Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source

scientific article

Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source is …
instance of (P31):
scholarly articleQ13442814

External links are
P356DOI10.1021/JA301519Q
P932PMC publication ID3397916
P698PubMed publication ID22519742
P5875ResearchGate publication ID224808420

P2093author name stringKe Sun
Quyen Nguyen
Tom G Driver
P2860cites workPalladium-Catalyzed Ligand-Directed C−H Functionalization ReactionsQ29012891
Synthesis of 1,3-diamines through rhodium-catalyzed C-H insertionQ33656399
Examination of the mechanism of Rh(2)(II)-catalyzed carbazole formation using intramolecular competition experimentsQ33906836
C-H bond functionalization via hydride transfer: direct coupling of unactivated alkynes and sp(3) C-H bonds catalyzed by platinum tetraiodideQ34271776
Organic azides: an exploding diversity of a unique class of compoundsQ34443016
A predictably selective aliphatic C-H oxidation reaction for complex molecule synthesisQ34708270
Recent advances in transition metal-catalyzed N-atom transfer reactions of azidesQ34985186
Ruthenium-catalyzed γ-carbolinium ion formation from aryl azides; synthesis of dimebolinQ34989553
Rhodium-Catalyzed C-H Amination - An Enabling Method for Chemical SynthesisQ35127763
Intramolecular Ir(I)-catalyzed benzylic C-H bond amination of ortho-substituted aryl azidesQ37345800
Catalytic C-H amination: recent progress and future directionsQ37744545
Strain release in C-H bond activation?Q40832116
Rhodium-catalyzed synthesis of 2,3-disubstituted indoles from β,β-disubstituted stryryl azidesQ42061881
A diruthenium catalyst for selective, intramolecular allylic C-H amination: reaction development and mechanistic insight gained through experiment and theoryQ43971646
Amination of benzylic C-H bonds by arylazides catalyzed by CoII-porphyrin complexes: a synthetic and mechanistic studyQ44265904
The mechanism of aluminum-catalyzed Meerwein-Schmidt-Ponndorf-Verley reduction of carbonyls to alcohols.Q45145424
Expanding the scope of C-H amination through catalyst designQ45162229
Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3).Q45936123
Catalytic intermolecular amination of C-H bonds: method development and mechanistic insightsQ46051033
C-H bond amination from a ferrous dipyrromethene complexQ46119817
Synthesis of beta-, gamma-, and delta-lactams via Pd(II)-catalyzed C-H activation reactionsQ46333074
Eta2-organoazide complexes of nickel and their conversion to terminal imido complexes via dinitrogen extrusionQ46409442
Cobalt-catalyzed asymmetric olefin aziridination with diphenylphosphoryl azideQ46424336
N-tosyloxycarbamates as reagents in rhodium-catalyzed C-H amination reactionsQ46567520
Toward a synthetically useful stereoselective C-H amination of hydrocarbonsQ46855838
Catalytic C-H bond amination from high-spin iron imido complexes.Q52609051
Mechanism of cobalt(II) porphyrin-catalyzed C-H amination with organic azides: radical nature and H-atom abstraction ability of the key cobalt(III)-nitrene intermediates.Q53418236
A DFT study on the mechanism of Rh2(II,II)-catalyzed intramolecular amidation of carbamates.Q53532985
Cobalt(II)-Catalyzed Intramolecular C−H Amination with Phosphoryl Azides: Formation of 6- and 7-Membered CyclophosphoramidatesQ57834075
C–H Functionalization in organic synthesisQ60020969
Copper and silver complexes containing organic azide ligands: syntheses, structures, and theoretical investigation of [HB(3,5-(CF3)2Pz)3]CuNNN(1-Ad) and [HB(3,5-(CF3)2Pz)3]AgN(1-Ad)NN (where Pz = pyrazolyl and 1-Ad = 1-adamantyl)Q73484242
Stereochemical models for rh-catalyzed amination reactions of chiral sulfamatesQ79341477
Transient terminal Cu-nitrene intermediates from discrete dicopper nitrenesQ79373439
Construction of robust ruthenium(salen)(CO) complexes and asymmetric aziridination with nitrene precursors in the form of azide compounds that bear easily removable N-sulfonyl groupsQ80174217
Intramolecular C-H amination reactions: exploitation of the Rh(2)(II)-catalyzed decomposition of azidoacrylatesQ80378798
Silver-catalyzed intermolecular amination of C--H groupsQ80397719
A highly effective cobalt catalyst for olefin aziridination with azides: hydrogen bonding guided catalyst designQ81112616
Dirhodium(II)-catalyzed intramolecular C-H amination of aryl azidesQ81359463
Transition metal-catalyzed synthesis of pyrroles from dienyl azidesQ81580393
Enantioselective C-H amination using cationic ruthenium(II)-pybox catalystsQ81672732
Bonding and structure of copper nitrenesQ82202244
Copper-nitrene complexes in catalytic C-H aminationQ82641043
Evidence for a one-electron mechanistic regime in dirhodium-catalyzed intermolecular C-H aminationQ83908744
Catalytic enantioselective intramolecular redox reactions: ring-fused tetrahydroquinolinesQ84477162
P433issue17
P407language of work or nameEnglishQ1860
P304page(s)7262-7265
P577publication date2012-04-24
P1433published inJournal of the American Chemical SocietyQ898902
P1476titleRh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source
P478volume134

Reverse relations

cites work (P2860)
Q46000420Application of a Palladium-Catalyzed C-H Functionalization/Indolization Method to Syntheses of cis-Trikentrin A and Herbindole B.
Q58064829Application of a Palladium-Catalyzed C−H Functionalization/Indolization Method to Syntheses ofcis-Trikentrin A and Herbindole B
Q46943397Asymmetric nitrene transfer reactions: sulfimidation, aziridination and C-H amination using azide compounds as nitrene precursors
Q48598208Biomass-Derived N-doped Carbon Materials with Silica-Supported Ultrasmall ZnO Nanoparticles: Robust Catalysts for the Green Synthesis of Benzimidazoles
Q87431547C-H activation: the road less travelled to amination
Q38905373Catalytic Synthesis of N-Heterocycles via Direct C(sp3)-H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand
Q49466223Cobalt catalyzed sp3 C-H amination utilizing aryl azides
Q45137871Complex N-heterocycle synthesis via iron-catalyzed, direct C-H bond amination
Q48166740Concise Synthesis of Astellatol Core Skeleton
Q40416475Copper-Catalyzed Formation of α-Alkoxycycloalkenones from N-Tosylhydrazones.
Q51531085Copper-mediated C(sp(3))-H azidation with Me3SiN3: synthesis of imidazoles from ketones and aldehydes.
Q37701705Development of a Suzuki cross-coupling reaction between 2-azidoarylboronic pinacolate esters and vinyl triflates to enable the synthesis of [2,3]-fused indole heterocycles
Q33761797Efficient synthesis of 3H-indoles enabled by the lead-mediated α-arylation of β-ketoesters or γ-lactams using aryl azides
Q64275301Enantioselective intramolecular C-H amination of aliphatic azides by dual ruthenium and phosphine catalysis
Q40093117In situ generation of N-unsubstituted imines from alkyl azides and their applications for imine transfer via copper catalysis.
Q36754682Iron(II) bromide-catalyzed intramolecular C-H bond amination [1,2]-shift tandem reactions of aryl azides
Q41856039Iron(II)-catalyzed intermolecular amino-oxygenation of olefins through the N-O bond cleavage of functionalized hydroxylamines.
Q48180171Iron-Catalyzed Intramolecular Aminations of C(sp3 )-H Bonds in Alkylaryl Azides.
Q43082425Ligand-controlled, tunable silver-catalyzed C-H amination
Q48111330Manganese(iii) acetate catalyzed oxidative amination of benzylic C(sp3)-H bonds with nitriles.
Q43025057Mechanism and Dynamics of Intramolecular C-H Insertion Reactions of 1-Aza-2-azoniaallene Salts
Q41533589Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and Benzenes
Q57496312Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity
Q48330716Nitroarenes as the Nitrogen Source in Intermolecular Palladium-Catalyzed Aryl C-H Bond Aminocarbonylation Reactions.
Q34678833Palladium(0)-catalyzed Heck reaction/C-H activation/amination sequence with diaziridinone: a facile approach to indolines
Q53354833Pd(II) -Catalyzed Intermolecular Amination of Unactivated C(sp(3) )-H Bonds.
Q92262736Quantum Suppression of Intramolecular Deuterium Kinetic Isotope Effects in a Pericyclic Hydrogen Transfer Reaction
Q44126397Recyclable copper catalyzed nitrogenation of biphenyl halides: a direct approach to carbazoles
Q53363214Rhodium-catalyzed direct C-H amination of benzamides with aryl azides: a synthetic route to diarylamines.
Q53100685Selective C(sp2)-C(sp) bond cleavage: the nitrogenation of alkynes to amides.
Q38167287Self-assembled selenium monolayers: from nanotechnology to materials science and adaptive catalysis.
Q89653943Synthesis of Carbazoles and Related Heterocycles from Sulfilimines by Intramolecular C-H Aminations
Q53559735Tandem Oxidative C-H Amination and Iodization to Synthesize Difunctional Atropoisomeric P-Stereogenic Phosphinamides.
Q57453377Terminal Imido Rhodium Complexes
Q39329176Triiodide-Mediated δ-Amination of Secondary C-H Bonds.

Search more.