syn-Selective crotylation of aldehydes using bismuth-crotyl bromide-(1-butyl-3-methylimidazolium bromide) combination: some synthetic applications.

scientific article

syn-Selective crotylation of aldehydes using bismuth-crotyl bromide-(1-butyl-3-methylimidazolium bromide) combination: some synthetic applications. is …
instance of (P31):
scholarly articleQ13442814

External links are
P356DOI10.1039/C7OB00626H
P698PubMed publication ID28406519

P2093author name stringSubrata Chattopadhyay
Anubha Sharma
Dibakar Goswami
Mrunesh R Koli
Sucheta Chatterjee
P2860cites workEnantioselective synthesis of (+)-cryptophycin 52 (LY355703), a potent antimitotic antitumor agentQ44680172
A convenient procedure for bismuth-mediated Barbier-type allylation of aldehydes in water containing fluoride ionsQ44790928
Direct preparation of allylic indium(III) reagents from allylic alcohols via a reductive transmetalation of pi-allylnickel(II) with indium(I) iodideQ44979983
A general model for selectivity in olefin cross metathesisQ46097320
Metal-dependent reaction tuning with cyclopentylmetal reagents: application to the asymmetric synthesis of (+)-alpha-conhydrine and (S)-2-cyclopentyl-2-phenylglycolic acidQ46171235
Developmental and genetic toxicity of stannous chloride in mouse dams and fetusesQ46376208
Nanoclusters in ionic liquids: evidence for N-heterocyclic carbene formation from imidazolium-based ionic liquids detected by (2)H NMR.Q46444936
Efficient allylation of aldehydes promoted by carboxylic acidsQ46498518
Asymmetric allyl- and crotylboration with the robust, versatile, and recyclable 10-TMS-9-borabicyclo[3.3.2]decanesQ46519594
Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromidesQ50223366
[bmim][Br] as a solvent and activator for the Ga-mediated Barbier allylation: direct formation of an N-heterocyclic carbene from Ga metal.Q50487340
Total Synthesis of Cryptophycins and Their 16-(3-Phenylacryloyl) Derivatives.Q50535945
Mechanism of scandium ion catalyzed Diels-Alder reaction of anthracenes with methyl vinyl ketone.Q51165706
Gallium-mediated allyl transfer from bulky homoallylic alcohol to aldehydes via retro-allylation: stereoselective synthesis of both erythro- and threo-homoallylic alcohols.Q51387502
Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and KetonesQ56431040
The Utility of Phosphonate Carbanions in Olefin SynthesisQ56833459
Cyclopropanes from an Easily Prepared, Highly Active Zinc—Copper Couple, Dibromomethane, and OlefinsQ56834107
The Bis(allyl)bismuth Cation: A Reagent for Direct Allyl Transfer by Lewis Acid Activation and Controlled Radical PolymerizationQ57903842
Microwave-Assisted and Yb(OTf)3-Promoted One-Pot Multicomponent Synthesis of Substituted Quinolines in Ionic LiquidQ58200812
Towards solvent-controlled reactivity in ionic liquidsQ58309492
Toxicity and health effects of selected organotin compounds: a reviewQ24547732
Pharmaceuticals from cultured algaeQ29011395
Highly Selective Synthesis of Z -Unsaturated Esters by Using New Horner−Emmons Reagents, Ethyl (Diarylphosphono)acetatesQ29038084
Olefin Metathesis and BeyondQ29999051
Catalytic asymmetric organozinc additions to carbonyl compoundsQ30308277
Development of a highly alpha-regioselective metal-mediated allylation reaction in aqueous media: new mechanistic proposal for the origin of alpha-homoallylic alcoholsQ30773896
Structures of ionic liquid-water mixtures investigated by IR and NMR spectroscopyQ30799654
Asymmetric crotylation reactions in synthesis of polypropionate-derived macrolides: application to total synthesis of oleandolideQ30865499
Scandium ion-promoted photoinduced electron-transfer oxidation of fullerenes and derivatives by p-chloranil and p-benzoquinone.Q31032428
Total synthesis of cryptophycin-24 (Arenastatin A) amenable to structural modifications in the C16 side chainQ31551842
The mechanism and an improved asymmetric allylboration of ketones catalyzed by chiral biphenolsQ33509550
The development of L2X2Ru=CHR olefin metathesis catalysts: an organometallic success storyQ33932697
Room-Temperature Ionic Liquids. Solvents for Synthesis and CatalysisQ34114471
Total synthesis of (-)-dictyostatin: confirmation of relative and absolute configurationsQ34341911
Ionic Liquids-New "Solutions" for Transition Metal CatalysisQ34512009
The cryptophycins: their synthesis and anticancer activityQ34540048
Synthesis and biological evaluation of (-)-dictyostatin and stereoisomersQ36025482
Enantioselective C-H crotylation of primary alcohols via hydrohydroxyalkylation of butadieneQ36226256
Recent approaches for the synthesis of modified cryptophycinsQ38111652
Vinylogous aldol products from chiral crotylsilanes obtained by enantioselective Rh(II) and Cu(I) carbenoid Si-H insertionQ38273604
Iridium Catalyzed Hydro-hydroxyalkylation of Butadiene: Carbonyl CrotylationQ41146779
Diastereo- and enantioselective ruthenium-catalyzed hydrohydroxyalkylation of 2-silyl-butadienes: carbonyl syn-crotylation from the alcohol oxidation levelQ42789846
Ambiphilic Dual Activation Role of a Task-Specific Ionic Liquid: 2-Hydroxyethylammonium Formate as a Recyclable Promoter and Medium for the Green Synthesis of β-NitrostyrenesQ42837818
Tubulin polymerizing activity of dictyostatin-1, a polyketide of marine sponge originQ43305329
Enantiospecific Total Synthesis of the Potent Antitumor Macrolides Cryptophycins 1 and 8.Q43634653
Basicity of a stable carbene, 1,3-di-tert-butylimidazol-2-ylidene, in THF.Q43993010
Synthesis of natural fragrant molecules cis-3-methyl-4-decanolide and aerangis lactone. General enantioselective routes to beta,gamma-cis-disubstituted gamma-lactones and gamma,delta-cis-disubstituted delta-lactones.Q44004168
Acceleration effect of Lewis acid in allylboration of aldehydes: catalytic, regiospecific, diastereospecific, and enantioselective synthesis of homoallyl alcoholsQ44180239
Stereochemistry of the allylation and crotylation reactions of alpha-methyl-beta-hydroxy aldehydes with allyl- and crotyltrifluorosilanes. Synthesis of anti,anti-dipropionate stereotriads and stereodivergent pathways for the reactions with 2,3-anti-Q44314415
An improved methodology for the synthesis of enantiomerically pure (S)-2,3-O-cyclohexylideneglyceraldehydeQ44365998
Scandium-catalyzed allylboration of aldehydes as a practical method for highly diastereo- and enantioselective construction of homoallylic alcoholsQ44554745
Noticeable facilitation of the bismuth-mediated Barbier-type allylation of aromatic carbonyl compounds under solvent-free conditionsQ44566910
Control of diastereoselectivity in the crotylation and cinnamylation of aldehydes by the selection of ligands on allylic indium reagentsQ44676452
New Lewis-basic N-oxides as chiral organocatalysts in asymmetric allylation of aldehydesQ44680116
P433issue17
P304page(s)3756-3774
P577publication date2017-05-01
P1433published inOrganic and Biomolecular ChemistryQ3355939
P1476titlesyn-Selective crotylation of aldehydes using bismuth-crotyl bromide-(1-butyl-3-methylimidazolium bromide) combination: some synthetic applications.
P478volume15

Reverse relations

cites work (P2860)
Q92997325Application of chiral 2-isoxazoline for the synthesis of syn-1,3-diol analogs
Q58718854Bi-mediated allylation of aldehydes in [bmim][Br]: a mechanistic investigation

Search more.