Steric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible

scientific article published on August 2011

Steric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible is …
instance of (P31):
scholarly articleQ13442814

External links are
P356DOI10.1021/OM200515F
P932PMC publication ID3159157
P698PubMed publication ID21869853
P5875ResearchGate publication ID51598021

P2093author name stringMichel R Gagné
Shu-Bin Zhao
Jennifer J Becker
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Alkyl carbon-nitrogen reductive elimination from platinum(IV)-sulfonamide complexesQ80728742
Regioselective oxidative cation-olefin cyclization of poly-enes: catalyst turnover via hydride abstractionQ81238039
Palladium-mediated fluorination of arylboronic acidsQ81589864
Carbon-fluorine reductive elimination from a high-valent palladium fluorideQ81615269
Palladium-Catalyzed Asymmetric Synthesis of Allylic FluoridesQ82501721
Palladium-catalyzed tandem fluorination and cyclization of enynesQ83245089
Palladium-catalyzed allylic fluorinationQ83520844
Fluorination of boronic acids mediated by silver(I) triflateQ84027574
Palladium-catalyzed intramolecular aminofluorination of unactivated alkenesQ84783375
Fluorine-enabled cationic gold catalysis: functionalized hydration of alkynesQ84965984
Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluoridesQ24626698
Fluorine in pharmaceuticals: looking beyond intuitionQ27648640
Catalysis for fluorination and trifluoromethylationQ27687352
A "greener" synthetic route for fluoroaromatics via copper (II) fluorideQ28221308
Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclizationQ34015710
Terminating platinum-initiated cation-olefin reactions with simple alkenesQ36110674
Mechanistic aspects of C-H activation by Pt complexes.Q36154662
Catalytic carbophilic activation: catalysis by platinum and gold pi acidsQ36788319
Electrophilic activation of alkenes by platinum(II): so much more than a slow version of palladium(II).Q36815025
Reversibility effects on the stereoselectivity of Pt(II)-mediated cascade poly-ene cyclizationsQ36980542
Carbon-fluorine bond formationQ37306634
The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorinationQ37605136
Gold and platinum catalysis--a convenient tool for generating molecular complexityQ37619277
Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysisQ37832211
Mechanism of C-F reductive elimination from palladium(IV) fluoridesQ39973971
Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoterQ42163150
Cycloisomerization of dienes with carbophilic lewis acids: mimicking terpene biosynthesis with Pt(II) catalystsQ42392904
Silver-catalyzed late-stage fluorinationQ42429716
Synthesis and reactivity of a mono-sigma-aryl palladium(IV) fluoride complexQ42557757
Reagent-Dependent Formation of C−C and C−F Bonds in Pt Complexes: An Unexpected Twist in the Electrophilic Fluorination ChemistryQ42948181
Palladium-catalyzed intermolecular aminofluorination of styrenesQ43165610
Mechanism of N-fluorobenzenesulfonimide promoted diamination and carboamination reactions: divergent reactivity of a Pd(IV) speciesQ43262622
Studies of reductive elimination reactions to form carbon-oxygen bonds from Pt(IV) complexesQ43677595
Synthesis of the Elusive (R3P)2MF2 (M = Pd, Pt) ComplexesQ44643151
Palladium-catalyzed carboamination of alkenes promoted by N-fluorobenzenesulfonimide via C-H activation of arenes.Q45958878
Silver-mediated fluorination of functionalized aryl stannanesQ46134408
Autocatalytic alkyne cycloadditions: evidence for colloidal Pt catalysisQ46725538
Direct C(sp3)-O reductive elimination of olefin oxides from Pt(IV)-oxetanes prepared by aerobic oxidation of Pt(II) olefin derivatives (olefin = cis-cyclooctene, norbornene).Q46791254
Competitive aryl-iodide vs aryl-aryl reductive elimination reactions in Pt(IV) complexes: experimental and theoretical studiesQ46849483
Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexesQ48541382
Evidence for associative methane loss following protonation of (diimine)Pt(II)(Ch(3))(2): three-coordinate 14-electron cations l(2)Pt(Ch(3))(+) are not necessarily intermediates in C-H activation at cationic Pt complexesQ49300815
Enantioselective halocyclization of polyprenoids induced by nucleophilic phosphoramidites.Q51062881
Activation of C−H Bonds by Metal ComplexesQ55933283
P433issue15
P304page(s)3926-3929
P577publication date2011-08-01
P1433published inOrganometallicsQ595719
P1476titleSteric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible
P478volume30

Reverse relations

cites work (P2860)
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