Desymmetrization of cyclic 1,3-diketones via Ir-catalyzed hydrogenation: an efficient approach to cyclic hydroxy ketones with a chiral quaternary carbon

scientific article published on 21 May 2019

Desymmetrization of cyclic 1,3-diketones via Ir-catalyzed hydrogenation: an efficient approach to cyclic hydroxy ketones with a chiral quaternary carbon is …
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scholarly articleQ13442814

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P356DOI10.1039/C9SC01769K
P932PMC publication ID6601421
P698PubMed publication ID31341590

P50authorXumu ZhangQ87633697
Jialin WenQ88107667
P2093author name stringQuan Gong
P2860cites workReadily Accessible and Highly Efficient Ferrocene-Based Amino-Phosphine-Alcohol (f-Amphol) Ligands for Iridium-Catalyzed Asymmetric Hydrogenation of Simple Ketones.Q51097857
Iridium Catalysts with f-Amphox Ligands: Asymmetric Hydrogenation of Simple Ketones.Q51305959
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Formal total synthesis of (+)-cortistatins A and JQ86008043
Catalytic asymmetric Torgov cyclization: a concise total synthesis of (+)-estroneQ87478094
Total Synthesis of Aplysiasecosterol AQ89230913
Iridium-Catalyzed Asymmetric Hydrogenation of Ketones with Accessible and Modular Ferrocene-Based Amino-phosphine Acid (f-Ampha) LigandsQ89946748
New syntheses of estrone, d,1-8-iso-oestrone and d,1-19-nortestosteroneQ114738492
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A global and local desymmetrization approach to the synthesis of steroidal alkaloids: stereocontrolled total synthesis of paspalineQ35538590
Steroid total synthesisQ35812193
Asymmetric Total Synthesis of the Indole Diterpene Alkaloid PaspalineQ36136712
Catalytic enantioselective synthesis of quaternary carbon stereocentresQ36420603
Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary StereocentersQ38850644
Allene synthesis via C-C fragmentation: method and mechanistic insightQ43279688
Catalytic enantioselective construction of quaternary stereocenters: assembly of key building blocks for the synthesis of biologically active molecules.Q46962522
P275copyright licenseCreative Commons Attribution-NonCommercial 3.0 UnportedQ18810331
P6216copyright statuscopyrightedQ50423863
P433issue25
P921main subjectchiralityQ214514
P304page(s)6350-6353
P577publication date2019-05-21
P1433published inChemical ScienceQ2962267
P1476titleDesymmetrization of cyclic 1,3-diketones via Ir-catalyzed hydrogenation: an efficient approach to cyclic hydroxy ketones with a chiral quaternary carbon
P478volume10