| P50 | author | Stefan van der Vorm | Q61456829 |
| | Thomas Hansen | Q57976869 |
| P2093 | author name string | G A van der Marel | |
| | H S Overkleeft | |
| | J D C Codée | |
| P2860 | cites work | A survey of Hammett substituent constants and resonance and field parameters | Q29036840 |
| | Is donor-acceptor hydrogen bonding necessary for 4,6-O-benzylidene-directed beta-mannopyranosylation? Stereoselective synthesis of beta-C-mannopyranosides and alpha-C-glucopyranosides | Q30437944 |
| | α-Selective Organocatalytic Synthesis of 2-Deoxygalactosides | Q62603825 |
| | Oxazolidinone Protection of N-Acetylglucosamine Confers High Reactivity on the 4-Hydroxy Group in Glycosylation | Q73252298 |
| | S-(4-methoxyphenyl) benzenethiosulfinate (MPBT)/trifluoromethanesulfonic anhydride: a convenient system for the generation of glycosyl triflates from thioglycosides | Q73287628 |
| | Formation of beta-Mannopyranosides of Primary Alcohols Using the Sulfoxide Method | Q74823657 |
| | Chemistry of 4,6-O-Benzylidene-D-glycopyranosyl Triflates: Contrasting Behavior between the Gluco and Manno Series | Q77051361 |
| | Capsular polysaccharide of Streptococcus pneumoniae type 19F: synthesis of the repeating unit | Q77589869 |
| | Stereocontrolled synthesis of beta-D-mannuronic acid esters: synthesis of an alginate trisaccharide | Q79180366 |
| | DFT studies of the ionization of alpha and beta glycopyranosyl donors | Q80445782 |
| | A comparative study of the influence of some protecting groups on the reactivity of D-glucosamine acceptors with a galactofuranosyl donor | Q83186261 |
| | A comparative study of the O-3 reactivity of isomeric N-dimethylmaleoyl-protected D-glucosamine and D-allosamine acceptors | Q83410372 |
| | Automated solid-phase synthesis of β-mannuronic acid alginates | Q83447656 |
| | Mannopyranosyl uronic acid donor reactivity | Q84581261 |
| | Study of the stereoselectivity of 2-azido-2-deoxygalactosyl donors: relationship to the steric factors of glycosyl acceptors | Q84948409 |
| | β-Mannosylation with 4,6-benzylidene protected mannosyl donors without preactivation | Q85638499 |
| | Tuning reactivity of glycosyl imidinium intermediate for 2-azido-2-deoxyglycosyl donors in α-glycosidic bond formation | Q86494909 |
| | Mechanisms of glycosylation reactions studied by low-temperature nuclear magnetic resonance | Q87210762 |
| | β-Selective mannosylation with a 4,6-silylene-tethered thiomannosyl donor | Q87243394 |
| | Solvent nucleophilicity | Q30760756 |
| | Why are the hydroxy groups of partially protected N-acetylglucosamine derivatives such poor glycosyl acceptors, and what can be done about it? A comparative study of the reactivity of N-acetyl-, N-phthalimido-, and 2-azido-2-deoxy-glucosamine deriva | Q33423429 |
| | Correlations between nucleophilicities and selectivities in the substitutions of tetrahydropyran acetals | Q33683347 |
| | Erosion of stereochemical control with increasing nucleophilicity: O-glycosylation at the diffusion limit | Q33727064 |
| | Free energy relationships for reactions of substituted benzhydrylium ions: from enthalpy over entropy to diffusion control | Q34354464 |
| | Automated Solution-Phase Synthesis of β-1,4-Mannuronate and β-1,4-Mannan. | Q35702107 |
| | Continuum of mechanisms for nucleophilic substitutions of cyclic acetals | Q37147601 |
| | Mechanism of Glycosylation of Anomeric Sulfonium Ions | Q37363866 |
| | Torsional Control of Stereoselectivities in Electrophilic Additions and Cycloadditions to Alkenes | Q37439126 |
| | Opportunities and challenges in synthetic oligosaccharide and glycoconjugate research | Q37477221 |
| | The impact of oxacarbenium ion conformers on the stereochemical outcome of glycosylations. | Q37719987 |
| | A propos of glycosyl cations and the mechanism of chemical glycosylation; the current state of the art. | Q38238441 |
| | Nucleophile-Directed Stereocontrol Over Glycosylations Using Geminal-Difluorinated Nucleophiles | Q38290264 |
| | Synthesis and bioactivity of β-(1→4)-linked oligomannoses and partially acetylated derivatives. | Q39142695 |
| | Synthesis of an alpha-kojibiosyl substituted glycerol teichoic acid hexamer | Q39880667 |
| | Further studies on cation clock reactions in glycosylation: observation of a configuration specific intramolecular sulfenyl transfer and isolation and characterization of a tricyclic acetal | Q41146868 |
| | Stereoselective C-glycoside formation with 2-O-benzyl-4,6-O-benzylidene protected 3-deoxy gluco- and mannopyranoside donors: comparison with O-glycoside formation | Q41476064 |
| | Cation clock permits distinction between the mechanisms of α- and β-O- and β-C-glycosylation in the mannopyranose series: evidence for the existence of a mannopyranosyl oxocarbenium ion. | Q41857348 |
| | Dissecting the mechanisms of a class of chemical glycosylation using primary ¹³C kinetic isotope effects | Q41900732 |
| | Influence of the O3 protecting group on stereoselectivity in the preparation of C-mannopyranosides with 4,6-O-benzylidene protected donors | Q42704172 |
| | Cation Clock Reactions for the Determination of Relative Reaction Kinetics in Glycosylation Reactions: Applications to Gluco- and Mannopyranosyl Sulfoxide and Trichloroacetimidate Type Donors | Q42734177 |
| | Mechanism of a chemical glycosylation reaction | Q43055773 |
| | Synthesis of potassium (2R)-2-O-alpha-d-glucopyranosyl-(1-->6)-alpha-d-glucopyranosyl-2,3-dihydroxypropanoate a natural compatible solute | Q43289617 |
| | Equatorial anomeric triflates from mannuronic acid esters | Q43296529 |
| | 1-Benzenesulfinyl piperidine/trifluoromethanesulfonic anhydride: a potent combination of shelf-stable reagents for the low-temperature conversion of thioglycosides to glycosyl triflates and for the formation of diverse glycosidic linkages | Q43734476 |
| | The stereodirecting effect of the glycosyl C5-carboxylate ester: stereoselective synthesis of beta-mannuronic acid alginates | Q43922980 |
| | Solid-phase synthesis of beta-mannosides | Q44076642 |
| | A Programmable One‐Pot Oligosaccharide Synthesis for Diversifying the Sugar Domains of Natural Products: A Case Study of Vancomycin | Q44610502 |
| | Influence of the 4,6-O-benzylidene, 4,6-O-phenylboronate, and 4,6-O-polystyrylboronate protecting groups on the stereochemical outcome of thioglycoside-based glycosylations mediated by 1-benzenesulfinyl piperidine/triflic anhydride and N-iodosuccini | Q44611878 |
| | Stereochemistry of nucleophilic substitution reactions depending upon substituent: evidence for electrostatic stabilization of pseudoaxial conformers of oxocarbenium ions by heteroatom substituents | Q44686011 |
| | Mechanism of 4,6-O-benzylidene-directed beta-mannosylation as determined by alpha-deuterium kinetic isotope effects | Q45093014 |
| | Direct chemical synthesis of the beta-mannans: linear and block syntheses of the alternating beta-(1-->3)-beta-(1-->4)-mannan common to Rhodotorula glutinis, Rhodotorula mucilaginosa, and Leptospira biflexa | Q45153101 |
| | Influence of O6 in mannosylations using benzylidene protected donors: stereoelectronic or conformational effects? | Q45165952 |
| | Stereodirecting effect of the pyranosyl C-5 substituent in glycosylation reactions. | Q45986286 |
| | Stereoselective C-glycosylation reactions of pyranoses: the conformational preference and reactions of the mannosyl cation. | Q45990754 |
| | Theoretical study on the effects of a 4,6-O-diacetal protecting group on the stability of ion pairs from D-mannopyranosyl and D-glucopyranosyl triflates | Q46727785 |
| | Programmable reactivity-based one-pot oligosaccharide synthesis | Q46754377 |
| | Chair interconversion and reactivity of mannuronic acid esters. | Q46890786 |
| | 2'-Carboxybenzyl glycosides: glycosyl donors for C-glycosylation and conversion into other glycosyl donors. | Q53599434 |
| | Tin-mediated regioselective benzylation and allylation of polyols: applicability of a catalytic approach under solvent-free conditions. | Q54492105 |
| | Tuning glycoside reactivity: New tool for efficient oligosaccharide synthesis | Q56514479 |
| | Effect of conformational change on reactivity in organic chemistry. Evaluations, applications, and extensions of Curtin-Hammett Winstein-Holness kinetics | Q56831841 |
| | Rapid assembly of oligosaccharides: 1,2-diacetal-mediated reactivity tuning in the coupling of glycosyl fluorides | Q56953247 |
| P433 | issue | 3 | |
| P407 | language of work or name | English | Q1860 |
| P921 | main subject | glycosylation | Q898365 |
| P304 | page(s) | 1867-1875 | |
| P577 | publication date | 2016-11-09 | |
| P1433 | published in | Chemical Science | Q2962267 |
| P1476 | title | The influence of acceptor nucleophilicity on the glycosylation reaction mechanism | |
| P478 | volume | 8 | |