Covalent hypercoordination: can carbon bind five methyl ligands?

scientific article published on 10 June 2014

Covalent hypercoordination: can carbon bind five methyl ligands? is …
instance of (P31):
scholarly articleQ13442814

External links are
P356DOI10.1002/ANIE.201403314
P698PubMed publication ID24917212

P2093author name stringHenry F Schaefer
Jay Agarwal
Paul von R Schleyer
William C McKee
P2860cites workX-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactorQ37239903
Prospecting for a 5-center 4-electron (C- - -H- - -C- - -H- - -C)+ bonding arrayQ44386720
Syntheses and structures of hypervalent pentacoordinate carbon and boron compounds bearing an anthracene skeleton--elucidation of hypervalent interaction based on X-ray analysis and DFT calculationQ46397326
Hexa- and octacoordinate carbon in hydrocarbon cages: theoretical design and characterization.Q46954977
Hypervalent silicon versus carbon: ball-in-a-box model.Q51624318
The Bonding of Trihalide and Bifluoride Ions by the Molecular Orbital MethodQ54033742
Hypervalent Carbon Atom: “Freezing” the SN2 Transition StateQ56433092
Pyramidal mono- and dications. Bridge between organic and organometallic chemistryQ56554438
Nature of the (CH)5+ species. II. Direct observation of the carbonium ion of 3-hydroxyhomotetrahedrane derivativesQ56554688
Effectively hypervalent molecules. 2. Lithium carbide (CLi5), lithium carbide (CLi6), and the related effectively hypervalent first row molecules, CLi5-nHn and CLi6-nHnQ56832901
Lithiated carbocations. The generation, structure, and stability of CLi5+Q56832923
Observation of hypervalent CLi6 by Knudsen-effusion mass spectrometryQ56836203
The rational design of helium bondsQ56973566
Overcoming lability of extremely long alkane carbon–carbon bonds through dispersion forcesQ57742709
P433issue30
P407language of work or nameEnglishQ1860
P1104number of pages4
P304page(s)7875-7878
P577publication date2014-06-10
P1433published inAngewandte Chemie International EditionQ62023953
P1476titleCovalent hypercoordination: can carbon bind five methyl ligands?
P478volume53