Intermediate P* from soluble methane monooxygenase contains a diferrous cluster

scientific article published on 13 June 2013

Intermediate P* from soluble methane monooxygenase contains a diferrous cluster is …
instance of (P31):
scholarly articleQ13442814

External links are
P356DOI10.1021/BI400182Y
P932PMC publication ID3712755
P698PubMed publication ID23718184

P50authorJohn D. LipscombQ38327124
Rahul BanerjeeQ60736123
P2093author name stringEckard Münck
Katlyn K Meier
P2860cites workEvolution of strategies to prepare synthetic mimics of carboxylate-bridged diiron protein active sitesQ27028195
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Crystal structures of substrate and substrate analog complexes of protocatechuate 3,4-dioxygenase: endogenous Fe3+ ligand displacement in response to substrate bindingQ27741668
Revisiting the mechanism of dioxygen activation in soluble methane monooxygenase from M. capsulatus (Bath): evidence for a multi-step, proton-dependent reaction pathwayQ33554957
Carboxylate as the protonation site in (Peroxo)diiron(III) model complexes of soluble methane monooxygenase and related diiron proteinsQ33615672
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Methanotrophic bacteriaQ34396674
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Nature of the Fe-O2 bonding in oxy-myoglobin: effect of the proteinQ34850317
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Substrate-mediated oxygen activation by homoprotocatechuate 2,3-dioxygenase: intermediates formed by a tyrosine 257 variant.Q36441965
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Finding intermediates in the O2 activation pathways of non-heme iron oxygenases.Q36848901
CD and MCD studies of the effects of component B variant binding on the biferrous active site of methane monooxygenase.Q37037824
Hydrogen peroxide dependent cis-dihydroxylation of benzoate by fully oxidized benzoate 1,2-dioxygenaseQ37287300
A diiron(IV) complex that cleaves strong C-H and O-H bondsQ37347607
Structural Model Studies for the High-Valent Intermediate Q of Methane Monooxygenase from Broken-Symmetry Density Functional CalculationsQ38572925
Interaction of Ammonia Monooxygenase from Nitrosomonas europaea with Alkanes, Alkenes, and Alkynes.Q39927705
Mössbauer spectroscopy of metalloproteins and the use of Fourier transformsQ40915515
Characterization of a high-spin non-heme Fe(III)-OOH intermediate and its quantitative conversion to an Fe(IV)═O complexQ41973020
Methane monooxygenase from Methylosinus trichosporium OB3b. Purification and properties of a three-component system with high specific activity from a type II methanotroph.Q42109246
Spectroscopic and computational studies of the de novo designed protein DF2t: correlation to the biferrous active site of ribonucleotide reductase and factors that affect O2 reactivityQ43432849
Methane monooxygenase component B mutants alter the kinetics of steps throughout the catalytic cycleQ43592649
Intermediate Q from soluble methane monooxygenase hydroxylates the mechanistic substrate probe norcarane: evidence for a stepwise reactionQ43809998
Key amino acid residues in the regulation of soluble methane monooxygenase catalysis by component B.Q44437408
How O2 binds to heme: reasons for rapid binding and spin inversionQ44748878
Role of the C-terminal region of the B component of Methylosinus trichosporium OB3b methane monooxygenase in the regulation of oxygen activationQ46918117
Methane monooxygenase hydroxylase and B component interactions.Q46964889
Regulation of methane monooxygenase catalysis based on size exclusion and quantum tunnelingQ47350630
Dioxygen activation in methane monooxygenase: a theoretical studyQ48012027
End-On and Side-On Peroxo Derivatives of Non-Heme Iron Complexes with Pentadentate Ligands: Models for Putative Intermediates in Biological Iron/Dioxygen ChemistryQ50494968
Computational studies of reaction mechanisms of methane monooxygenase and ribonucleotide reductase.Q51641685
Oxygen activation catalyzed by methane monooxygenase hydroxylase component: proton delivery during the O-O bond cleavage steps.Q52218830
Residues inMethylosinus trichosporiumOB3b Methane Monooxygenase Component B Involved in Molecular Interactions with Reduced- and Oxidized-Hydroxylase Component: A Role for the N-Terminus†Q57943617
Unmasking of Deuterium Kinetic Isotope Effects on the Methane Monooxygenase Compound Q Reaction by Site-Directed Mutagenesis of Component BQ57943622
Kinetics and Activation Thermodynamics of Methane Monooxygenase CompoundQFormation and Reaction with Substrates†Q57943631
An Fe2IVO2 Diamond Core Structure for the Key Intermediate Q of Methane MonooxygenaseQ57943668
Large Kinetic Isotope Effects in Methane Oxidation Catalyzed by Methane Monooxygenase: Evidence for C−H Bond Cleavage in a Reaction Cycle Intermediate†Q57943713
Gating Effects of Component B on Oxygen Activation by the Methane Monooxygenase Hydroxylase ComponentQ57943718
Effect of Heme Modification on Oxygen Affinity of Myoglobin and Equilibrium of the Acid−Alkaline Transition in MetmyoglobinQ60463519
Methane monooxygenase component B and reductase alter the regioselectivity of the hydroxylase component-catalyzed reactions. A novel role for protein-protein interactions in an oxygenase mechanismQ67858553
Methane monooxygenase from Methylosinus trichosporium OB3bQ68665791
Evidence for a mu-oxo-bridged binuclear iron cluster in the hydroxylase component of methane monooxygenase. Mössbauer and EPR studiesQ69831973
Transient intermediates of the methane monooxygenase catalytic cycleQ70500721
O-O bond cleavage and alkane hydroxylation in methane monooxygenaseQ73470005
Dioxygen Activation by Enzymes Containing Binuclear Non-Heme Iron ClustersQ77646438
Heme protein oxygen affinity regulation exerted by proximal effectsQ80290047
Geometric and electronic structure studies of the binuclear nonheme ferrous active site of toluene-4-monooxygenase: parallels with methane monooxygenase and insight into the role of the effector proteins in O2 activationQ81274217
Mössbauer, electron paramagnetic resonance, and theoretical study of a high-spin, four-coordinate Fe(II) diketiminate complexQ81947002
Dioxygen affinity in heme proteins investigated by computer simulationQ82406122
Peroxo-type intermediates in class I ribonucleotide reductase and related binuclear non-heme iron enzymesQ84370303
P433issue25
P407language of work or nameEnglishQ1860
P921main subjectmethaneQ37129
P304page(s)4331-4342
P577publication date2013-06-13
P1433published inBiochemistryQ764876
P1476titleIntermediate P* from soluble methane monooxygenase contains a diferrous cluster
P478volume52

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cites work (P2860)
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Q35599145Structure of the key species in the enzymatic oxidation of methane to methanol
Q38749062Time-Resolved Investigations of Heterobimetallic Cofactor Assembly in R2lox Reveal Distinct Mn/Fe Intermediates.

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