Stereodefined acyclic trisubstituted metal enolates towards the asymmetric formation of quaternary carbon stereocentres

scientific article published in October 2014

Stereodefined acyclic trisubstituted metal enolates towards the asymmetric formation of quaternary carbon stereocentres is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1039/C4CC04391J
P698PubMed publication ID25054432

P50authorYury MinkoQ85274437
P2093author name stringIlan Marek
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All-carbon quaternary stereogenic centers in acyclic systems through the creation of several C-C bonds per chemical stepQ46933855
Stereoselective generation of E- and Z-disubstituted amide enolates. Reductive enolate formation from bicyclic thioglycolate lactamsQ49308700
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Stereoselective formation of alpha-quaternary stereocenters in the Mannich reaction.Q53401516
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The Stereochemistry of the Ivanov and Reformatsky Reactions. IQ56288425
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Stereochemical control in the ester enolate Claisen rearrangement. 1. Stereoselectivity in silyl ketene acetal formationQ56288430
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Forming all-carbon quaternary stereogenic centres in acyclic systems from alkynesQ59070002
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Generation of stereochemically defined tetrasubstituted enolborinates by 1,4-hydroboration of α,β-unsaturated morpholine carboxamides with (diisopinocampheyl)boraneQ37542796
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Regio- and stereoselective carbometallation reactions of N-alkynylamides and sulfonamidesQ39908226
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A simple, scalable synthetic route to (+)- and (-)-pseudoephenamineQ41972325
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Pseudoephenamine: a practical chiral auxiliary for asymmetric synthesisQ42708042
A unique approach to aldol products for the creation of all-carbon quaternary stereocentresQ42747316
P433issue84
P407language of work or nameEnglishQ1860
P304page(s)12597-12611
P577publication date2014-10-01
P1433published inChemical CommunicationsQ426303
P1476titleStereodefined acyclic trisubstituted metal enolates towards the asymmetric formation of quaternary carbon stereocentres
P478volume50

Reverse relations

cites work (P2860)
Q48346593Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis.
Q58610670Allenoates in Enantioselective [2+2] Cycloadditions: From a Mechanistic Curiosity to a Stereospecific Transformation
Q90510939Catalytic Enantioselective Synthesis of Acyclic Quaternary Centers: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Acyclic Enol Carbonates
Q41594809Chiral ammonium betaine-catalyzed asymmetric Mannich-type reaction of oxindoles
Q89893012Cu-Catalyzed Diastereo- and Enantioselective Reactions of γ,γ-Disubstituted Allyldiboron Compounds with Ketones
Q64174733Cyclometalated Iridium-PhanePhos Complexes Are Active Catalysts in Enantioselective Allene-Fluoral Reductive Coupling and Related Alcohol-Mediated Carbonyl Additions That Form Acyclic Quaternary Carbon Stereocenters
Q48107967Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer
Q46642667Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.
Q42732697Enantioselective Formation of All-Carbon Quaternary Centers via C-H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation
Q48294382Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation
Q41833646Enantioselective allylic alkylation of stereodefined polysubstituted copper enolates as an entry to acyclic quaternary carbon stereocentres
Q92278178Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates
Q47100392Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol

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