Unnatural Amino Acid Synthesis Enabled by the Regioselective Cobalt(III)-Catalyzed Intermolecular Carboamination of Alkenes

scientific article published on 27 October 2016

Unnatural Amino Acid Synthesis Enabled by the Regioselective Cobalt(III)-Catalyzed Intermolecular Carboamination of Alkenes is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1002/ANIE.201608729
P698PubMed publication ID27785863

P50authorFrank GloriusQ18020215
Constantin G. DaniliucQ41393857
P2093author name stringAndreas Lerchen
Tobias Knecht
P2860cites workRecent advances in homogeneous nickel catalysisQ26994718
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Metal-catalysed 1,2-diamination reactionsQ39967149
Stereoselective synthesis of cis- or trans-3,5-disubstituted pyrazolidines via Pd-catalyzed carboamination reactions: use of allylic strain to control product stereochemistry through N-substituent manipulationQ41824042
Enantioselective Synthesis of Tetrahydroquinolines, Tetrahydroquinoxalines, and Tetrahydroisoquinolines via Pd-Catalyzed Alkene Carboamination ReactionsQ41891315
Rh(III)-catalyzed cyclopropanation initiated by C-H activation: ligand development enables a diastereoselective [2 + 1] annulation of N-enoxyphthalimides and alkenesQ42054408
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Highly Stereoselective Cobalt(III)-Catalyzed Three-Component C-H Bond Addition CascadeQ42390534
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Asymmetric Pd-Catalyzed Alkene Carboamination Reactions for the Synthesis of 2-Aminoindane DerivativesQ42430306
Intramolecular Pd-catalyzed carboetherification and carboamination. Influence of catalyst structure on reaction mechanism and product stereochemistryQ42564495
Intramolecular alkene aminopalladation reactions of (dppf)Pd(Ar)[N(Ar(1))(CH(2))(3)CH=CH(2)] complexes. insertion of unactivated alkenes into Pd-N bondsQ43096737
Distinct reactivity of Pd(OTs)2: the intermolecular Pd(II)-catalyzed 1,2-carboamination of dienesQ43139123
Rhodium-catalysed syn-carboamination of alkenes via a transient directing groupQ43184824
A cationic high-valent Cp*Co(III) complex for the catalytic generation of nucleophilic organometallic species: directed C-H bond activationQ43791456
Palladium-catalyzed carboamination of alkenes promoted by N-fluorobenzenesulfonimide via C-H activation of arenes.Q45958878
On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexesQ46145223
Carboxylate-assisted ruthenium-catalyzed alkyne annulations by C-H/Het-H bond functionalizationsQ46236096
Homogeneous gold-catalyzed oxidative carboheterofunctionalization of alkenesQ46399577
Rhodium(III)-catalyzed cyclative capture approach to diverse 1-aminoindoline derivatives at room temperatureQ46798369
Pyrroloindolone synthesis via a Cp*Co(III)-catalyzed redox-neutral directed C-H alkenylation/annulation sequenceQ46916473
Low-valent cobalt catalysis: new opportunities for C-H functionalizationQ46926603
Pd(II)-catalyzed enantioselective oxidative tandem cyclization reactions. Synthesis of indolines through C-N and C-C bond formationQ46979182
Overcoming the Limitations of C-H Activation with Strongly Coordinating N-Heterocycles by Cobalt CatalysisQ48150027
Cobalt-Catalyzed C-H Thiolation through Dehydrogenative Cross-CouplingQ48152674
Cobalt(III)-Catalyzed Redox-Neutral Synthesis of Unprotected Indoles Featuring an N-N Bond CleavageQ48248981
An Umpolung Approach to Alkene Carboamination: Palladium Catalyzed 1,2-Amino-Acylation, -Carboxylation, -Arylation, -Vinylation, and -Alkynylation.Q50971481
Synthesis of pyrrolidines via palladium(II)-catalyzed aerobic oxidative carboamination of butyl vinyl ether and styrenes with allyl tosylamides.Q51178082
Low-valent iron-catalyzed C-C bond formation-addition, substitution, and C-H bond activation.Q51629326
Cobalt(III)-Catalyzed C-H/N-O Functionalizations: Isohypsic Access to Isoquinolines.Q52913221
Oxidative coupling of aromatic substrates with alkynes and alkenes under rhodium catalysis.Q53304057
Cobalt(III)-Catalyzed Dehydrative [4+2] Annulation of Oxime with Alkyne by C-H and N-OH Activation.Q53516963
Mild C-H/C-C Activation by Z-Selective Cobalt Catalysis.Q54503355
Catalytic Asymmetric DihydroxylationQ55877980
Cobaltkatalysierte C-H-Thiolierung durch dehydrierende KreuzkupplungQ57657005
Cooperative Lewis Acid/Cp*CoIIICatalyzed C−H Bond Activation for the Synthesis of Isoquinolin-3-onesQ57657028
P433issue48
P407language of work or nameEnglishQ1860
P921main subjectcobaltQ740
P304page(s)15166-15170
P577publication date2016-10-27
P1433published inAngewandte Chemie International EditionQ62023953
P1476titleUnnatural Amino Acid Synthesis Enabled by the Regioselective Cobalt(III)-Catalyzed Intermolecular Carboamination of Alkenes
P478volume55

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cites work (P2860)
Q48295018A General Cp*CoIII -Catalyzed Intramolecular C-H Activation Approach for the Efficient Total Syntheses of Aromathecin, Protoberberine, and Tylophora Alkaloids.
Q46409049C-H functionalization by high-valent Cp*Co(iii) catalysis.
Q46355469Capturing Elusive Cobaltacycle Intermediates: A Real-Time Snapshot of the Cp*CoIII -Catalyzed Oxidative Alkyne Annulation.
Q90142670Carboamination of Unactivated Alkenes through Three-Component Radical Conjugate Addition
Q53293744Cp*CoIII-catalyzed directed C-H trifluoromethylthiolation of 2-phenylpyridines and 6-arylpurines.
Q48245200Full Selectivity Control in Cobalt(III)-Catalyzed C-H Alkylations by Switching of the C-H Activation Mechanism
Q58656139Full Selectivity Control in Cobalt(III)-Catalyzed C−H Alkylations by Switching of the C−H Activation Mechanism
Q60912755Iron-catalyzed carboazidation of alkenes and alkynes
Q48256474Isolation of Cp*CoIII -Alkenyl Intermediate in Efficient Cobalt-Catalyzed C-H Alkenylation with Alkynes.
Q64266976Perfluoroalkylative pyridylation of alkenes 4-cyanopyridine-boryl radicals
Q91639269Photosensitized Intermolecular Carboimination of Alkenes through the Persistent Radical Effect
Q53189208Recent advances using [Cp*Co(CO)I2] catalysts as a powerful tool for C-H functionalisation.
Q46377311Rhodium(III)-Catalyzed Annulative Carbooxygenation of 1,1-Disubstituted Alkenes Triggered by C-H Activation.

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