Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis.

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Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis. is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1021/ACSCENTSCI.5B00035
P932PMC publication ID4827665
P698PubMed publication ID27162946
P5875ResearchGate publication ID277562948

P50authorSubrata K GhoshQ58806618
P2093author name stringNattamai Bhuvanesh
John A Gladysz
Kyle G Lewis
P2860cites workEnzyme Catalysis by Hydrogen Bonds: The Balance between Transition State Binding and Substrate Binding in Oxyanion HolesQ29302348
The advent and development of organocatalysisQ29394444
Recent Progress on the Stereoselective Synthesis of Cyclic Quaternary alpha-Amino AcidsQ33730582
Enantioselective alpha-amination of 1,3-dicarbonyl compounds using squaramide derivatives as hydrogen bonding catalystsQ33821298
Enantioselective Michael Reaction of Malonates to Nitroolefins Catalyzed by Bifunctional OrganocatalystsQ34269830
Asymmetric catalysis by chiral hydrogen-bond donorsQ34496444
Kinetic origin of the chelate effect. Base hydrolysis, H-exchange reactivity, and structures of syn,anti-[Co(cyclen)(NH3)2]3+ and syn,anti-[Co(cyclen)(diamine)]3+ ions (diamine = H2N(CH2)2NH2, H2N(CH2)3NH2).Q34513527
Small-molecule H-bond donors in asymmetric catalysisQ34723907
Applications of chiral C3-symmetric moleculesQ36541644
Recent approaches towards the asymmetric synthesis of alpha,alpha-disubstituted alpha-amino acidsQ36718001
Hydrogen-bond-mediated asymmetric catalysisQ37089163
Squaramide-catalyzed enantioselective Michael addition of diphenyl phosphite to nitroalkenes.Q37594884
Asymmetric catalysis with an inert chiral-at-metal iridium complexQ44286253
Highly enantioselective conjugate addition of malonate and beta-ketoester to nitroalkenes: asymmetric C-C bond formation with new bifunctional organic catalysts based on cinchona alkaloidsQ45013302
Chiral-at-metal octahedral iridium catalyst for the asymmetric construction of an all-carbon quaternary stereocenterQ45717113
Stereospecific synthesis of C2 symmetric diamines from the mother diamine by resonance-assisted hydrogen-bond directed diaza-Cope rearrangementQ46431688
Novel bifunctional chiral urea and thiourea derivatives as organocatalysts: enantioselective nitro-Michael reaction of malonates and diketonesQ46630606
Enantioselective organocatalytic Michael addition of malonate esters to nitro olefins using bifunctional cinchonine derivativesQ46681778
Recognition and activation by ureas and thioureas: stereoselective reactions using ureas and thioureas as hydrogen-bonding donorsQ46835559
Enantioselective 1,4-addition reactions of diphenyl phosphite to nitroalkenes catalyzed by an axially chiral guanidineQ46931730
The low barrier hydrogen bond in enzymatic catalysis.Q55067989
Zur Kenntnis des asymmetrischen Kobaltatoms. VQ56434676
Extended scale for the hydrogen-bond basicity of ionic liquidsQ57390153
Axially chiral guanidine as highly active and enantioselective catalyst for electrophilic amination of unsymmetrically substituted 1,3-dicarbonyl compoundsQ79430129
Asymmetric construction of quaternary stereocenters by direct organocatalytic amination of alpha-substituted alpha-cyanoacetates and beta-dicarbonyl compoundsQ80259779
Phase transfer of enantiopure Werner cations into organic solvents: an overlooked family of chiral hydrogen bond donors for enantioselective catalysisQ81195438
Chiral 2-aminobenzimidazoles as recoverable organocatalysts for the addition of 1,3-dicarbonyl compounds to nitroalkenesQ84281416
New media for classical coordination chemistry: phase transfer of Werner and related polycations into highly nonpolar fluorous solventsQ87162331
C3 Symmetry in Asymmetric Catalysis and Chiral RecognitionQ88519999
P433issue1
P407language of work or nameEnglishQ1860
P921main subjectcobaltQ740
chiralityQ214514
enantioselectivityQ1339952
P304page(s)50-56
P577publication date2015-03-23
P1433published inACS Central ScienceQ27726586
P1476titleCobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis
P478volume1

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cites work (P2860)
Q53139683A copper-templated, bifunctional organocatalyst: a strongly cooperative dynamic system for the aldol reaction.
Q50237319Chiral Cobalt(III) Complexes as Bifunctional Brønsted Acid-Lewis Base Catalysts for the Preparation of Cyclic Organic Carbonates
Q38985699Octahedral Werner complexes with substituted ethylenediamine ligands: a stereochemical primer for a historic series of compounds now emerging as a modern family of catalysts
Q52575898Rhodium-catalyzed asymmetric hydrogenation of β-cyanocinnamic esters with the assistance of a single hydrogen bond in a precise position.
Q91783277Synthesis of non-racemic 4-nitro-2-sulfonylbutan-1-ones via Ni(II)-catalyzed asymmetric Michael reaction of β-ketosulfones
Q55391131The robust, readily available cobalt(iii) trication [Co(NH2CHPhCHPhNH2)3]3+ is a progenitor of broadly applicable chirality and prochirality sensing agents.
Q51443505The squaramide-catalyzed asymmetric Michael/cyclization tandem reaction for the synthesis of chiral trifluoromethylated hydroxyimino tetrahydrobenzofuranones.
Q48351453Vibrational optical activity as probe for intermolecular interactions.
Q48229111Werner Complexes with ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands: Bifunctional Hydrogen-Bond-Donor Catalysts for Highly Enantioselective Michael Additions

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