Role of structure and pH in cyclization of allene oxide fatty acids: implications for the reaction mechanism

scientific article published in December 2002

Role of structure and pH in cyclization of allene oxide fatty acids: implications for the reaction mechanism is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1016/S0009-3084(02)00107-X
P698PubMed publication ID12426078

P50authorAlexander GrechkinQ21094361
P2093author name stringAlexander N Grechkin
Ivan R Chechetkin
Mats Hamberg
Lucia S Mukhtarova
P2860cites workNew cyclopentenone fatty acids formed from linoleic and linolenic acids in potatoQ31396611
Isolation and characterization of natural allene oxides: unstable intermediates in the metabolism of lipid hydroperoxidesQ33573375
Recent developments in biochemistry of the plant lipoxygenase pathway.Q33597615
A pathway for biosynthesis of divinyl ether fatty acids in green leavesQ34485342
Oxylipin pathway to jasmonates: biochemistry and biological significanceQ35461131
Formation of ketols from linolenic acid 13-hydroperoxide via allene oxide. Evidence for two distinct mechanisms of allene oxide hydrolysisQ45893136
Hydroperoxides of alpha-ketols. Novel products of the plant lipoxygenase pathwayQ67992755
Absolute configuration of cis-12-oxophytodienoic acid of flaxseed: implications for the mechanism of biosynthesis from the 13(S)-hydroperoxide of linolenic acidQ68284235
Allene oxide cyclase: a new enzyme in plant lipid metabolismQ68714103
Formation of 12-[18-O]oxo-cis-10, cis-15-phytodienoic acid from 13[18-O]hydroperoxylinolenic acid by hydroperoxide cyclaseQ71512828
Cyclization of natural allene oxide fatty acids. The anchimeric assistance of beta, gamma-double bond beside the oxirane and the reaction mechanismQ72046019
The lipoxygenase pathway in garlic (Allium sativum L.) bulbs: detection of the novel divinyl ether oxylipinsQ72052212
On the mechanism of biosynthesis of divinyl ether oxylipins by enzyme from garlic bulbsQ73291813
Formation of cyclopentenones from all-(E) hydroperoxides of linoleic acid via allene oxides. New insight into the mechanism of cyclizationQ73387588
Catalytic properties of allene oxide synthase from flaxseed (Linum usitatissimum L.).Q74326658
Substrate specificity for the synthesis of cyclic Fatty acids by a flaxseed extractQ83253137
Intermediacy of 8-(R)-HPETE in the conversion of arachidonic acid to pre-clavulone a by Clavularia viridis. Implications for the biosynthesis of marine prostanoidsQ105145204
P433issue1-2
P921main subjectfatty acidQ61476
P304page(s)87-99
P577publication date2002-12-01
P1433published inChemistry and Physics of LipidsQ15746139
P1476titleRole of structure and pH in cyclization of allene oxide fatty acids: implications for the reaction mechanism
P478volume120

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cites work (P2860)
Q27673332Crystal Structures of Physcomitrella patens AOC1 and AOC2: Insights into the Enzyme Mechanism and Differences in Substrate Specificity
Q36746538Investigation into 9(S)-HPODE-derived allene oxide to cyclopentenone cyclization mechanism via diradical oxyallyl intermediates
Q46660428The allene oxide cyclase family of Arabidopsis thaliana: localization and cyclization

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