Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes.

scientific article published on 22 December 2017

Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes. is …
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scholarly articleQ13442814

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P819ADS bibcode2017NatCo...8.2258W
P356DOI10.1038/S41467-017-02382-7
P8608Fatcat IDrelease_vxf6hcmifbfwrod7d7m4iyfhie
P932PMC publication ID5741631
P698PubMed publication ID29273720

P50authorShaozhong GeQ87934624
Chao WangQ88194863
Wei Jie TeoQ88796898
P2093author name stringChao Wang
Shaozhong Ge
Wei Jie Teo
P2860cites workRegioselective allene hydroarylation via one-pot allene hydrosilylation/Pd-catalyzed cross-couplingQ34361012
Endo-selective Pd-catalyzed silyl methyl Heck reactionQ34926965
General and practical one-pot synthesis of dihydrobenzosiloles from styrenesQ36036199
Remote control of diastereoselectivity in intramolecular reactions of chiral allylsilanes.Q36846623
Regioselective allene hydrosilylation catalyzed by N-heterocyclic carbene complexes of nickel and palladiumQ37338903
One-pot multicomponent coupling methods for the synthesis of diastereo- and enantioenriched (Z)-trisubstituted allylic alcoholsQ37359306
Regio- and stereoselective Ni-catalyzed 1,4-hydroboration of 1,3-dienes: access to stereodefined (Z)-allylboron reagents and derived allylic alcoholsQ40157465
Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activationQ41986987
Anchoring of silyl donors on a N-heterocyclic carbene through the cobalt-mediated silylation of benzylic C-H bondsQ43486414
Stereoselective synthesis of tetrahydrofurans via formal [3+2]-cycloaddition of aldehydes and allylsilanes. Formal total synthesis of the muscarine alkaloids (-)-allomuscarine and (+)-epimuscarineQ43944550
Stereoselective synthesis of highly enantioenriched (E)-allylsilanes by palladium-catalyzed intramolecular bis-silylation: 1,3-chirality transfer and enantioenrichment via dimer formationQ45297037
Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes.Q46427801
Activation and discovery of earth-abundant metal catalysts using sodium tert-butoxideQ48108131
Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of AlkynesQ48150017
Cobalt-Catalyzed Z-Selective Hydrosilylation of Terminal Alkynes.Q48154998
Regio- and Enantioselective Cobalt-Catalyzed Sequential Hydrosilylation/Hydrogenation of Terminal AlkynesQ48188601
Cobalt-Catalyzed Asymmetric Hydroboration/Cyclization of 1,6-Enynes with Pinacolborane.Q48223336
Unified Total Synthesis of Madangamines A, C, and E.Q48249583
Highly efficient regioselective hydrosilylation of allenes using a [(3IP)Pd(allyl)]OTf catalyst; first example of allene hydrosilylation with phenyl- and diphenylsilane.Q50438450
Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes.Q51564352
Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity.Q52984119
σ-Bond Metathesis: A 30-Year RetrospectiveQ56058517
High-value alcohols and higher-oxidation-state compounds by catalytic Z-selective cross-metathesisQ59051475
Ligand-Controlled Highly Stereoselective Syntheses ofE- andZ-Allylsilanes from Dienes and Aldehydes Using Nickel ComplexQ61988592
Stereochemical Control in Organic Synthesis Using Silicon-Containing CompoundsQ77646602
Selective and efficient platinum(0)-carbene complexes as hydrosilylation catalystsQ78329784
A one-pot multicomponent coupling reaction for the stereocontrolled synthesis of (Z)-trisubstituted allylic alcoholsQ79814225
Regiodivergent and Stereoselective Hydrosilylation of 1,3-Disubstituted AllenesQ85386835
Ligandless Regioselective Hydrosilylation of Allenes Catalyzed by Gold NanoparticlesQ86052928
Regio- and stereoselective hydrosilylation of alkynes catalyzed by three-coordinate cobalt(I) alkyl and silyl complexesQ86061923
Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt CatalystQ86410065
Rhodium(II)-catalyzed stereoselective synthesis of allylsilanesQ86856634
Z-selective alkene isomerization by high-spin cobalt(II) complexesQ87029745
Broadly applicable Z- and diastereoselective ring-opening/cross-metathesis catalyzed by a dithiolate ru complexQ87185844
Rhodium-Catalyzed Hydroformylation of 1,1-Disubstituted Allenes Employing the Self-Assembling 6-DPPon SystemQ87198138
Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt CatalystQ88183568
P275copyright licenseCreative Commons Attribution 4.0 InternationalQ20007257
P6216copyright statuscopyrightedQ50423863
P433issue1
P407language of work or nameEnglishQ1860
P921main subjectcobaltQ740
P304page(s)2258
P577publication date2017-12-22
P1433published inNature CommunicationsQ573880
P1476titleAccess to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes
P478volume8

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cites work (P2860)
Q58565307A β-diketiminate manganese catalyst for alkene hydrosilylation: substrate scope, silicone preparation, and mechanistic insight
Q64231392Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions
Q48200831Cobalt-Catalyzed Diborylation of 1,1-disubstituted Vinylarenes: A Practical Route to Branched gem-Bis(boryl)alkanes.

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