Recent advances in the use of temporary silicon tethers in metal-mediated reactions

scientific article published on September 14, 2010

Recent advances in the use of temporary silicon tethers in metal-mediated reactions is …
instance of (P31):
scholarly articleQ13442814

External links are
P356DOI10.1039/C0CS00007H
P953full work available at URLhttp://pubs.rsc.org/en/content/articlepdf/2010/CS/C0CS00007H
P698PubMed publication ID20838677

P2093author name stringSonia Bracegirdle
Edward A. Anderson
P2860cites workA Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin MetathesisQ95822205
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Synthesis of unsymmetrical o-biphenols and o-binaphthols via silicon-tethered Pd-catalyzed C-H arylationQ33863304
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Enantioselective total synthesis of the potent antitumor agent (-)-mucocin using a temporary silicon-tethered ring-closing metathesis cross-coupling reactionQ34507206
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Stereoselective synthesis of syn,syn- and syn,anti-1,3,5-triols via intramolecular hydrosilylation of substituted pent-3-en-1,5-diolsQ38472750
Diastereoselective intramolecular temporary silicon-tethered rhodium-catalyzed [4+2+2] cycloisomerization reactions: regiospecific incorporation of substituted 1,3-butadienesQ40484504
Application of tandem ring-closing enyne metathesis: formal total synthesis of (-)-cochleamycin A.Q41826660
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Arylsilane oxidation—new routes to hydroxylated aromaticsQ56059315
The oxidation of the carbon-silicon bondQ56830554
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Asymmetric Si–O coupling of alcoholsQ59203489
Zirconocene-Mediated Intramolecular Carbon−Carbon Bond Formation of Two Alkynyl Groups of Bis(alkynyl)silanesQ60167027
Synthesis of C-19-functionalized 1alpha-hydroxyvitamin D(2) analogues via ring-closing metathesisQ73046749
Intramolecular syn and anti hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted allylic alcoholsQ73178747
Synthesis of various silacycles via the lewis acid-catalyzed intramolecular trans-hydrosilylation of unactivated alkynesQ73375450
New and efficient procedure for the preparation of unsymmetrical silaketalsQ73488085
Efficient stereochemical relay en route to leucascandrolide AQ73643252
Rapid assembly of structurally defined and highly functionalized conjugated dienes via tethered enyne metathesisQ74062828
Intramolecular hydrosilylation and silicon-assisted cross-coupling: an efficient route to trisubstituted homoallylic alcoholsQ74109273
The synthesis of an exhaustively stereodiversified library of cis-1,5 enediols by silyl-tethered ring-closing metathesisQ74146343
Tandem intramolecular silylformylation-crotylsilylation: highly efficient synthesis of polyketide fragmentsQ74403539
Silicon-tethered cyclocarbonylation of alkynesQ74618870
Temporary Silicon-Tethered Ring-Closing Metathesis Approach to C(2)-Symmetrical 1,4-Diols: Asymmetric Synthesis of D-AltritolQ74838788
Lewis acid catalyzed stereoselective carbosilylation. Intramolecular trans-vinylsilylation and trans-arylsilylation of unactivated alkynesQ77096066
Silicon tether-aided coupling metathesis: application to the synthesis of attenol AQ78492259
Intramolecular anti-hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted homoallylic alcoholsQ78492298
Intramolecular endo-dig hydrosilylation catalyzed by ruthenium: evidence for a new mechanistic pathwayQ78756712
Catalytic asymmetric silane alcoholysis: practical access to chiral silanesQ78849581
Stereocontrolled total synthesis of amphidinolide X via a silicon-tethered metathesis reactionQ79628603
Stereoselective total synthesis of (+)-streptazolin by using a temporary silicon-tethered RCM strategyQ79813432
Totally chemo- and regioselective cobalt(I)-mediated formal intermolecular cyclotrimerization of alkynesQ79969012
Enantioselective total synthesis of (-)-acylfulvene and (-)-irofulvenQ80059589
Ruthenium-catalyzed silyl ether formation and enyne metathesis sequence: synthesis of siloxacycles from terminal alkenyl alcohols and alkynylsilanesQ80391162
The Claisen rearrangement approach to fused bicyclic medium-ring oxacyclesQ80672181
Group-selective ring-closing enyne metathesis: concentration-dependent selectivity profile of alkynylsilyloxy-tethered dienynesQ80798727
High-yielding palladium-catalyzed intramolecular alkane arylation: reaction development and mechanistic studiesQ81559366
Titanium(II)-mediated cyclizations of (silyloxy)enynes: a total synthesis of (-)-7-demethylpiericidin A1Q82219330
Diastereoselective oxidative carbon-carbon bond formation via silyl bis-enol ethersQ82824076
Stereocontrol in intramolecular hydrosilylation of allyl and homoallyl alcohols: a new approach to the stereoselective synthesis of 1,3-diol skeletonsQ82992575
Total synthesis of (-)-dictyostatinQ83166049
Palladium-catalyzed cross-coupling reactions of silanolates: a paradigm shift in silicon-based cross-coupling reactionsQ83278132
Iron-catalyzed, directed oxidative arylation of olefins with organozinc and Grignard reagentsQ84295061
Zirconium- and silicon-containing intermediates with three fused rings in a zirconocene-mediated intermolecular coupling reactionQ84483564
P433issue11
P407language of work or nameEnglishQ1860
P921main subjectsiliconQ670
P304page(s)4114-4129
P577publication date2010-09-14
P1433published inChemical Society ReviewsQ2962268
P1476titleRecent advances in the use of temporary silicon tethers in metal-mediated reactions
P478volume39

Reverse relations

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