation.Q37254438
Well-defined N-heterocyclic carbenes-palladium(II) precatalysts for cross-coupling reactionsQ37262095
Selective monoarylation of acetate esters and aryl methyl ketones using aryl chloridesQ37355521
An improved protocol for the Pd-catalyzed alpha-arylation of aldehydes with aryl halides.Q37357310
The medicinal applications of imidazolium carbene-metal complexesQ37542176
Ruthenium Vinyl Carbene Intermediates in Enyne MetathesisQ37546885
Metathesis in the synthesis of aromatic compounds.Q37556506
Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexesQ37558266
Metal-NHC complexes: a survey of anti-cancer properties.Q37744648
Fused polycyclic nucleophilic carbenes - synthesis, structure, and functionQ37744650
Alkene oligomerisation and polymerisation with metal-NHC based catalystsQ37744654
Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation.Q38607086
Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal ComplexesQ38739368
Synthesis of phosphaformamidines and phosphaformamidinatesQ38739419
Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenesQ38789356
A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexesQ39141061
Stable P-heterocyclic carbenes: scope and limitations.Q39141112
Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)CarbenesQ39598786
Carbodiphosphoranes: The Chemistry of Divalent Carbon(0)Q56610296
Stable Versions of Transient Push-Pull Carbenes: Extending Lifetimes from Nanoseconds to WeeksQ56637188
N-Heterocyclic Carbenes in Late Transition Metal CatalysisQ56637209
Development of catalysts for the hydroamination of olefinsQ56639238
Organolanthanide-Catalyzed HydroaminationQ56639247
Abnormal Carbenes as Ligands in Transition Metal Chemistry: Curiosities with Exciting PerspectivesQ57503034
Carbenes in ActionQ57503039
C4-bound imidazolylidenes: from curiosities to high-impact carbene ligandsQ57503059
Neutral Ligands with Exceptional Donor Ability for Palladium-Catalyzed Alkene HydrogenationQ57503080
Surveying Sterically Demanding N-Heterocyclic Carbene Ligands with Restricted Flexibility for Palladium-catalyzed Cross-Coupling ReactionsQ57657436
Sterically Demanding, Bioxazoline-Derived N-Heterocyclic Carbene Ligands with Restricted Flexibility for CatalysisQ57657465
An N-Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross-Coupling of Sterically Hindered Aryl Chlorides at Room TemperatureQ57657467
Efficient Synthesis of 3-Aminocyclobut-2-en-1-ones:  Squaramide Surrogates as Potent VLA-4 AntagonistsQ58858596
A Diaminocarbene-Phosphonium Ylide: Direct Access to C,C Chelating LigandsQ59359065
Equilibrium Ring-Closing MetathesisQ59579147
A Simple Catalyst for the Efficient Benzylation of Arenes by Using Alcohols, Ethers, Styrenes, Aldehydes, or KetonesQ59733873
Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic ApplicationsQ59733886
Copper, Silver, and Gold Complexes in Hydrosilylation ReactionsQ60491180
Stable, Three-Coordinate Ni(CO)2(NHC) (NHC =N-Heterocyclic Carbene) Complexes Enabling the Determination of Ni−NHC Bond EnergiesQ60491577
Golden opportunities in catalysisQ62032115
Grubbs’ Ruthenium-Carbenes Beyond the Metathesis Reaction: Less Conventional Non-Metathetic UtilityQ63386234
Synthesis of new pyrazolones as potent anti-inflammatory agentsQ67443301
N-Acylation during the addition of carboxylic acids to N-tert-butylacylketenimines and the use of the reagent N-tert-butyl-5-methylisoxazolium perchlorate for peptide synthesisQ69656288
The "Wanzlick Equilibrium" V.P.W.B. wishes to thank the Fonds der Chemischen Industrie for a Kekulé fellowshipQ73228219
Evidence for an Equilibrium between an N-heterocyclic Carbene and Its Dimer in SolutionQ73441233
1,2,4,6-Cycloheptatetraene: Room-Temperature Stabilization inside a Hemicarcerand This work was supported by the Petroleum Research Fund administered by the American Chemical Society, by Kansas State University, and by KSU Center for Basic Cancer ReQ73666867
Synthesis of an Isolable Diphosphaisobenzene and a Stable Cyclic Allene with Six Ring Atoms Phosphorus Compounds, Part 147. This work was supported by the Fonds der Chemischen Industrie and the Deutsche Forschungsgemeinschaft (Graduate College "PhosQ73681043
Au(I)-catalyzed highly efficient intermolecular hydroamination of alkynesQ73872569
Stable (amino)(phosphino)carbenes: difunctional moleculesQ74275258
An unprecedented dinuclear alkylrhodium(III) complex built up by two 14-electron [RhCl2(alkyl)(PR3)] unitsQ74602930
Stable non-push-pull phosphanylcarbenes: NMR spectroscopic characterization of a methylcarbeneQ74689560
The first asymmetric cyclopropanation reactions involving a stable carbeneQ77230539
Stable CarbenesQ77366524
Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidinesQ78007618
Experimental investigation on the formation of carbon-bearing molecules in the interstellar medium via neutral-neutral reactionsQ78066203
Stable (aryl)(phosphino)carbenes: new ligands for transition metalsQ78310701
Quinone-annulated N-heterocyclic carbene-transition-metal complexes: observation of pi-backbonding using FT-IR spectroscopy and cyclic voltammetryQ79440393
Triplet 1,3-diphenylpropynylidene (Ph-C-C-C-Ph)Q79722773
Gold(III)-catalyzed double hydroamination of o-alkynylaniline with terminal alkynes leading to N-vinylindolesQ79739849
CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap.Q39602520
Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium saltsQ39602894
Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynesQ40593384
Abnormal ligand binding and reversible ring hydrogenation in the reaction of imidazolium salts with IrH(5)(PPh(3))(2).Q40637538
A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic ActivityQ41319875
A New Synthetic Method for the Preparation of Protonated-NHCs and Related CompoundsQ41320057
A persistent P,N-heterocyclic carbene.Q41484581
A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amineQ41878759
Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs).Q42157859
Homogeneous catalytic hydroamination of alkynes and allenes with ammoniaQ42426687
Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary aminesQ42548092
Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivativesQ43057503
Atropochiral (C,C)-chelating NHC-ylide ligands: synthesis and resolution of palladium(II) complexes thereof.Q43070917
N-heterocyclic carbenes bearing two, one and no nitrogen atoms at the ylidene carbon: insight from theoretical calculationsQ43070982
Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs).Q43081191
Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagentQ43130843
Cyclic (amino)[bis(ylide)]carbene as an anionic bidentate ligand for transition-metal complexesQ43213810
Palladium complexes of abnormal N-heterocyclic carbenes as precatalysts for the much preferred Cu-free and amine-free Sonogashira coupling in air in a mixed-aqueous mediumQ43214184
Syntheses and X-ray crystal structures of cationic, two-coordinate gold(I) pi-alkene complexes that contain a sterically hindered o-biphenylphosphine ligandQ43258505
Synchrotron photoionization measurements of combustion intermediates: photoionization efficiency and identification of C3H2 isomersQ43269304
Synthesis and structural characterisation of stable cationic gold(I) alkene complexes.Q43296977
Chemistry and properties of cycloheptatetraene in the inner phase of a hemicarcerandQ43588293
Synthesis and rearrangement of diphosphorus analogues of amidinium saltsQ43915533
Structural Investigations into the retro-Diels-Alder Reaction. Experimental and Theoretical Studies.Q43975081
Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complexQ44143692
Coordination chemistry at carbonQ44265814
A methylene-bis-triazolium ligand precursor in an unusual rearrangement of norbornadiene to nortricyclylQ44314118
Yttrium alkyl complexes with a sterically demanding benzamidinate ligand: synthesis, structure and catalytic ethene polymerisationQ44363216
Cyclopropenylium cations, cyclopropenones, and heteroanalogues-recent advancesQ44395626
Synthesis of carbenes through substitution reactions at a carbene centerQ44567882
Amino-aryl-carbenes: alternative ligands for transition metals?Q44753433
Oxidative addition of imidazolium salts to Ni(0) and Pd(0): synthesis and structural characterization of unusually stable metal-hydride complexesQ44781203
1,3-dialkyl- and 1,3-diaryl-3,4,5,6-tetrahydropyrimidin-2-ylidene rhodium(i) and palladium(II) complexes: synthesis, structure, and reactivityQ44791175
Gold(I)-catalyzed Conia-ene reaction of beta-ketoesters with alkynesQ44834570
The 1,4-diphosphabuta-1,3-diene ligand for coordination of divalent group 13 and 14 elements: a density functional studyQ44837881
Stable optically pure phosphino(silyl)carbenes: reagents for highly enantioselective cyclopropanation reactionsQ44840442
Anti-markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systemsQ44864791
Synthesis, reactivity, and ligand properties of a stable alkyl carbeneQ44975934
Polymer-supported well-defined metathesis catalystsQ79777612
Réplique: a new concept for bonding in carbodiphosphoranes?Q79851844
Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexesQ80005402
Cationic eta(1)/eta(2)-gold(I) complexes of simple arenesQ80103376
Titanocene and zirconocene complexes of a phosphorus analog of an Arduengo's carbene: application in the synthesis of 1,3-diphosphafulvenesQ80111975
Brønsted acid catalyzed addition of phenols, carboxylic acids, and tosylamides to simple olefinsQ80220712
Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflatesQ80220714
Reversible C-F bond formation and the Au-catalyzed hydrofluorination of alkynesQ80425583
Generation and coordinating properties of a carbene bearing a phosphorus ylide: an intensely electron-donating ligandQ80448722
P433issue47
P407language of work or nameEnglishQ1860
P304page(s)8810-8849
P577publication date2010-11-01
P1433published inAngewandte Chemie International EditionQ62023953
P1476titleStable cyclic carbenes and related species beyond diaminocarbenes
P478volume49

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Q52968705Activation of C-F bonds in fluoroarenes by N-heterocyclic carbenes as an effective route to synthesize abnormal NHC complexes.
Q48156101Adduct Formation, B-H Activation and Ring Expansion at Room Temperature from Reactions of HBcat with NHCs
Q46834701Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3.
Q57284463Alkyl Isosteres
Q38189659Allenes and computational chemistry: from bonding situations to reaction mechanisms.
Q34252320Allenes in molecular materials
Q48313057An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents.
Q46320941An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH].
Q29394718An overview of N-heterocyclic carbenes
Q45000731Anionic 1,2,3-triazole-4,5-diylidene: a 1,2-dihapto ligand for the construction of bimetallic complexes
Q44275238Anionic and zwitterionic copper(I) complexes incorporating an anionic N-heterocyclic carbene decorated with a malonate backbone: synthesis, structure and catalytic applications.
Q46121094Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine
Q52893216Aromatic ylide-stabilized carbocyclic silylene.
Q39075418Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs).
Q46632440Bond activation with an apparently benign ethynyl dithiocarbamate Ar-C≡C-S-C(S)NR2.
Q56519260Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2
Q56113838Building a Lewis Base with Boron
Q44051361C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions
Q52861826C-H activation in Ir(III) and N-demethylation in Pt(II) complexes with mesoionic carbene ligands: examples of monometallic, homobimetallic and heterobimetallic complexes.
Q48164847C-N Bond Activation and Ring Opening of a Saturated N-Heterocyclic Carbene by Lateral Alkali-Metal-Mediated Metalation
Q53153589C-N bond cleavage and ring expansion of N-heterocyclic carbenes using hydrosilanes.
Q38123495Carbene-Stabilized Main Group Radicals and Radical Ions
Q46083901Carbodicarbenes, carbon(0) derivatives, can dimerize
Q46441788Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.
Q57502898Chelating C4-Bound Imidazolylidene Complexes through Oxidative Addition of Imidazolium Salts to Palladium(0)
Q48179679Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C-H and C-F Bond Activation.
Q46051770Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene-carbene adducts
Q42279109Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC-B(CN)2.
Q46629423Complexation behavior of two-coordinated carbon compounds containing fluorenyl ligands
Q52542108Coordination Behavior of a Planar Chiral Cyclic (Amino)(Ferrocenyl)Carbene Ligand in Iridium Complexes.
Q41814303Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane
Q53395744Correlations and Contrasts in Homo- and Heteroleptic Cyclic (Alkyl)(amino)carbene-Containing Pt(0) Complexes.
Q46459036Cross-coupling reactions between stable carbenes
Q42157859Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs).
Q47772086Crystalline Neutral Allenic Diborene
Q39642679Cyclic (Alkyl)(Amino)Carbene Complexes of Rhodium and Nickel and Their Steric and Electronic Parameters
Q46209678Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals
Q42682072Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis
Q52875250Cyclometalated mono- and dinuclear Ir(III) complexes with "click"-derived triazoles and mesoionic carbenes.
Q42042236Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion
Q39156899Determination of conditional stability constants for phytic acid complexes with Mg2+, Ca2+ and Zn2+ ions using electrospray ionization mass spectrometry.
Q83718045Diamidocarbenes as versatile and reversible [2 + 1] cycloaddition reagents
Q45069502Diastereoselective synthesis of eight-membered-ring allenes from propargylic epoxides and aldehydes by silylene insertion into carbon-oxygen bonds
Q50211637Dinuclear iridium and rhodium complexes with bridging arylimidazolide-N(3),C(2) ligands: synthetic, structural, reactivity, electrochemical and spectroscopic studies
Q36524958Direct estimate of the internal π-donation to the carbene centre within N-heterocyclic carbenes and related molecules
Q45904984Direct evidence for the attack of a free N-heterocyclic carbene at a carbonyl ligand: a zwitterionic osmium carbonyl cluster.
Q92936903Distinct Palladium(II) Carbene Complexes Supported by Six-Membered 1,3-Disubstituted Permidin-2-ylidene, Six-Membered N-Heterocyclic Carbenes
Q46539008Distinguishing carbones from allenes by complexation to AuCl.
Q48129589Diversity of reactivity modes upon interplay between Au(iii)-bound isocyanides and cyclic nitrones: a theoretical consideration
Q51490505Donor-Flexible Nitrogen Ligands for Efficient Iridium-Catalyzed Water Oxidation Catalysis.
Q50888046Donor-Stabilized Silylene/Phosphine-Supported Carbon(0) Center with High Electron Density.
Q59332855Double dative bond between divalent carbon(0) and uranium
Q45718850Easy abstraction of a hydride anion from an alkyl C-H bond of a coordinated bis(N-heterocyclic carbene).
Q46972842Efficient electronic communication of two ruthenium centers through a rigid ditopic N-heterocyclic carbene linker
Q48140312Eight-membered-ring diaminocarbenes bearing naphthalene moiety in the backbone: DFT studies, synthesis of amidinium salts, generation of free carbene, metal complexes, and solvent-free copper catalyzed azide-alkyne cycloaddition (CuAAC) reaction
Q57835123Ein robuster mesoionischer Pyridylcarben-Cobalt-Komplex als Elektrokatalysator für die Wasserstoff-Produktion
Q52861969Electrocatalytic Dihydrogen Production with a Robust Mesoionic Pyridylcarbene Cobalt Catalyst.
Q45060842Electronic structure trends in N-heterocyclic carbenes (NHCs) with varying number of nitrogen atoms and NHC-transition-metal bond properties.
Q57502835Ether formation through reductive coupling of ketones or aldehydes catalyzed by a mesoionic carbene iridium complex
Q43832317Expanding the coordination chemistry of donor-stabilized group-14 metalenes.
Q50241065Expedient Mechanosynthesis of N,N-Dialkyl Imidazoliums and Silver(I)-Carbene Complexes in a Ball-Mill
Q57905672Experimental Charge Density Study of a Silylone
Q46116229Experimental and computational studies of anti-Bredt amidinium salts
Q57905673Experimentelle Elektronendichteuntersuchung eines Silylons
Q49626857Exploring bis-(amino)cyclopropenylidene as a non-covalent Brønsted base catalyst in conjugate addition reactions
Q43729492Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters
Q47161564Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system
Q47353076Facile Synthesis of Size-Tunable Functional Polyimidazolium Macrocycles through a Photochemical Closing Strategy
Q50092830Facile insertion of a cyclic alkyl(amino) carbene carbon into the B-B bond of diboron(4) reagents
Q35055232Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts
Q46665915First N-Heterocyclic Carbenes Relying on the Triazolone Structural Motif: Syntheses, Modifications and Reactivity
Q46037797Fusing N-heterocyclic carbenes with carborane anions.
Q46407829Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes
Q37390532Gold(I) and Palladium(II) Complexes of 1,3,4-Trisubstituted 1,2,3-Triazol-5-ylidene "Click" Carbenes: Systematic Study of the Electronic and Steric Influence on Catalytic Activity
Q42264885Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes.
Q42796001Grubbs and Hoveyda-Type Ruthenium Complexes Bearing a Cyclic Bent-Allene
Q46384231Half-sandwich iridium N-heterocyclic carbene anticancer complexes
Q48094674High-Fidelity, Narcissistic Self-Sorting in the Synthesis of Organometallic Assemblies from Poly-NHC Ligands.
Q53315708Homo- and Heterodinuclear Ir and Rh Imine-functionalized Protic NHC Complexes: Synthetic, Structural Studies, and Tautomerization/Metallotropism Insights.
Q43512268How can a carbene be active in an ionic liquid?
Q52575988How to tame a palladium terminal oxo.
Q41171343Imidazol-2-ylidene-N'-phenylureate ligands in alkali and alkaline earth metal coordination spheres--heterocubane core to polymeric structural motif formation
Q55632949Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir-η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion.
Q50600572Isolation of a Cyclic (Alkyl)(amino)germylene.
Q46701803Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species
Q48095883Isolation of a Reactive Cyclopropane Intermediate via a Unique Catalyst-Free Spontaneous Cyclopropanation Step at 0 °C.
Q46872559Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile
Q35085855Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes.
Q46829900Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct: a mesoionic germylene equivalent
Q34502847Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction".
Q42004049Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes
Q54946221Isolation of diborenes and their 90°-twisted diradical congeners.
Q39192573Labile coordination approach for the modulation of the electronic properties of ruthenium(II) and iridium(III) complexes within an "N-heterocyclic carbene (NHC)-pyridyl" dynamic platform
Q48294569Ligand versus Complex: C-F and C-H Bond Activation of Polyfluoroaromatics at a Cyclic (Alkyl)(Amino)Carbene
Q46314793Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine
Q57502908Mesoionic oxides: facile access from triazolium salts or triazolylidene copper precursors, and catalytic relevance
Q41957992Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes
Q53551494Metal-Free Reduction of CO2 to Methoxyborane under Ambient Conditions through Borondiformate Formation.
Q52880002Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex.
Q64996932Molecular Orbital Insights of Transition Metal-Stabilized Carbocations.
Q53090754Molecular rectangles from platinum(II) and bridging dicarbene, diisocyanide and 4,4'-bipyridine ligands.
Q45834376Molecular zinc dihydride stabilized by N-heterocyclic carbenes.
Q54765831N,N'-diamidocarbenes facilitate selective C-H insertions and transfer hydrogenations.
Q38662698N-Heterocyclic carbenes as supporting ligands in transition metal complexes of N2.
Q47136620N-Phosphine Oxide-Substituted Imidazolylidenes (PoxIms): Multifunctional Multipurpose Carbenes.
Q56997601NHC-Au(I) Complexes: Synthesis, Activation, and Application
Q45942798NHC-CAAC Heterodimers with Three Stable Oxidation States.
Q52695191NMR analysis of an Fe(i)-carbene complex with strong magnetic anisotropy.
Q38219323New bonding modes of carbon and heavier group 14 atoms Si-Pb
Q37855584New perspectives for "non-classical" molecules: heavy [1.1.1]propellanes of group 14.
Q84424027Nitrenium ions as ligands for transition metals
Q46791581Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor
Q27684791Observation of a stable carbene at the active site of a thiamin enzyme
Q50250123One-Electron Oxidation of a Disilicon(0) Compound: An Experimental and Theoretical Study of [Si2](+) Trapped by N-Heterocyclic Carbenes
Q46250744Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct
Q54438712Oxidative addition of 2-halogenoazoles-direct synthesis of palladium(II) complexes bearing protic NH,NH-functionalized NHC ligands.
Q57502919PEPPSI-Type Palladium Complexes Containing Basic 1,2,3-Triazolylidene Ligands and Their Role in Suzuki-Miyaura Catalysis
Q64169612Palladium Complexes Bearing Mesoionic Carbene Ligands: Applications in α-Arylation, α-Methylation and Suzuki-Miyaura Coupling Reactions
Q46679168Palladium(II) complexes with chelating N-phosphanyl acyclic diaminocarbenes: synthesis, characterization and catalytic performance in Suzuki couplings
Q51012832Palladium-catalyzed direct C2-arylation of an N-heterocyclic carbene: an atom-economic route to mesoionic carbene ligands.
Q46605368Platinum(II) and platinum(IV) complexes stabilized by abnormal/mesoionic C4-bound dicarbenes
Q58486770Proton transfer reactions ofN-aryl triazolium salts: unusualortho-substituent effects
Q42152980Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis
Q44043186Pyridine-based dicarbene ligand: synthesis and structure of a bis-2-pyridylidene palladium complex
Q42154167Pyridylidene ligand facilitates gold-catalyzed oxidative C-H arylation of heterocycles
Q41949860Rare-Earth- and Uranium-Mesoionic Carbenes: A New Class of f-Block Carbene Complex Derived from an N-Heterocyclic Olefin
Q48294813Reactivity of NHC Alane Adducts towards N-Heterocyclic Carbenes and Cyclic (Alkyl)(amino)carbenes: Ring Expansion, Ring Opening, and Al-H Bond Activation
Q44187286Recent advances in the field of main-group mono- and diatomic "allotropes" stabilised by neutral ligands
Q46660560Redox-active multinuclear Pd(II) complexes with bis- and tris-mesoionic carbenes
Q38906499Regioselective Photoisomerization/C-C Bond Formation of Asymmetric B(ppy)(Mes)(Ar): The Role of the Aryl Groups on Boron.
Q54767545Reversible photochemical modifications in dicarbene-derived metallacycles with coumarin pendants.
Q52944550Room temperature ring expansion of N-heterocyclic carbenes and B-B bond cleavage of diboron(4) compounds.
Q52868914Ru(II), Os(II), and Ir(III) complexes with chelating pyridyl-mesoionic carbene ligands: structural characterization and applications in transfer hydrogenation catalysis.
Q52849698RuII, IrIII and OsII mesoionic carbene complexes: efficient catalysts for transfer hydrogenation of selected functionalities.
Q46899776Ruthenium complexes of an abnormally bound, anionic N-heterocyclic carbene
Q46613696Serendipitous Observation of Al(I) Insertion into a CO Bond in L2 PhB: (L=oxazol-2-ylidene).
Q46737509Silver(I) NHC mediated C-C bond activation of alkyl nitriles and catalytic efficiency in oxazoline synthesis
Q51683313Silver-Catalyzed Amidiniumation of Alkynes: Isolation of a Silver Intermediate, Synthesis of Enamine Amido Carbene Precursors, and an Unprecedented Umpolung of Propiolamide.
Q48355179Small Molecule Activation with N,NR-MIC Platinum Complexes
Q46015067Stability and electronic properties of imidazole-based mesoionic carbenes.
Q48135888Stable Di- and Tri-coordinated Carbon(II) Supported by an Electron-Rich β-Diketiminate Ligand.
Q92168212Stable Mesoionic N-Heterocyclic Olefins (mNHOs)
Q57974347Strong electron-donating metalla-N-heterocyclic carbenes
Q35580573Structurally Characterized Cationic Silver(I) and Ruthenium(II)carbene complexes of 1,2,3-Triazol-5-ylidenes
Q48301881Subporpholactone, Subporpholactam, Imidazolosubporphyrin, and Iridium Complexes of Imidazolosubporphyrin: Formation of Iridium Carbene Complexes
Q48367840Supramolecular Assembly of Phosphole Oxide Based Alkynylplatinum(II) 2,6-Bis(N-alkylbenzimidazol-2'-yl)pyridine Complexes-An Interplay of Hydrophobicity and Aromatic π-Surfaces
Q40710283Syntheses, structural characterisation and electronic structures of some simple acyclic amino carbene complexes.
Q45117505Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines
Q37928601Synthesis and reactions of N-heterocyclic carbene boranes
Q44223404Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes
Q51043863Synthesis and structural characterization of a C₄ cumulene including 4-pyridylidene units, and its reactivity towards ammonia-borane.
Q53518807Synthesis of Complexes with Abnormal "Protic" N-Heterocyclic Carbenes.
Q41854222Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis
Q45991766Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon.
Q53611280Synthesis of a flexible macrocyclic tetraimidazolium salt-precursor for a tetracarbene ligand with metal dependent coordination modes.
Q46307046Synthesis of polynuclear Ag(I) and Au(I) complexes from macrocyclic tetraimidazolium salts.
Q50278281Synthesis, Characterization, and Theoretical Investigation of Two-Coordinate Palladium(0) and Platinum(0) Complexes Utilizing π-Accepting Carbenes
Q53404538Synthesis, Electronic Structure, and Reactivities of Two-Sulfur-Stabilized Carbones Exhibiting Four-Electron Donor Ability.
Q46653537Synthesis, Structure, and Reactivities of Iminosulfane- and Phosphane-Stabilized Carbones Exhibiting Four-Electron Donor Ability.
Q52876186Systematic investigation of the ring-expansion reaction of N-heterocyclic carbenes with an iminoborane dihydride.
Q44367699Temporary intramolecular generation of pyridine carbenes in metal-free three-component C-H bond functionalisation/aryl-transfer reactions.
Q47748752The Forgotten Nitroaromatic Phosphines as Weakly Donating P-ligands: An N-Aryl-benzimidazolyl Series in RhCl(CO) Complexes.
Q37887529The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters.
Q54488257The ambivalent chemistry of a free anionic N-heterocyclic carbene decorated with a malonate backbone: the plus of a negative charge.
Q90535423The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis
Q46660117The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound
Q54025361Theoretical strategies toward stabilization of singlet remote N-heterocyclic carbenes.
Q45055924Theory of the formation and decomposition of N-heterocyclic aminooxycarbenes through metal-assisted [2+3]-dipolar cycloaddition/retro-cycloaddition
Q52886149Transfer hydrogenation with abnormal dicarbene rhodium(iii) complexes containing ancillary and modular poly-pyridine ligands.
Q48313129Triazolylidene-Iridium Complexes with a Pendant Pyridyl Group for Cooperative Metal-Ligand Induced Catalytic Dehydrogenation of Amines
Q45096085Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts
Q52863312Triply cyclometalated trinuclear iridium(III) and trinuclear palladium(II) complexes with a tri-mesoionic carbene ligand.
Q58864847Tunable Photochromism in Air-Stable, Robust Dithienylethene-Containing Phospholes through Modifications at the Phosphorus Center
Q58864691Tunable Photochromism in the Robust Dithienylethene-Containing Phospholes: Design, Synthesis, Characterization, Electrochemistry, Photophysics, and Photochromic Studies
Q51566185Turn-On Fluorescence in Tetra-NHC Ligands by Rigidification through Metal Complexation: An Alternative to Aggregation-Induced Emission.
Q48223404Two Structurally Characterized Conformational Isomers with Different C-P Bonds
Q46788992Unexpected migratory insertion reactions of M(alkyl)2 (M=Zn, Cd) and diamidocarbenes
Q50098803Unveiling the role of ancillary ligands in acceptorless benzyl alcohol dehydrogenation and etherification mediated by mesoionic carbene iridium complexes
Q46535573Versatile bonding and coordination modes of ditriazolylidene ligands in rhodium(iii) and iridium(iii) complexes
Q41906295Versatile deprotonated NHC: C,N-bridged dinuclear iridium and rhodium complexes
Q38195732Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization
Q49956024What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?
Q46387885Ynamides: stable ligand equivalents of unstable oxazol-4-ylidenes (novel mesoionic carbenes).
Q53551536[CNN]-pincer nickel(II) complexes of N-heterocyclic carbene (NHC): synthesis and catalysis of the Kumada reaction of unactivated C-Cl bonds.
Q45309453ortho-Phenylene bridged palladium bis-N-heterocyclic carbene complexes: synthesis, structure and catalysis
Q38763980α-Radical Phosphines: Synthesis, Structure, and Reactivity
Q43723599β- and α-Hydride abstraction in Gold(I) alkyl complexes

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