Resolution of RacemicN-Benzyl α-Amino Acids by Liquid-Liquid Extraction: A Practical Method Using a Lipophilic Chiral Cobalt(III) Salen Complex and Mechanistic Studies

scholarly article by Pawel Dzygiel et al published March 2008 in European Journal of Organic Chemistry

Resolution of RacemicN-Benzyl α-Amino Acids by Liquid-Liquid Extraction: A Practical Method Using a Lipophilic Chiral Cobalt(III) Salen Complex and Mechanistic Studies is …
instance of (P31):
scholarly articleQ13442814

External links are
P356DOI10.1002/EJOC.200701101

P50authorCesare GennariQ38544575
Umberto PiarulliQ42741758
P2093author name stringIgor Tvaroska
Pawel Dzygiel
Martin Krupicka
Toby B. Reeve
P2860cites workEnantiomeric Recognition of Amine Compounds by Chiral Macrocyclic ReceptorsQ77651558
Lipases: Interfacial Enzymes with Attractive ApplicationsQ88520762
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Separation of amino acid enantiomers by micelle-enhanced ultrafiltrationQ31407553
Enzymatic resolution of amino acids via ester hydrolysisQ33683228
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Preparative chiral chromatographic resolution of enantiomers in drug discoveryQ35051394
Highly selective hydrolytic kinetic resolution of terminal epoxides catalyzed by chiral (salen)Co(III) complexes. Practical synthesis of enantioenriched terminal epoxides and 1,2-diolsQ43883623
Enantioselective transport by a steroidal guanidinium receptor.Q44254025
Kinetics and Mechanism of the Cobalt Phthalocyanine Catalyzed Reduction of Nitrite and Nitrate by Dithionite in Aqueous SolutionQ44401973
Guanidinium receptors as enantioselective amino acid membrane carriersQ44498829
A cobalt(III)-salen complex with an axial substituent in the diamine backbone: stereoselective recognition of amino alcoholsQ46826401
Copolymerization of cyclohexene oxide and carbon dioxide using (salen)Co(III) complexes: synthesis and characterization of syndiotactic poly(cyclohexene carbonate).Q46853799
A practical approach to the resolution of racemic N-benzyl alpha-amino acids by liquid-liquid extraction with a lipophilic chiral salen-cobalt(III) complexQ46984230
Dithionite reduction kinetics of the dissimilatory copper-containing nitrite reductase of Alcalegenes xylosoxidans. The SO(2)(.-) radical binds to the substrate binding type 2 copper site before the type 2 copper is reduced.Q50499615
Efficient resolution of racemic N-benzyl beta3-amino acids by iterative liquid-liquid extraction with a chiral (salen)cobalt(III) complex as enantioselective selector.Q53521290
A metal complex that binds alpha-amino acids with high and predictable stereospecificityQ56902131
Protease inhibitors. Part 7Q58863337
Amino acid recognition of pyridine bis(oxazoline)–copper(II) complex in aqueous solventQ59768848
Highly diastereoselective formation of ruthenium complexes for efficient catalytic asymmetric transfer hydrogenationQ61782058
Predetermination of chirality at octahedral centres with tetradentate ligands: prospects for enantioselective catalysisQ63350506
Separation of amino-acid enantiomers using micellar-enhanced ultrafiltration.Q64959401
Separation of pyridone carboxylic acid enantiomers by high-performance liquid chromatography using copper(II)-L-amino acid as the eluentQ68062836
Bis(L-amino acid amidato) copper(II) complexes as chiral eluents in the enantiomeric separation of D,L-dansylamino acids by reversed-phase high-performance liquid chromatographyQ68488623
Preparation of 2,3,4-Trisubstituted Piperidines by a Formal Hetero-Ene Reaction of Amino Acid DerivativesQ74822832
P433issue7
P921main subjectcobaltQ740
chiralityQ214514
P304page(s)1253-1264
P577publication date2008-03-01
P1433published inEuropean Journal of Organic ChemistryQ899286
P1476titleResolution of RacemicN-Benzyl α-Amino Acids by Liquid-Liquid Extraction: A Practical Method Using a Lipophilic Chiral Cobalt(III) Salen Complex and Mechanistic Studies
P478volume2008

Reverse relations

cites work (P2860)
Q37812271Chiral separation by enantioselective liquid-liquid extraction
Q87901359Circular dichroism sensing of chiral compounds using an achiral metal complex as probe
Q54765904Enantioselective liquid-liquid extraction of zopiclone with mandelic acid ester derivatives.
Q47763989Enantioselective resolution of 4-chloromandelic acid by liquid-liquid extraction using 2-chloro-N-carbobenzyloxy-L-amino acid.
Q53627624Highly enantioselective extraction of underivatized amino acids by the uryl-pendant hydroxyphenyl-binol ketone.
Q46511256In Situ Generation of Co(III) -Salen Complexes for Copolymerization of Propylene Oxide and CO2.
Q46305427Mononuclear salen-gallium complexes for iso-selective ring-opening polymerization (ROP) of rac-lactide
Q38180013Processes to separate enantiomers

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