A Systematic Study of Structure and E-H Bond Activation Chemistry by Sterically Encumbered Germylene Complexes.

scientific article published on 6 July 2016

A Systematic Study of Structure and E-H Bond Activation Chemistry by Sterically Encumbered Germylene Complexes. is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1002/CHEM.201601840
P8608Fatcat IDrelease_d2okz5nsmfg7rlej33x3ngcupa
P698PubMed publication ID27381647

P50authorJesus CamposQ57631421
Arnab RitQ83178462
Eugene L KolychevQ83424983
Simon AldridgeQ88085319
P2093author name stringAndrey V Protchenko
Rémi Tirfoin
Matthew Usher
P2860cites workDensity-functional exchange-energy approximation with correct asymptotic behaviorQ21709057
Processing of X-ray diffraction data collected in oscillation modeQ26778468
Density-functional approximation for the correlation energy of the inhomogeneous electron gasQ27440259
An Appraisal of Valence-bond Structures and Hybridization in Compounds of the First-row elements.Q29028801
Boryllithium: isolation, characterization, and reactivity as a boryl anionQ31064800
Solution synthesis of germanium nanowires using a Ge2+ alkoxide precursorQ36882113
Frustrated Lewis pair chemistry: development and perspectivesQ38479992
Stable singlet carbenes as mimics for transition metal centers.Q41771662
Synthesis and structural characterization of a series of dimeric metal(II) imido complexes {M(mu-NAr(#))}2 [M = Ge, Sn, Pb; Ar(#) = C6H3-2,6-(C6H2-2,4,6-Me3)2] and the related monomeric primary amido derivatives M{N(H)Ar(#)}2 (M = Ge, Sn, Pb): spectQ42992453
Activation of gaseous PH3 with low coordinate diaryltetrylene compoundsQ43527384
Synthesis and properties of a germanium(II) metalloheterocycle derived from 1,8-di(isopropylamino)naphthalene. A novel ligand leading to formation of Ni[Ge[((i)PrN)(2)C(10)H(6)]]4).Q43791800
Bis(tri-tert-butylsilyl)silylene: Triplet Ground State SilyleneQ44412485
EH3 (E = N, P, As) and H2 activation with N-heterocyclic silylene and germylene homologuesQ45079851
Formation and structures of germanium(II) Aryloxo/oxo clusters.Q45925077
Main-group elements as transition metals.Q45972195
Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center.Q46007374
Room-temperature reaction of carbon monoxide with a stable diarylgermylene.Q46026743
Dispersion forces and counterintuitive steric effects in main group molecules: heavier group 14 (Si-Pb) dichalcogenolate carbene analogues with sub-90° interligand bond anglesQ46067178
C-H activation of cycloalkenes by dimetallynes (M = Ge, Sn) under ambient conditions.Q46091381
Reaction of hydrogen or ammonia with unsaturated germanium or tin molecules under ambient conditions: oxidative addition versus arene elimination.Q46138221
Cleavage of a N-H bond of ammonia at room temperature by a germyleneQ46178630
Reaction of a germylene, stannylene, or plumbylene with trimethylaluminum and trimethylgallium: insertion into Al-C or ga-C bonds, a reversible metal-carbon insertion equilibrium, and a new route to diplumbenes.Q46251345
Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E-H Bonds by a Bis(boryl)stannyleneQ46579227
A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilyleneQ46629627
Multiple bonding in heavier element compounds stabilized by bulky terphenyl ligandsQ46705572
Interaction of multiple bonded and unsaturated heavier main group compounds with hydrogen, ammonia, olefins, and related moleculesQ46726138
Different reactivity of the heavier group 14 element alkyne analogues Ar'MMAr' (M = Ge, Sn; Ar' = C6H3-2,6(C6H3-2,6-Pri2)2) with R2NO.Q46761902
The transfer of tin and germanium atoms from N-heterocyclic stannylenes and germylenes to diazadienesQ46775457
Stabilization of a diphosphagermylene through pπ-pπ interactions with a trigonal-planar phosphorus centerQ46924488
Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride.Q52880424
A heterofulvene-like germylene with a betain reactivity.Q52932448
Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes.Q55026316
Stable Heavier Carbene AnaloguesQ56592634
Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermyleneQ56592635
Ligand-Protected Strain-Free Diarylgermylenes†Q56592636
Synthesis and Characterization of the Monomeric Sterically Encumbered Diaryls E{C6H3-2,6-(C6H3-2,6-Pri2)2}2 (E = Ge, Sn, or Pb)Q56592638
Activation of H2by a Multiply Bonded Amido-Digermyne: Evidence for the Formation of a Hydrido-GermyleneQ56592692
Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl CompoundsQ56592698
Synthesis of the bulky m-terphenyl phenol Ar*OH (Ar* = C6H3-2,6-Mes2, Mes = 2,4,6-trimethylphenyl) and the preparation and structural characterization of several of its metal complexesQ56936827
Bivalent germanium, tin, and lead 2,6-di-tert-butylphenoxides and the crystal and molecular structures of M(OC6H2Me-4-But2-2,6)2 (M = Ge or Sn)Q57088266
Influence of Ligand Modifications on Structural and Spectroscopic Properties in Terphenyl Based Heavier Group 14 Carbene HomologuesQ57713526
Synthese und Struktur des Disilagermirans R2Ge(SiR2)2 und des solvensseparierten Ionenpaares [Li([12]Krone-4)2][GeR3]; R = SiMe3Q57906426
Synthesis and Structure of the Disilagermirane R2Ge(SiR2)2 and the Solvent-Separated Ion Pair [Li([12]crown-4)2][GeR3]; (R = SiMe3)Q57906430
Hypervalent Sulfur-Functionalized Diphosphagermylene and Diphosphastannylene CompoundsQ57966753
P433issue33
P407language of work or nameEnglishQ1860
P304page(s)11685-11698
P577publication date2016-07-06
P1433published inChemistry—A European JournalQ898737
P1476titleA Systematic Study of Structure and E-H Bond Activation Chemistry by Sterically Encumbered Germylene Complexes.
P478volume22

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cites work (P2860)
Q33744984A Fully Phosphane-Substituted Disilene.
Q48217397A Germylene Stabilized by Homoconjugation.
Q64274236Acyclic 1,2-dimagnesioethanes/-ethene derived from magnesium(i) compounds: multipurpose reagents for organometallic synthesis
Q50040395An acyclic zincagermylene: rapid activation of dihydrogen at sub-ambient temperature.
Q48183754Diverse Activation Modes in the Hydroboration of Aldehydes and Ketones with Germanium, Tin, and Lead Lewis Pairs.
Q53836042Exceptionally Strong Electron-Donating Ability of Bora-Ylide Substituent vis-à-vis Silylene and Silylium Ion.
Q64907907Isolation of a Diylide-Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment.
Q46501101Ligand coordination modulates reductive elimination from aluminium(iii).
Q48358929Lithium Hexamethyldisilazide-Mediated Enolization of Acylated Oxazolidinones: Solvent, Cosolvent, and Isotope Effects on Competing Monomer- and Dimer-Based Pathways.
Q46441836N,P-Heterocyclic Germylene/B(C6 F5 )3 Adducts: A Lewis Pair with Multi-reactive Sites
Q48341771Reductive Dehydrogenation of a Stannane via Multiple Sn-H Activation by Frustrated Lewis Pairs
Q48179089Silylene-Nickel Promoted Cleavage of B-O Bonds: From Catechol Borane to the Hydroborylene Ligand
Q54511713Using N-Heterocyclic Vinyl Ligands to Access Stable Divinylgermylenes and a Germylium Cation.

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