General, Mild, and Selective Method for Desaturation of Aliphatic Amines.

scientific article

General, Mild, and Selective Method for Desaturation of Aliphatic Amines. is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1021/JACS.8B00488
P932PMC publication ID5821538
P698PubMed publication ID29400959

P50authorVladimir GevorgyanQ87610828
Marvin ParasramQ57045554
P2093author name stringYi Shi
Padon Chuentragool
P2860cites workThe catalytic hydroamination of alkynesQ28189606
Synthesis and Sulfur Electrophilicity of theNupharThiaspirane PharmacophoreQ28468157
Palladium-catalysed transannular C-H functionalization of alicyclic aminesQ28820908
Design and synthesis of new bicyclic diketopiperazines as scaffolds for receptor probes of structurally diverse functionality.Q31172630
Dehydrogenation and related reactions catalyzed by iridium pincer complexesQ34169700
Visible light photoredox catalysis with transition metal complexes: applications in organic synthesisQ34333964
Endo-selective Pd-catalyzed silyl methyl Heck reactionQ34926965
Diverted Total Synthesis of Promysalin Analogs Demonstrates That an Iron-Binding Motif Is Responsible for Its Narrow-Spectrum Antibacterial ActivityQ35994688
Synthesis of enamines, enol ethers and related compounds by cross-coupling reactionsQ36047200
Novel synthesis of enamines by iridium-catalyzed dehydrogenation of tertiary aminesQ73842285
Allylic AminationQ77646740
The palladium-catalyzed C-H activation of benzylic gem-dialkyl groupsQ79352081
Palladium-catalyzed Heck-type reactions of alkyl iodidesQ82584351
Functionalization of organic molecules by transition-metal-catalyzed C(sp3)-H activationQ82837929
Iron-catalyzed C-C bond formation at alpha-position of aliphatic amines via C-H bond activation through 1,5-hydrogen transferQ83980131
Remote Hydroxylation through Radical Translocation and Polar CrossoverQ85219619
Direct generation of oxygen-stabilized radicals by H• transfer from transition metal hydridesQ86493879
Synthesis of Lepadiformine Using a Hydroamination TransformQ86736544
Amide α,β-Dehydrogenation Using Allyl-Palladium Catalysis and a Hindered Monodentate AnilideQ87121790
Heck Reaction of Electronically Diverse Tertiary Alkyl HalidesQ89797543
Free Radical Chemistry Enabled by Visible Light-Induced Electron Transfer.Q36104920
Direct sp3 C-H bond activation adjacent to nitrogen in heterocyclesQ36852273
Activation of sp3 C-H bonds with cobalt(I): catalytic synthesis of enaminesQ36876650
The catalytic hydroamination of alkynesQ36895255
Organometallic enantiomeric scaffolding: general access to 2-substituted oxa- and azabicyclo[3.2.1]octenes via a Brønsted acid catalyzed [5 + 2] cycloaddition reactionQ37376885
Recent advances in transition metal-catalyzed sp3 C-H amination adjacent to double bonds and carbonyl groupsQ37917616
1,n-Hydrogen-atom transfer (HAT) reactions in which n≠5: an updated inventoryQ38262807
Asymmetric catalysis activated by visible lightQ38312022
Transition-Metal Hydride Radical Cations.Q38717385
Dual Catalysis Strategies in Photochemical SynthesisQ38816266
Organic Photoredox CatalysisQ38861188
Triiodide-Mediated δ-Amination of Secondary C-H Bonds.Q39329176
Palladium-Catalyzed Transformations of Alkyl C-H BondsQ39428953
Bidentate, monoanionic auxiliary-directed functionalization of carbon-hydrogen bondsQ39883238
γ,δ,ε-C(sp(3))-H Functionalization through Directed Radical H-AbstractionQ40668223
Guided desaturation of unactivated aliphaticsQ42088049
Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp(3)-sp(2) Cross-CouplingQ42409615
Investigation of the Mechanism of C(sp3)−H Bond Cleavage in Pd(0)-Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and SulfonamidesQ42948152
Amide-directed photoredox-catalysed C-C bond formation at unactivated sp3 C-H bondsQ43279712
1,3-Diol synthesis via controlled, radical-mediated C-H functionalizationQ46088031
Photoinduced Formation of Hybrid Aryl Pd-Radical Species Capable of 1,5-HAT: Selective Catalytic Oxidation of Silyl Ethers into Silyl Enol EthersQ46552998
Palladium-Catalyzed α,β-Dehydrogenation of Esters and NitrilesQ46736601
Carbonylation reactions of alkyl iodides through the interplay of carbon radicals and Pd catalysts.Q46908321
Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transferQ47108193
Visible-Light-Driven Palladium-Catalyzed Radical Alkylation of C-H Bonds with Unactivated Alkyl Bromides.Q47430115
The recent achievements of redox-neutral radical C-C cross-coupling enabled by visible-light.Q47859555
Irradiation-Induced Heck Reaction of Unactivated Alkyl Halides at Room Temperature.Q48049498
Iridium-Catalyzed Aerobic α,β-Dehydrogenation of γ,δ-Unsaturated Amides and Acids: Activation of Both α- and β-C-H bonds through an Allyl-Iridium Intermediate.Q48100353
Copper-Catalyzed Bromination of C(sp3 )-H Bonds Distal to Functional GroupsQ48191274
Directed γ-C(sp3)-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox CatalysisQ48205331
General, Auxiliary-Enabled Photoinduced Pd-Catalyzed Remote Desaturation of Aliphatic AlcoholsQ48220526
Silicon-Tethered Strategies for C-H Functionalization ReactionsQ48299900
Visible Light-Induced Room-Temperature Heck Reaction of Functionalized Alkyl Halides with Vinyl Arenes/HeteroarenesQ48301910
Palladium-Catalyzed Carbocyclizations of Unactivated Alkyl Bromides with Alkenes Involving Auto-tandem Catalysis.Q48321045
Direct Catalytic Desaturation of Lactams Enabled by Soft EnolizationQ48336741
Directed β C-H Amination of Alcohols via Radical Relay Chaperones.Q48351025
Visible-Light-Promoted Remote C-H Functionalization of o-Diazoniaphenyl Alkyl Sulfones.Q50587422
Copper-catalyzed aerobic aliphatic C-H oxygenation directed by an amidine moiety.Q51344543
Visible light-induced transition metal-catalyzed transformations: beyond conventional photosensitizers.Q52545564
γ-Functionalizations of Amines through Visible-Light-Mediated, Redox-Neutral C-C Bond Cleavage.Q52765215
Visible-Light-Mediated Remote Aliphatic C-H Functionalizations through a 1,5-Hydrogen Transfer Cascade.Q53684066
Selective Intramolecular CH Amination through the Metalloradical Activation of Azides: Synthesis of 1,3-Diamines under Neutral and Nonoxidative ConditionsQ57834081
Remote oxidation of steroids by photolysis of attached benzophenone groupsQ69530024
P433issue7
P407language of work or nameEnglishQ1860
P304page(s)2465-2468
P577publication date2018-02-07
P1433published inJournal of the American Chemical SocietyQ898902
P1476titleGeneral, Mild, and Selective Method for Desaturation of Aliphatic Amines
P478volume140

Reverse relations

cites work (P2860)
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Q59791307Irradiation-induced palladium-catalyzed decarboxylative desaturation enabled by a dual ligand system
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Q90105996Vicinal, Double C-H Functionalization of Alcohols via an Imidate Radical-Polar Crossover Cascade
Q90187399Visible-Light-Induced Palladium-Catalyzed Generation of Aryl Radicals from Aryl Triflates