Stereoinversion of tertiary alcohols to tertiary-alkyl isonitriles and amines

scientific article published in September 2013

Stereoinversion of tertiary alcohols to tertiary-alkyl isonitriles and amines is …
instance of (P31):
scholarly articleQ13442814

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P6179Dimensions Publication ID1024909026
P356DOI10.1038/NATURE12472
P698PubMed publication ID24025839
P5875ResearchGate publication ID256500722

P50authorRyan A. ShenviQ38319786
P2093author name stringSergey V Pronin
Christopher A Reiher
P2860cites workSynthesis of a potent antimalarial amphilectene.Q34645427
Marine isocyanides and related natural products--structure, biosynthesis and ecologyQ35708928
What is the stabilizing interaction with nucleophilic solvents in the transition state for solvolysis of tertiary derivatives: nucleophilic solvent participation or nucleophilic solvation?Q38439443
1,4,7-Trimethyloxatriquinane: SN2 Reaction at Tertiary CarbonQ44033938
Asymmetric alpha-alkylation of N'-tert-butanesulfinyl amidines. Application to the total synthesis of (6R,7S)-7-amino-7,8-dihydro-alpha-bisabolene.Q46107450
Synthesis of highly strained terpenes by non-stop tail-to-head polycyclizationQ46266383
Salt Effects and Ion Pairs in Solvolysis and Related Reactions. III.1 Common Ion Rate Depression and Exchange of Anions during AcetolysisQ55983409
Medicinal Natural ProductsQ56502446
Total synthesis and absolute configuration of 7,20-diisocyanoadocianeQ56658635
Walden Inversion and Reaction Mechanism: Walden Inversion in Unimolecular Reactions of Secondary and Tertiary Alkyl HalidesQ59093734
Walden Inversion and Reaction Mechanism: Walden Inversion in the Acid Hydrolysis of Carboxylic Esters by Unimolecular Alkyl FissionQ59093751
Diastereoselective Ritter reactions of chiral secondary benzylic alcoholsQ64218269
Total synthesis of (+/-)-kalihinol CQ79818492
Total synthesis of 10-isocyano-4-cadinene and determination of its absolute configurationQ82781181
Antimalarial activity of kalihinol A and new relative diterpenoids from the Okinawan sponge, Acanthella sp.Q105275358
P433issue7466
P407language of work or nameEnglishQ1860
P304page(s)195-199
P577publication date2013-09-01
P1433published inNatureQ180445
P1476titleStereoinversion of tertiary alcohols to tertiary-alkyl isonitriles and amines
P478volume501

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cites work (P2860)
Q45976871A Formal Enantiospecific Synthesis of 7,20-Diisocyanoadociane.
Q85243815A one-pot approach to pyridyl isothiocyanates from amines
Q40280443Antimalarial Properties of Simplified Kalihinol Analogues
Q48353833Asymmetric Synthesis of Less Accessible α-Tertiary Amines from Alkynyl Z-Ketimines
Q99634810Asymmetric Synthesis of Tertiary α -Hydroxyketones by Enantioselective Decarboxylative Chlorination and Subsequent Nucleophilic Substitution
Q57025577Asymmetric synthesis via stereospecific C-N and C-O bond activation of alkyl amine and alcohol derivatives
Q55254957Chirality sensing of tertiary alcohols by a novel strong hydrogen-bonding donor - selenourea.
Q57496659Diverse secondary C(sp)-H bond functionalization site-selective trifluoroacetoxylation of aliphatic amines
Q42123782Enantioselective decarboxylative chlorination of β-ketocarboxylic acids.
Q35733963Enantioselective synthesis of tertiary α-chloro esters by non-covalent catalysis
Q100552864Erratum: Corrigendum: Stereoinversion of tertiary alcohols to tertiary-alkyl isonitriles and amines
Q92832677Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst
Q35029999Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization
Q90579303Nucleophilic Isocyanation
Q41239639Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile
Q92803418Quantitative Ligand Affinity Scales for Metal Triflate Salts: Application to Isomer Differentiation
Q53225889SN 2 Reactions at Tertiary Carbon Centers in Epoxides.
Q89529930Scalable and Phosphine-Free Conversion of Alcohols to Carbon-Heteroatom Bonds through the Blue Light-Promoted Iodination Reaction
Q46623783Stereocontrolled Synthesis of Kalihinol C.
Q90401278Stereoinversion of Unactivated Alcohols by Tethered Sulfonamides
Q41169168Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity
Q35553153Syntheses and biological studies of marine terpenoids derived from inorganic cyanide.
Q40103003Synthesis and potent antimalarial activity of kalihinol B.
Q46651034Synthesis of (+)-7,20-Diisocyanoadociane and Liver-Stage Antiplasmodial Activity of the Isocyanoterpene Class
Q34171634Synthesis of medicinally relevant terpenes: reducing the cost and time of drug discovery
Q55259874Synthesis of the Privileged 8-Arylmenthol Class by Radical Arylation of Isopulegol.
Q54488684Tertiary alcohols as substrates for S(N)2-like stereoinversion.
Q53380965Williamson Ether Synthesis with Phenols at a Tertiary Stereogenic Carbon: Formal Enantioselective Phenoxylation of β-Keto Esters.

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