VFe3S4 single and double cubane clusters: synthesis, structures, and dependence of redox potentials and electron distribution on ligation and heterometal

scientific article published on April 2008

VFe3S4 single and double cubane clusters: synthesis, structures, and dependence of redox potentials and electron distribution on ligation and heterometal is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1021/IC702372F
P932PMC publication ID2527441
P698PubMed publication ID18366157
P5875ResearchGate publication ID5486598

P2093author name stringR H Holm
Thomas A Scott
P2860cites workPrecursors to clusters with the topology of the P(N) cluster of nitrogenase: edge-bridged double cubane clusters [(Tp)2Mo2Fe6S8L4]z: synthesis, structures, and electron transfer seriesQ46961613
Structureminus signFunction Relationships of Alternative NitrogenasesQ77646462
Reduced mono-, di-, and tetracubane-type clusters containing the [MoFe3S4]2+ core stabilized by tertiary phosphine ligationQ78788209
Sulfur ligand substitution at the nickel(II) sites of cubane-type and cubanoid NiFe3S4 clusters relevant to the C-clusters of carbon monoxide dehydrogenaseQ79901627
Edge-bridged Mo2Fe6S8 to pN-type Mo2Fe6S9 cluster conversion: structural fate of the attacking sulfide/selenide nucleophileQ80214931
New insights into structure-function relationships in nitrogenase: A 1.6 A resolution X-ray crystallographic study of Klebsiella pneumoniae MoFe-proteinQ27620021
Redox-dependent structural changes in the nitrogenase P-clusterQ27734955
Vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4] core unit: synthesis of a cluster with the topology of the PN cluster of nitrogenase.Q30333197
XAFS studies of nitrogenase: the MoFe and VFe proteins and the use of crystallographic coordinates in three-dimensional EXAFS data analysis.Q30759672
Initial synthesis and structure of an all-ferrous analogue of the fully reduced [Fe4S4]0 cluster of the nitrogenase iron protein.Q33896066
Speculative synthetic chemistry and the nitrogenase problemQ34914160
The clusters of nitrogenase: synthetic methodology in the construction of weak-field clustersQ35660912
Stabilization of reduced molybdenum-iron-sulfur single- and double-cubane clusters by cyanide ligationQ42121940
Synthesis of MFe3S4 clusters containing a planar M(II) site (M = Ni, Pd, Pt), a structural element in the C-cluster of carbon monoxide dehydrogenaseQ43193527
Heterometal cubane-type MFe(3)S(4) clusters (M = Mo, V) trigonally symmetrized with hydrotris(pyrazolyl)borate(1-) and tris(pyrazolyl)methanesulfonate(1-) capping ligandsQ43889288
Single- and double-cubane clusters in the multiple oxidation states [VFe(3)S(4)](3+,2+,1+).Q43919252
Synthesis and reactions of cubane-type iron-sulfur-phosphine clusters, including soluble clusters of nuclearities 8 and 16.Q44269785
Synthesis of a molecular Mo2Fe6S9 cluster with the topology of the PN cluster of nitrogenase by rearrangement of an edge-bridged Mo2Fe6S8 double cubaneQ44375622
Initial structure modification of tetrahedral to planar nickel(II) in a nickel-iron-sulfur cluster related to the C-cluster of carbon monoxide dehydrogenase.Q44900355
P433issue8
P407language of work or nameEnglishQ1860
P304page(s)3426-3432
P577publication date2008-04-01
P1433published inInorganic ChemistryQ902828
P1476titleVFe3S4 single and double cubane clusters: synthesis, structures, and dependence of redox potentials and electron distribution on ligation and heterometal
P478volume47

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cites work (P2860)
Q37696184Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters
Q41784468Selenium as a structural surrogate of sulfur: template-assisted assembly of five types of tungsten-iron-sulfur/selenium clusters and the structural fate of chalcogenide reactants
Q35547039Specific incorporation of chalcogenide bridge atoms in molybdenum/tungsten-iron-sulfur single cubane clusters
Q35176941The [MoFe3S4]2+ oxidation state: synthesis, substitution reactions, and structures of phosphine-ligated cubane-type clusters with the S=2 ground state

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