Copper-catalyzed arylation of 1H-perfluoroalkanes

scientific article

Copper-catalyzed arylation of 1H-perfluoroalkanes is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1021/JA2041942
P932PMC publication ID3122272
P698PubMed publication ID21627068
P5875ResearchGate publication ID51179084

P2093author name stringOlafs Daugulis
Sergey Lindeman
Ilya Popov
P2860cites workCF(3)-bearing aromatic and heterocyclic building blocksQ36539285
Copper-catalyzed arylation and alkenylation of polyfluoroarene C-H bondsQ36876264
A general method for copper-catalyzed arylation of arene C-H bondsQ37339126
Aryl-CF(3) bond-forming reductive elimination from palladium(IV)Q39400915
The palladium-catalyzed trifluoromethylation of aryl chloridesQ41268772
Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoterQ43149782
Aromatic trifluoromethylation catalytic in copperQ46075872
Active trifluoromethylating agents from well-defined Copper(I)-CF3 complexesQ46548048
Highly selective room-temperature copper-catalyzed C-N coupling reactionsQ79837045
Fluorine in medicinal chemistryQ80497522
Bipyridinium ionic liquid-promoted cross-coupling reactions between perfluoroalkyl or pentafluorophenyl halides and aryl iodidesQ81719988
Unexpected H2O-induced Ar-X activation with trifluoromethylpalladium(II) arylsQ83085930
P433issue24
P407language of work or nameEnglishQ1860
P921main subjectcopperQ753
P304page(s)9286-9289
P577publication date2011-05-31
P1433published inJournal of the American Chemical SocietyQ898902
P1476titleCopper-catalyzed arylation of 1H-perfluoroalkanes
P478volume133

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cites work (P2860)
Q42549258A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)]
Q51358879A highly stable and versatile heterobifunctional fluoroalkylation reagent for preparation of fluorinated organic compounds.
Q51753819A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums.
Q51028386Combination of fluoroalkylation and Kornblum-DeLaMare reaction: a new strategy for the construction of (Z)-β-perfluoroalkyl enaminones.
Q48279878Convenient protocols for Mizoroki-Heck reactions of aromatic bromides and polybromides with fluorous alkenes of the formula H2C[double bond, length as m-dash]CH(CF2)n-1CF3 (n = 8, 10).
Q42114703Copper-catalyzed CuAAC/intramolecular C-H arylation sequence: Synthesis of annulated 1,2,3-triazoles
Q50449835Copper-catalyzed phosphorylation of sp(2) C-H bonds
Q45582770Copper-catalyzed synthesis of trifluoromethyl-substituted isoxazolines
Q44631339Copper-catalyzed trifluoromethylation-cyclization of enynes: highly regioselective construction of trifluoromethylated carbocycles and heterocycles
Q36399655Copper-promoted sulfenylation of sp2 C-H bonds
Q43419559Cu-catalyzed direct C-H bond functionalization: a regioselective protocol to 5-aryl thiazolo[3,2-b]-1,2,4-triazoles
Q42109961Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide.
Q51533686CuCl-catalyzed ortho trifluoromethylation of arenes and heteroarenes with a pivalamido directing group.
Q46780836Dialkylzinc-mediated cross-coupling reactions of perfluoroalkyl and perfluoroaryl halides with aryl halides
Q43889129Direct synthesis of a trifluoromethyl copper reagent from trifluoromethyl ketones: application to trifluoromethylation
Q38913481Facile Access to Fluoroaromatic Molecules by Transition-Metal-Free C-F Bond Cleavage of Polyfluoroarenes: An Efficient, Green, and Sustainable Protocol
Q38123135Introduction of fluorine and fluorine-containing functional groups.
Q50921717Lewis Acid Catalyzed Asymmetric Three-Component Coupling Reaction: Facile Synthesis of α-Fluoromethylated Tertiary Alcohols.
Q101464199Metallaphotoredox Perfluoroalkylation of Organobromides
Q36908251Nickel-Catalyzed Arylation of Heteroaryl-containing Diarylmethanes: Exceptional Reactivity of the Ni(NIXANTPHOS)-based Catalyst
Q46707137Perfluoroalkyl and -aryl zinc ate complexes: generation, reactivity, and synthetic application.
Q50219401Photo-induced iodination of aryl halides under very mild conditions
Q58750258Practical tetrafluoroethylene fragment installation through a coupling reaction of (1,1,2,2-tetrafluorobut-3-en-1-yl)zinc bromide with various electrophiles
Q42157743Regio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates
Q87429316Regioselective trifluoromethylation of N-heteroaromatic compounds using trifluoromethyldifluoroborane activator
Q90678509Ruthenium-Catalyzed Site-Selective Trifluoromethylations and (Per)Fluoroalkylations of Anilines and Indoles
Q47259807Synthesis of Diarylated 4-Pyridylmethyl Ethers via Palladium-Catalyzed Cross-Coupling Reactions
Q34266984Tamed arene and heteroarene trifluoromethylation.
Q34316578Taming of fluoroform: direct nucleophilic trifluoromethylation of Si, B, S, and C centers
Q46533727The critical effect of the countercation in the direct cupration of fluoroform with [Cu(OR)2 ](-).
Q48295776The first nucleophilic C-H perfluoroalkylation of aromatic compounds via (arene)tricarbonylchromium complexes
Q40333861Unprecedented copper-mediated oxidative demethylation of propionamides via bidentate-chelation assistance.

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