Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor

scientific article published on 10 November 2016

Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1002/ANIE.201608806
P698PubMed publication ID27862765

P50authorYasuhiro OhkiQ42933043
P2093author name stringKazuyuki Tatsumi
Chi Chung Lee
Markus W Ribbe
Yilin Hu
Takayuki Nagasawa
Kazuki Tanifuji
Kosuke Miyazaki
Nathaniel Sickerman
P2860cites workA sulfido-bridged diiron(II) compound and its reactions with nitrogenase-relevant substratesQ44834565
ENDOR characterization of a synthetic diiron hydrazido complex as a model for nitrogenase intermediatesQ46841849
Mechanism of nitrogen fixation by nitrogenase: the next stageQ26828626
Evidence for Interstitial Carbon in Nitrogenase FeMo CofactorQ27675640
A Sulfide-Bridged Diiron(II) Complex with a cis-N2H4LigandQ28468643
Mechanism of Molybdenum NitrogenaseQ34114433
Characterization of isolated nitrogenase FeVcoQ34131445
Isolation of an iron-molybdenum cofactor from nitrogenaseQ35042673
Extending the carbon chain: hydrocarbon formation catalyzed by vanadium/molybdenum nitrogenasesQ35156302
N2 functionalization at iron metallaboratranesQ35539828
Binding of dinitrogen to an iron-sulfur-carbon siteQ36119351
Structural basis of biological nitrogen fixationQ36131620
Uncoupling binding of substrate CO from turnover by vanadium nitrogenaseQ36300368
Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco).Q37218477
X-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactorQ37239903
Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clustersQ37696184
Catalytic reduction of CN-, CO, and CO2 by nitrogenase cofactors in lanthanide-driven reactionsQ41763818
Ligand binding to the FeMo-cofactor: structures of CO-bound and reactivated nitrogenaseQ41864738
Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchorQ41948280
Diiron bridged-thiolate complexes that bind N2 at the Fe(II)Fe(II), Fe(II)Fe(I), and Fe(I)Fe(I) redox statesQ41971319
ATP-independent formation of hydrocarbons catalyzed by isolated nitrogenase cofactorsQ42396707
Insights into hydrocarbon formation by nitrogenase cofactor homologsQ42746733
Synthesis, structures, and electronic properties of [8Fe-7S] cluster complexes modeling the nitrogenase P-cluster.Q43289097
High-nuclearity sulfide-rich molybdenum[bond]iron[bond]sulfur clusters: reevaluation and extensionQ44021325
P433issue50
P407language of work or nameEnglishQ1860
P304page(s)15633-15636
P577publication date2016-11-10
P1433published inAngewandte Chemie International EditionQ62023953
P1476titleStructure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor
P478volume55

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cites work (P2860)
Q88199897A Thermodynamic Model for Redox-Dependent Binding of Carbon Monoxide at Site-Differentiated, High Spin Iron Clusters
Q39330178Activation of CO2 by Vanadium Nitrogenase
Q58790942N activation on a molybdenum-titanium-sulfur cluster
Q47323684Nitrogen Reduction to Ammonia on a Biomimetic Mononuclear Iron Centre: Insights into the Nitrogenase Enzyme
Q90703658Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity
Q90031127Reactivity, Mechanism, and Assembly of the Alternative Nitrogenases
Q46339342Synthesis and Characterization of Bioinspired [Mo2 Fe2 ]-Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2.
Q45940874Synthetic Analogues of Nitrogenase Metallocofactors: Challenges and Developments.