Triiodide-Mediated δ-Amination of Secondary C-H Bonds.

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Triiodide-Mediated δ-Amination of Secondary C-H Bonds. is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1002/ANIE.201604704
P932PMC publication ID5166987
P698PubMed publication ID27384522

P50authorDavid A. NagibQ42293165
P2093author name stringStacy C Fosu
Trevor C Chopko
Ethan A Wappes
P2860cites workPalladium-Catalyzed Ligand-Directed C−H Functionalization ReactionsQ29012891
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertionQ29308505
Intermolecular Ritter-type C-H amination of unactivated sp3 carbons.Q30505165
Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activationQ33645846
Metal-catalyzed nitrogen-atom transfer methods for the oxidation of aliphatic C-H bondsQ33831365
Iron-catalyzed intramolecular allylic C-H amination.Q34248390
Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalizationQ35029999
Heterocycle synthesis via direct C-H/N-H couplingQ35670227
Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom sourceQ36098151
Recent progress in the generation and use of nitrogen-centred radicalsQ37224417
Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicalityQ37294999
C-H functionalization logic in total synthesisQ37836434
C-H bond functionalization: emerging synthetic tools for natural products and pharmaceuticalsQ38034172
Analysis of the structural diversity, substitution patterns, and frequency of nitrogen heterocycles among U.S. FDA approved pharmaceuticalsQ38254225
N-Acyloxyphthalimides as nitrogen radical precursors in the visible light photocatalyzed room temperature C-H amination of arenes and heteroarenesQ39046016
γ,δ,ε-C(sp(3))-H Functionalization through Directed Radical H-AbstractionQ40668223
Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron TransferQ41824874
Iron-Catalyzed Direct Diazidation for a Broad Range of OlefinsQ41855560
Iron(II)-catalyzed intermolecular amino-oxygenation of olefins through the N-O bond cleavage of functionalized hydroxylamines.Q41856039
syn-1,2-Amino alcohols via diastereoselective allylic C-H aminationQ42938646
Enantioselective direct α-amination of aldehydes via a photoredox mechanism: a strategy for asymmetric amine fragment couplingQ42963867
Ligand-controlled, tunable silver-catalyzed C-H aminationQ43082425
Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization ReactionsQ43170725
Intramolecular hydrogen abstraction reaction promoted by N-radicals in carbohydrates. Synthesis of chiral 7-oxa-2-azabicyclo[2.2.1]heptane and 8-oxa-6-azabicyclo[3.2.1]octane ring systemsQ44296814
C-H bond activation enables the rapid construction and late-stage diversification of functional moleculesQ44783398
Use of a readily removable auxiliary group for the synthesis of pyrrolidones by the palladium-catalyzed intramolecular amination of unactivated γ C(sp(3))-H bondsQ44981550
Complex N-heterocycle synthesis via iron-catalyzed, direct C-H bond aminationQ45137871
1,3-Diol synthesis via controlled, radical-mediated C-H functionalizationQ46088031
Electrocatalytic Generation of Amidyl Radicals for Olefin Hydroamidation: Use of Solvent Effects to Enable Anilide OxidationQ48044648
A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones We thank Professors Brauman, Stack, Trost, and Wender for many helpful discussions. C.G.E. is the recipient of an NSF Predoctoral Fellowship. J.D.B. gQ48370443
Cobalt catalyzed sp3 C-H amination utilizing aryl azidesQ49466223
Silver-catalysed direct amination of unactivated C-H bonds of functionalized moleculesQ50450860
Site-selective arene C-H amination via photoredox catalysis.Q50933853
Iodoarene-Catalyzed Stereospecific Intramolecular sp(3) C-H Amination: Reaction Development and Mechanistic Insights.Q50969767
An Iodine-Catalyzed Hofmann-Löffler Reaction.Q50972067
Visible-light-promoted iminyl-radical formation from acyl oximes: a unified approach to pyridines, quinolines, and phenanthridines.Q51011635
Photocatalytic generation of N-centered hydrazonyl radicals: a strategy for hydroamination of β,γ-unsaturated hydrazones.Q51024724
Organometallic chemistry: C-H activation.Q53199987
Visible-light-promoted remote C(sp(3))-H amidation and chlorination.Q53268699
Highly efficient syntheses of azetidines, pyrrolidines, and indolines via palladium catalyzed intramolecular amination of C(sp3)-H and C(sp2)-H bonds at γ and δ positions.Q53393802
Mechanism of cobalt(II) porphyrin-catalyzed C-H amination with organic azides: radical nature and H-atom abstraction ability of the key cobalt(III)-nitrene intermediates.Q53418236
Highly regioselective amination of unactivated alkanes by hypervalent sulfonylimino-λ³-bromane.Q54183085
Ueber die Einwirkung des Broms in alkalischer Lösung auf die AmineQ56434185
Über eine neue Bildungsweise vonN-alkylierten PyrrolidinenQ56434644
Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of AlkenesQ57657177
Selective Alkane Transformations via Radicals and Radical Cations: Insights into the Activation Step from Experiment and TheoryQ57743157
Palladium-catalysed C–H activation of aliphatic amines to give strained nitrogen heterocyclesQ59068183
C−H Activation for the Construction of C−B BondsQ60318528
Metal-Free Radical Azidoarylation of Alkenes: Rapid Access to Oxindoles by Cascade CN and CC Bond-Forming ReactionsQ64027941
Organocatalytic, Oxidative, Intramolecular CH Bond Amination and Metal-free Cross-Amination of Unactivated Arenes at Ambient TemperatureQ64027956
Enantioselective C-H amination using cationic ruthenium(II)-pybox catalystsQ81672732
Chemistry. Adding aliphatic C-H bond oxidations to synthesisQ83464757
Efficient method for selective introduction of substituents as C5 of isoleucine and other alpha-amino acidsQ83992395
Copper-catalyzed intermolecular aminocyanation and diamination of alkenesQ85966528
Visible-Light-Catalyzed Direct Benzylic C(sp(3))-H Amination Reaction by Cross-Dehydrogenative CouplingQ86500313
N-Iodosuccinimide-Promoted Hofmann-Löffler Reactions of Sulfonimides under Visible LightQ87108986
Manganese-catalyzed late-stage aliphatic C-H azidationQ87110086
Chemoselective intramolecular functionalization of methyl groups in nonconstrained molecules promoted by N-iodosulfonamidesQ87226854
Iridium-catalyzed intermolecular amidation of sp³ C-H bonds: late-stage functionalization of an unactivated methyl groupQ87379089
Catalytic olefin hydroamination with aminium radical cations: a photoredox method for direct C-N bond formationQ87586613
Regioselective radical aminofluorination of styrenesQ87667731
A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to OxazolidinonesQ88522085
P433issue34
P407language of work or nameEnglishQ1860
P304page(s)9974-9978
P577publication date2016-07-07
P1433published inAngewandte Chemie International EditionQ62023953
P1476titleTriiodide-Mediated δ-Amination of Secondary C-H Bonds
P478volume55

Reverse relations

cites work (P2860)
Q47878455Asymmetric alkylation of remote C(sp3)-H bonds by combining proton-coupled electron transfer with chiral Lewis acid catalysis
Q64883566Catalytic Alkene Difunctionalization via Imidate Radicals.
Q64266900Catalytic β C-H amination an imidate radical relay
Q40951283Cooperative Light-Activated Iodine and Photoredox Catalysis for the Amination of Csp3 -H Bonds.
Q48191274Copper-Catalyzed Bromination of C(sp3 )-H Bonds Distal to Functional Groups
Q48160580Copper-catalyzed remote (δ) C(sp3)-H bond amination: a practical strategy to construct pyrrolidine derivatives.
Q61795886Copper-catalyzed remote C(sp)-H azidation and oxidative trifluoromethylation of benzohydrazides
Q90075850Development of an Imine Chaperone for Selective C-H Functionalization of Alcohols via Radical Relay
Q48351025Directed β C-H Amination of Alcohols via Radical Relay Chaperones.
Q48205331Directed γ-C(sp3)-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis
Q47312537Distal radical migration strategy: an emerging synthetic means.
Q48105970General, Mild, and Selective Method for Desaturation of Aliphatic Amines.
Q89705313Harnessing the biocatalytic potential of iron- and α-ketoglutarate-dependent dioxygenases in natural product total synthesis
Q57905278Kooperative Licht-aktivierte Iod- und Photoredox-Katalyse zur Aminierung von Csp3 -H-Bindungen
Q91579948Merging Photochemistry with Electrochemistry: Functional-Group Tolerant Electrochemical Amination of C(sp3 )-H Bonds
Q48227682Palladium-Catalyzed Atom-Transfer Radical Cyclization at Remote Unactivated C(sp3 )-H Sites: Hydrogen-Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates
Q48345967Photoinduced Remote Functionalisations by Iminyl Radical Promoted C-C and C-H Bond Cleavage Cascades.
Q47128255Photoredox Imino Functionalizations of Olefins
Q92298244Photoredox Radical/Polar Crossover Enables Construction of Saturated Nitrogen Heterocycles
Q49631047Radical-mediated intramolecular β-C(sp3)-H amidation of alkylimidates: facile synthesis of 1,2-amino alcohols
Q88654204Remote C-H Functionalization via Selective Hydrogen Atom Transfer
Q53831835Site-selective bromination of sp3 C-H bonds.
Q48374886Sulfamate Esters Guide Selective Radical-Mediated Chlorination of Aliphatic C-H Bonds
Q53559735Tandem Oxidative C-H Amination and Iodization to Synthesize Difunctional Atropoisomeric P-Stereogenic Phosphinamides.
Q90105996Vicinal, Double C-H Functionalization of Alcohols via an Imidate Radical-Polar Crossover Cascade
Q53684066Visible-Light-Mediated Remote Aliphatic C-H Functionalizations through a 1,5-Hydrogen Transfer Cascade.
Q90470809Visible-light promoted regioselective amination and alkylation of remote C(sp3)-H bonds
Q48367334α-Aminoxy-Acid-Auxiliary-Enabled Intermolecular Radical γ-C(sp3 )-H Functionalization of Ketones
Q59222742α-Aminoxy-Acid-Auxiliary-Enabled Intermolecular Radical γ-C(sp3 )−H Functionalization of Ketones
Q91667565δ C-H (hetero)arylation via Cu-catalyzed radical relay

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