The N-H functional group in organometallic catalysis.

scientific article published on 07 March 2013

The N-H functional group in organometallic catalysis. is …
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scholarly articleQ13442814

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P356DOI10.1002/ANIE.201204921
P698PubMed publication ID23471875

P50authorKuiling DingQ56452547
P2093author name stringBaoguo Zhao
Zhaobin Han
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Asymmetric Activation/Deactivation of Racemic Ru Catalysts for Highly Enantioselective Hydrogenation of Ketonic Substrates We are grateful to Drs. H. Kumobayashi and N. Sayo of the Takasago International Corp. for providing the BINAP ligands. We alsQ53330738
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Bifunctional metal-ligand catalysis: hydrogenations and new reactions within the metal-(di)amine scaffoldQ28274230
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Self-assembly of bidentate ligands for combinatorial homogeneous catalysis: asymmetric rhodium-catalyzed hydrogenationQ33237847
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Mechanism of asymmetric hydrogenation of ketones catalyzed by BINAP/1,2-diamine-rutheniumII complexesQ33430487
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Application of a supramolecular-ligand library for the automated search for catalysts for the asymmetric hydrogenation of industrially relevant substratesQ33500219
Transition-state stabilization by a secondary substrate-ligand interaction: a new design principle for highly efficient transition-metal catalysisQ33524474
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Supramolecular catalysis beyond enzyme mimicsQ34127515
An additional coordination group leads to extremely efficient chiral iridium catalysts for asymmetric hydrogenation of ketonesQ34200033
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Heterogeneous enantioselective catalysts: strategies for the immobilisation of homogeneous catalystsQ35651469
Metal-ligand bifunctional catalysis for asymmetric hydrogenation.Q36131602
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Desymmetrization of meso-Cyclic Imides via Enantioselective MonohydrogenationQ42927796
Asymmetric Hydrogenation of Bicyclic Ketones Catalyzed by BINAP/IPHAN−Ru(II) ComplexQ42952603
Asymmetric hydrogenation of ketones catalyzed by a ruthenium(II)-indan-ambox complexQ43091134
Oxidation catalysis of Nb(salan) complexes: asymmetric epoxidation of allylic alcohols using aqueous hydrogen peroxide as an oxidantQ43112120
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Mechanism of the hydrogenation of ketones catalyzed by trans-dihydrido(diamine)ruthenium II complexesQ44244423
Highly efficient chiral metal cluster systems derived from Ru3(CO)12 and chiral diiminodiphosphines for the asymmetric transfer hydrogenation of ketonesQ44335099
Hydrogen bonding as a construction element for bidentate donor ligands in homogeneous catalysis: regioselective hydroformylation of terminal alkenesQ44455670
A new class of "tethered" ruthenium(II) catalyst for asymmetric transfer hydrogenation reactions.Q44744340
Noncovalent anchoring of homogeneous catalysts to silica supports with well-defined binding sitesQ45135339
Enantioselective tandem michael addition/H2-hydrogenation catalyzed by ruthenium hydride borohydride complexes containing beta-aminophosphine ligandsQ45219506
A dynamic supramolecular system exhibiting substrate selectivity in the catalytic epoxidation of olefins.Q45227121
A succession of isomers of ruthenium dihydride complexes. Which one is the ketone hydrogenation catalyst?Q45257633
Self-assembly of bidentate ligands for combinatorial homogeneous catalysis based on an A-T base-pair modelQ45259997
Kinetic hydrogen/deuterium effects in the direct hydrogenation of ketones catalyzed by a well-defined ruthenium diphosphine diamine complex.Q45927947
Metal-Brønsted acid cooperative catalysis for asymmetric reductive amination.Q46032109
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New benzo[h]quinoline-based ligands and their pincer Ru and Os complexes for efficient catalytic transfer hydrogenation of carbonyl compounds.Q46358171
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Direct observations of the metal-ligand bifunctional addition step in an enantioselective ketone hydrogenationQ46430383
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"Tethered" Ru(II) catalysts for asymmetric transfer hydrogenation of ketones.Q46431771
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Asymmetric transfer hydrogenation of C=O and C=N bonds by tethered Rh(III) catalystsQ46455685
CpRu(PN) complex-catalyzed isomerization of allylic alcohols and its application to the asymmetric synthesis of musconeQ46456684
Self-supported heterogeneous titanium catalysts for enantioselective carbonyl-ene and sulfoxidation reactionsQ46463695
Dual functionalities of hydrogen-bonding self-assembled catalysts in chelation-assisted hydroacylationQ46526450
Asymmetric hydrogenation of tert-alkyl ketonesQ46532465
Construction of pseudo-heterochiral and homochiral di-mu-oxotitanium(Schiff base) dimers and enantioselective epoxidation using aqueous hydrogen peroxideQ46585579
Role of the NH2 functionality and solvent in terdentate CNN alkoxide ruthenium complexes for the fast transfer hydrogenation of ketones in 2-propanolQ46668231
A remarkably effective catalyst for the asymmetric transfer hydrogenation of aromatic ketones in water and air.Q46681744
Ethanol as hydrogen donor: highly efficient transfer hydrogenations with rhodium(I) amidesQ46695683
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Metal-organic cooperative catalysis in C-H and C-C bond activation and its concurrent recoveryQ46773697
P433issue18
P407language of work or nameEnglishQ1860
P304page(s)4744-4788
P577publication date2013-03-07
P1433published inAngewandte Chemie International EditionQ62023953
P1476titleThe N-H functional group in organometallic catalysis
P478volume52