Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality (scientific article published on January 2009)

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Q55262006	Exploring the mechanism of the Pd-catalyzed spirocyclization reaction: a combined DFT and experimental study.
Q42854480	Facile Synthesis of 2-(Phenylthio)phenols by Copper(I)-Catalyzed Tandem Transformation of C−S Coupling/C−H Functionalization
Q45499774	Facile access to 3-acylindoles through palladium-catalyzed addition of indoles to nitriles: the one-pot synthesis of indenoindolones
Q44902741	Facile access to cis-2,6-disubstituted tetrahydropyrans by palladium-catalyzed decarboxylative allylation: total syntheses of (±)-centrolobine and (+)-decytospolides A and B.
Q37211916	Facile synthesis of unsymmetrical acridines and phenazines by a Rh(III)-catalyzed amination/cyclization/aromatization cascade
Q38940325	Fe-Catalyzed Cross-Dehydrogenative Coupling Reactions.
Q42177350	Fluorenone synthesis by palladacycle-catalyzed sequential reactions of 2-bromobenzaldehydes with arylboronic acids
Q62060803	Fluorescence Quenching in BODIPYs Having Ir- and Rh-Tethered Complexes
Q45567923	Fluorescent Probes for Pd2+ Detection by Allylidene–Hydrazone Ligands with Excellent Selectivity and Large Fluorescence Enhancement
Q53172516	Formation of CC-type palladacycles with assistance from an apparently innocent NH(CO) functional group.
Q33869691	Formation of a C-C double bond from two aliphatic carbons. Multiple C-H activations in an iridium pincer complex.
Q48245200	Full Selectivity Control in Cobalt(III)-Catalyzed C-H Alkylations by Switching of the C-H Activation Mechanism
Q58656139	Full Selectivity Control in Cobalt(III)-Catalyzed C−H Alkylations by Switching of the C−H Activation Mechanism
Q39079192	Functionalization of C-H Bonds by Photoredox Catalysis.
Q39044891	General allylic C-H alkylation with tertiary nucleophiles
Q34489853	General method for functionalized polyaryl synthesis via aryne intermediates.
Q42854788	Generation of benzyne from benzoic acid using C–H activation
Q50454913	Gold-catalyzed C(sp3)-H/C(sp)H coupling/cyclization/oxidative alkynylation sequence: a powerful strategy for the synthesis of 3-alkynyl polysubstituted furans
Q50278986	Gold-catalyzed cascade C-H/C-H cross-coupling/cyclization/alkynylation: an efficient access to 3-alkynylpyrroles
Q36028073	Harnessing C-H Activation of Benzhydroxamates as a Macrocyclization Strategy: Synthesis of Structurally Diverse Macrocyclic Isoquinolones
Q50972231	Heteroatom-Guided, Palladium-Catalyzed, Site-Selective C-H Arylation of 4H-Chromenes: Diastereoselective Assembly of the Core Structure of Myristinin B through Dual C-H Functionalization.
Q38891800	Heterocycle Formation via Palladium-Catalyzed C-H Functionalization
Q35670227	Heterocycle synthesis via direct C-H/N-H coupling
Q48051193	Heteromultimetallic catalysis for sustainable organic syntheses.
Q50935939	Hf(OTf)4-Catalyzed highly diastereoselective synthesis of 1,3-disubstituted tetralin derivatives via benzylic C(sp3)-H bond functionalization.
Q85158739	Highly Effective Pd‐Catalyzed orthoOlefination of Acetanilides: Broad Substrate Scope and High Tolerability
Q64916014	Highly diastereoselective synthesis of tricyclic fused-pyrans by sequential hydride shift mediated double C(sp3)-H bond functionalization.
Q93014325	Hydrogen Bond Directed ortho-Selective C-H Borylation of Secondary Aromatic Amides
Q38940195	Hydrogen-Atom Transfer Reactions
Q48158539	Hydroxoiridium-Catalyzed Hydroalkylation of Terminal Alkenes with Ureas by C(sp3 )-H Bond Activation
Q42126723	Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C-H hydroxylation and amination
Q97542733	In silico rationalisation of selectivity and reactivity in Pd-catalysed C-H activation reactions
Q43450381	Indole synthesis by rhodium(III)-catalyzed hydrazine-directed C-H activation: redox-neutral and traceless by N-N bond cleavage
Q36884999	Insight into the palladium catalyzed oxidative arylation of benzofuran: Heteropoly acid oxidants evoke a Pd(II)/Pd(IV) mechanism
Q90183723	Insights into Cobalta(III/IV/II)-Electrocatalysis: Oxidation-Induced Reductive Elimination for Twofold C-H Activation
Q48308372	Internal Peptide Late-Stage Diversification: Peptide-Isosteric Triazoles for Primary and Secondary C(sp3 )-H Activation
Q58656116	Internal Peptide Late-Stage Diversification: Peptide-Isosteric Triazoles for Primary and Secondary C(sp3 )−H Activation
Q90300175	Intracellular Deprotection Reactions Mediated by Palladium Complexes Equipped with Designed Phosphine Ligands
Q42929627	Intramolecular Arene C-H to C-P Functionalization Mediated by Ni(II) and Pd(II).
Q57657330	Investigating N-methoxy-N′-aryl ureas in oxidative C–H olefination reactions: an unexpected oxidation behaviour
Q42948152	Investigation of the Mechanism of C(sp3)−H Bond Cleavage in Pd(0)-Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and Sulfonamides
Q46808240	Investigation on the mechanism of water-assisted palladium-catalyzed benzylic C-H amination by N-fluorobenzenesulfonimide
Q50179126	Iodine mediated oxidative cross-coupling of unprotected anilines and heteroarylation of benzothiazoles with 2-methylquinoline
Q50200220	Iodine-catalyzed sulfenylation of pyrazolones using dimethyl sulfoxide as an oxidant
Q51049271	Iodine-mediated [Formula: see text] C-H functionalization of methyl ketones: a one-pot synthesis of functionalized indolizines via the 1,3-dipolar cycloaddition reaction between pyridinium ylides and ynones.
Q50871516	Iodine-mediated synthesis of sulfur-bridged enaminones and chromones via double C(sp2)-H thiolation.
Q51528995	Ir(III)-catalyzed C-H alkynylation of arenes under chelation assistance.
Q54058132	Iridium-catalysed ortho-H/D and -H/T exchange under basic conditions: C-H activation of unprotected tetrazoles.
Q53575199	Iridium-catalyzed enantioselective C-H alkylation of ferrocenes with alkenes using chiral diene ligands.
Q50453874	Iron or boron-catalyzed C-H arylthiation of substituted phenols at room temperature
Q38940419	Iron-Catalyzed C-H Functionalization Processes
Q42032059	Iron-Catalyzed Heterocycle and Arene Deprotonative Alkylation
Q37714052	Iron-catalyzed arylation of heterocycles via directed C-H bond activation
Q37186144	Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process
Q50488505	Iron-mediated direct arylation with arylboronic acids through an aryl radical transfer pathway.
Q40377908	Kinetic Studies on the Palladium(II)-Catalyzed Oxidative Cross-Coupling of Thiophenes with Arylboron Compounds and Their Mechanistic Implications
Q44171543	Kinetico-mechanistic studies of cyclometalating C-H bond activation reactions on Pd(II) and Rh(II) centres: the importance of non-innocent acidic solvents in the process
Q51036714	Late-stage diversification of biologically active pyridazinones via a direct C-H functionalization strategy.
Q34751859	Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction
Q44277465	Ligand Promoted meta-C-H Chlorination of Anilines and Phenols
Q51119337	Ligand-Accelerated Direct C-H Arylation of BINOL: A Rapid One-Step Synthesis of Racemic 3,3'-Diaryl BINOLs.
Q37074358	Ligand-Accelerated ortho-C-H Olefination of Phenylacetic Acids
Q53448513	Ligand-Enabled Catalytic C-H Arylation of Aliphatic Amines by a Four-Membered-Ring Cyclopalladation Pathway.
Q46598011	Ligand-Enabled Pd(II)-Catalyzed Bromination and Iodination of C(sp3)-H Bonds
Q92929923	Ligand-Enabled, Palladium-Catalyzed β-C(sp3)-H Arylation of Weinreb Amides
Q41027240	Ligand-Promoted Meta-C-H Arylation of Anilines, Phenols, and Heterocycles
Q42161197	Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism
Q39588170	Ligand-accelerated cross-coupling of C(sp2)-H bonds with arylboron reagents
Q42920887	Ligand-controlled C(sp³)-H arylation and olefination in synthesis of unnatural chiral α-amino acids
Q54035463	Ligand-controlled regiodivergent pathways of rhodium(III)-catalyzed dihydroisoquinolone synthesis: experimental and computational studies of different cyclopentadienyl ligands.
Q41578174	Ligand-enabled cross-coupling of C(sp3)-H bonds with arylboron reagents via Pd(II)/Pd(0) catalysis
Q55019636	Ligand-enabled ortho-C-H olefination of phenylacetic amides with unactivated alkenes.
Q41881355	Ligand-promoted alkylation of C(sp3)-H and C(sp2)-H bonds
Q48105896	Manganese(I)-Catalyzed Dispersion-Enabled C-H/C-C Activation
Q50936534	Manganese-Catalyzed Direct Nucleophilic C(sp(2))-H Addition to Aldehydes and Nitriles.
Q38798477	Mechanism of Nickel-Catalyzed Suzuki-Miyaura Coupling of Amides
Q35715096	Mechanism of the rhodium(III)-catalyzed arylation of imines via C-H bond functionalization: inhibition by substrate
Q43977854	Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp3)-H borylation of chlorosilanes
Q50022067	Mechanisms for C(sp2)-Si activation of aryltrimethylsilyl groups in palladium-catalysed couplings
Q34987089	Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation
Q41832992	Mechanistic comparison between Pd-catalyzed ligand-directed C-H chlorination and C-H acetoxylation
Q54940454	Mechanistic insights into cobalt(ii/iii)-catalyzed C-H oxidation: a combined theoretical and experimental study.
Q59287834	Mechanistic insights into the S2-type reactivity of aryl-Co(iii) masked-carbenes for C-C bond forming transformations
Q53601755	Mechanistic study on Rh-catalyzed stereoselective C-C/C-H activation of tert-cyclobutanols.
Q45670909	Mechanistic study on ligand-controlled cobalt-catalyzed regioselectivity-switchable hydroarylation of styrenes
Q41148346	Merging Visible Light Photoredox Catalysis with Metal Catalyzed C-H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants
Q43121523	Merging photoredox and nickel catalysis: decarboxylative cross-coupling of carboxylic acids with vinyl halides.
Q48179880	Meta-Selective C-H Arylation of Aromatic Alcohols with a Readily Attachable and Cleavable Molecular Scaffold
Q50801642	Metal free TBHP-promoted intramolecular carbonylation of arenes via radical cross-dehydrogenative coupling: synthesis of indenoquinolinones, 4-azafluorenones and fluorenones.
Q50459217	Metal- and reagent-free highly selective anodic cross-coupling reaction of phenols
Q38872648	Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds.
Q53594111	Metal-Free Oxidative C-C Bond Formation through C-H Bond Functionalization.
Q58730683	Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp)-H bonds
Q54551440	Metal-free nitro-carbocyclization of activated alkenes: a direct approach to synthesize oxindoles by cascade C-N and C-C bond formation.
Q47351002	Metal-free oxidative para-acylation of unprotected anilines with N-heteroarylmethanes
Q35660405	Methoxy-directed aryl-to-aryl 1,3-rhodium migration
Q46129412	Methylene C(sp3)-H Arylation of Aliphatic Ketones Using a Transient Directing Group.
Q48292264	Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C-H/C-C Activation
Q57905591	Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C−H/C−C Activation
Q53296007	Microwave-assisted, rhodium(III)-catalyzed N-annulation reactions of aryl and α,β-unsaturated ketones with alkynes.
Q48181240	Mild Cobalt(III)-Catalyzed Allylative C-F/C-H Functionalizations at Room Temperature
Q48356635	Mild Decarboxylative C-H Alkylation: Computational Insights for Solvent-Robust Ruthenium(II) Domino Manifold.
Q38921963	Mild Palladium Catalyzed ortho C-H Bond Functionalizations of Aniline Derivatives.
Q51388598	Mild and efficient C2-alkenylation of indoles with alkynes catalyzed by a cobalt complex.
Q45152068	Mild copper-mediated direct oxidative cross-coupling of 1,3,4-oxadiazoles with polyfluoroarenes by using dioxygen as oxidant
Q41446940	Mild palladium-catalyzed C-H alkylation using potassium alkyltrifluoroborates in combination with MnF3
Q46900762	Mild rhodium(III)-catalyzed cyclization of amides with α,β-unsaturated aldehydes and ketones to azepinones: application to the synthesis of the homoprotoberberine framework
Q64106564	Modular, stereocontrolled C-H/C-C activation of alkyl carboxylic acids
Q92342131	Molecular-decoration technique offers boost to medicinal chemists
Q53726820	Mono-N-protected amino acid ligands stabilize dimeric palladium(ii) complexes of importance to C-H functionalization.
Q42094195	Monoselective o-C-H Functionalizations of Mandelic Acid and α-Phenylglycine
Q47640532	N,N-Chelate-control on the regioselectivity in acetate-assisted C-H activation
Q42636203	N-acylsulfonamide assisted tandem C-H olefination/annulation: synthesis of isoindolinones
Q34202358	Natural product synthesis at the interface of chemistry and biology
Q38194098	Negishi coupling: an easy progress for C-C bond construction in total synthesis
Q39404811	New synthetic approach to paullones and characterization of their SIRT1 inhibitory activity
Q50496432	Nickel catalyzed alkylation of N-aromatic heterocycles with Grignard reagents through direct C-H bond functionalization.
Q41997526	Nickel or phenanthroline mediated intramolecular arylation of sp3 C-H bonds using aryl halides.
Q39673635	Nickel, manganese, cobalt, and iron-catalyzed deprotonative arene dimerization
Q50099912	Nickel-Catalyzed C-H Arylation of Benzoxazoles and Oxazoles: Benchmarking the Influence of Electronic, Steric and Leaving Group Variations in Phenolic Electrophiles
Q88617949	Nickel-Catalyzed Coupling of Azoles with Aromatic Nitriles
Q38940338	Nickel-Catalyzed Cross-Coupling Reactions of Unreactive Phenolic Electrophiles via C-O Bond Activation
Q58347049	Nickel-Catalyzed Decarbonylative CH Coupling Reactions: A Strategy for Preparing Bis(heteroaryl) Backbones
Q36164787	Nickel-Catalyzed Decarboxylative Arylation of Azoles with Perfluoro- and Nitrobenzoates
Q47125301	Nickel-Mediated Synthesis of Isoindolinones at Room Temperature
Q58656181	Nickel-catalyzed C–H activation of purine bases with alkyl halides
Q50460023	Nickel-catalyzed chelation-assisted direct arylation of unactivated C(sp3)-H bonds with aryl halides
Q53552590	Nickel-catalyzed decarboxylative acylation of heteroarenes by sp2 C-H functionalization.
Q45012020	Nickel-catalyzed directed sulfenylation of sp(2) and sp(3) C-H bonds
Q50512914	Nickel-catalyzed sp2 C-H bonds arylation of N-aromatic heterocycles with Grignard reagents at room temperature.
Q46564019	Non-redox metal ion promoted oxidative coupling of indoles with olefins by the palladium(ii) acetate catalyst through dioxygen activation: experimental results with DFT calculations
Q30995038	Non-redox metal ions can promote Wacker-type oxidations even better than copper(II): a new opportunity in catalyst design.
Q42201427	Nonnatural amino acid synthesis by using carbon-hydrogen bond functionalization methodology
Q43906247	Novel triazole-based fluorescent probes for Pd2+ in aqueous solutions: design, theoretical calculations and imaging.
Q50468181	Nucleophilic attack of α-aminoalkyl radicals on carbon-nitrogen triple bonds to construct α-amino nitriles: an experimental and computational study.
Q39349576	O-acetyl oximes as transformable directing groups for Pd-catalyzed C-H bond functionalization
Q58482024	O2insertion into a palladium(ii)-hydride bond: Observation of mechanistic crossover between HX-reductive-elimination and hydrogen-atom-abstraction pathways
Q34140301	On the Mechanism of Palladium-Catalyzed Aromatic C−H Oxidation
Q57614639	One-Pot Formation of CC and CN Bonds through Palladium-Catalyzed Dual CH Activation: Synthesis of Phenanthridinones
Q53033224	One-pot synthesis of highly substituted polyheteroaromatic compounds by rhodium(III)-catalyzed multiple C-H activation and annulation.
Q48348195	One-pot synthesis of quaternary carbon centered cyclobutanes via Pd(ii)-catalyzed cascade C(sp3)-H activations.
Q40519432	Orchestrated triple C-H activation reactions using two directing groups: rapid assembly of complex pyrazoles
Q39780780	Organic chemistry. Functionalization of C(sp3)-H bonds using a transient directing group
Q38803445	Organo- and Organometallic-Catalytic Intramolecular [1,5]-Hydride Transfer/Cyclization Process through C(sp(3) )-H Bond Activation
Q58374761	Organocatalytic Asymmetric Direct C sp 3H Functionalization of Ethers: A Highly Efficient Approach to Chiral Spiroethers
Q84961619	Ortho-directed functionalization of arenes using magnesate bases
Q42174611	Overcoming the "oxidant problem": strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu).
Q48150027	Overcoming the Limitations of C-H Activation with Strongly Coordinating N-Heterocycles by Cobalt Catalysis
Q58656195	Overcoming the Limitations of C−H Activation with Strongly Coordinating N-Heterocycles by Cobalt Catalysis
Q51062141	Oxidant-free dehydrogenative coupling reactions via hydrogen evolution.
Q53317063	Oxidative biaryl coupling of thiophenes and thiazoles with arylboronic acids through palladium catalysis: otherwise difficult C4-selective C-H arylation enabled by boronic acids.
Q46570045	Oxidative catalytic coupling reactions: selective formation of C-C and C-X bonds using radical processes
Q57502919	PEPPSI-Type Palladium Complexes Containing Basic 1,2,3-Triazolylidene Ligands and Their Role in Suzuki-Miyaura Catalysis
Q57916667	Palladacycle catalysis: an innovation to the Suzuki–Miyaura cross-coupling reaction
Q48273292	Palladium Catalyzed Arylation and Benzylation of Nitroarenes Using Aryl Sulfonates and Benzyl Acetates.
Q90403810	Palladium catalyzed regioselective B-C(sp) coupling via direct cage B-H activation: synthesis of B(4)-alkynylated o-carboranes
Q42929786	Palladium catalyzed synthesis of highly substituted naphthalenes via direct ring construction from amides with alkynes
Q53545462	Palladium dichloride adduct of N,N-bis-(diphenylphosphanylmethyl)-2-aminopyridine: synthesis, structure and catalytic performance in the decarboxylative cross-coupling of 4-picolinic acid with aryl bromide.
Q48987061	Palladium meets copper: one-pot tandem synthesis of pyrido fused heterocycles via Sonogashira conjoined electrophilic cyclization
Q57749501	Palladium(0)-Catalyzed CarbonHydrogen Bond Functionalization for the Synthesis of Indoloquinazolinones
Q51692924	Palladium(II)-Catalyzed Acetoxime Directed ortho-Arylation of Aromatic Alcohols.
Q42775875	Palladium(II)-Catalyzed Tandem Oxidative Acetoxylation/ortho C-H Activation/Carbocyclization of Arylallenes
Q50783663	Palladium(II)-Catalyzed ortho-Arylation of Aromatic Alcohols with a Readily Attachable and Cleavable Molecular Scaffold.
Q53599892	Palladium(II)-catalyzed ortho-C-H arylation/alkylation of N-benzoyl α-amino ester derivatives.
Q86606058	Palladium(II)-catalyzed othro-C-H-benzoxylation of 2-arylpyridines by oxidative coupling with aryl acylperoxides
Q50499365	Palladium(II)-catalyzed oxidative C-H/C-H cross-coupling between two structurally similar azoles.
Q34175475	Palladium(III) in Synthesis and Catalysis
Q41941753	Palladium(ii)-catalyzed synthesis of dibenzothiophene derivatives via the cleavage of carbon-sulfur and carbon-hydrogen bonds
Q57749525	Palladium-Catalyzed Amidation by Chemoselective C(sp3)H Activation: Concise Route to Oxindoles Using a Carbamoyl Chloride Precursor
Q57749527	Palladium-Catalyzed Amidation by Chemoselective C(sp3)H Activation: Concise Route to Oxindoles Using a Carbamoyl Chloride Precursor
Q58656190	Palladium-Catalyzed C-H Arylation of Amides by Triazole Assistance
Q34865914	Palladium-Catalyzed C8-Selective C-H Arylation of Quinoline N-Oxides: Insights into the Electronic, Steric and Solvation Effects on the Site-Selectivity by Mechanistic and DFT Computational Studies
Q42909252	Palladium-Catalyzed Carbo-Heterofunctionalization of Alkenes for the Synthesis of Oxindoles and Spirooxindoles
Q57404802	Palladium-Catalyzed CH Bond Acetoxylation: An Approach toortho-Substituted Hydroxy[2.2]paracyclophane Derivatives
Q57614513	Palladium-Catalyzed Decarboxylative ortho-Acylation of Anilines with Carbamate as a Removable Directing Group
Q41763219	Palladium-Catalyzed Directed C(sp(3))-H Arylation of Saturated Heterocycles at C-3 Using a Concise Optimization Approach
Q50854910	Palladium-Catalyzed Directed para C-H Functionalization of Phenols.
Q50856067	Palladium-Catalyzed Heteroarylation and Concomitant ortho-Alkylation of Aryl Iodides.
Q48253927	Palladium-Catalyzed Intermolecular Acylation of Aryl Diazoesters with ortho-Bromobenzaldehydes.
Q41863453	Palladium-Catalyzed Intra- and Intermolecular C-H Arylation Using Mesylates: Synthetic Scope and Mechanistic Studies
Q29012891	Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
Q57614613	Palladium-Catalyzed Synthesis of Aromatic Sultones via Sulfonic Acid Group-Directed CH Activation
Q42907891	Palladium-Catalyzed Tandem Diperoxidation/C−H Activation Resulting in Diperoxy-oxindole in Air
Q50214496	Palladium-Catalyzed Tandem Oxidative Arylation/Olefination of Aromatic Tethered Alkenes/Alkynes
Q39428953	Palladium-Catalyzed Transformations of Alkyl C-H Bonds
Q57834065	Palladium-Catalyzed Tunable Functionalization of Allylic Imidates: Regioselective Aminodiacetoxylation and Aziridination
Q46691287	Palladium-Catalyzed Zinc-Amide-Mediated C-H Arylation of Fluoroarenes and Heteroarenes with Aryl Sulfides
Q46739513	Palladium-Catalyzed [3+3] Annulation between Diarylamines and α,β-Unsaturated Acids through CH Activation: Direct Access to 4-Substituted 2-Quinolinones
Q50049885	Palladium-N-heterocyclic carbene (NHC)-catalyzed asymmetric synthesis of indolines through regiodivergent C(sp3)-H activation: scope and DFT study
Q53731940	Palladium-catalysed decarboxylative nitrile insertion via C-H activation or self-coupling of indole-2-carboxylic acids: a new route to indolocarbolines and triindoles.
Q28820908	Palladium-catalysed transannular C-H functionalization of alicyclic amines
Q50458067	Palladium-catalyzed C(sp(3))-H activation: a facile method for the synthesis of 3,4-dihydroquinolinone derivatives.
Q53599806	Palladium-catalyzed C-H activation and intermolecular annulation with allenes.
Q48620840	Palladium-catalyzed C-H activation/C-C cross-coupling reactions via electrochemistry
Q50523172	Palladium-catalyzed C-H bond functionalization of C6-arylpurines.
Q84800889	Palladium-catalyzed acetoxylation of sp3 C–H bonds using molecular oxygen
Q38468279	Palladium-catalyzed aerobic dehydrogenation of substituted cyclohexanones to phenols
Q46580486	Palladium-catalyzed aerobic intermolecular cyclization of acrylic acid with 1-octene to afford α-methylene-γ-butyrolactones: the remarkable effect of continuous water removal from the reaction mixture and analysis of the reaction by kinetic, ESI-MS,
Q39343593	Palladium-catalyzed benzofuran and indole synthesis by multiple C-H functionalizations.
Q51323542	Palladium-catalyzed cross-coupling of unactivated alkenes with acrylates: application to the synthesis of the C13-C21 fragment of palmerolide A.
Q38457733	Palladium-catalyzed dehydrogenation/oxidative cross-coupling sequence of β-heteroatom-substituted ketones
Q50508476	Palladium-catalyzed desulfitative C-H arylation of heteroarenes with sodium sulfinates.
Q44674173	Palladium-catalyzed direct C-3 oxidative alkenylation of phosphachromones
Q51378150	Palladium-catalyzed direct C-H arylation of enamides with simple arenes.
Q51527215	Palladium-catalyzed direct arylation of indoles with arylsulfonyl hydrazides.
Q45966562	Palladium-catalyzed direct functionalization of 2-aminobutanoic acid derivatives: application of a convenient and versatile auxiliary.
Q50122874	Palladium-catalyzed direct sulfonylation of C-H bonds with the insertion of sulfur dioxide
Q53087135	Palladium-catalyzed direct synthesis of phosphole derivatives from triarylphosphines through cleavage of carbon-hydrogen and carbon-phosphorus bonds.
Q51760747	Palladium-catalyzed double C-H activation: one-pot synthesis of benzo[c]pyrazolo[1,2-a]cinnolin-1-ones from 5-pyrazolones and aryl iodides.
Q46148339	Palladium-catalyzed interannular meta-C-H arylation
Q41903560	Palladium-catalyzed ligand-promoted site-selective cyanomethylation of unactivated C(sp3)-H bonds with acetonitrile
Q50499138	Palladium-catalyzed monoselective C-H borylation of acetanilides under acidic conditions.
Q57614533	Palladium-catalyzed ortho-acyloxylation of N-nitrosoanilines via direct sp2 C–H bond activation
Q54519164	Palladium-catalyzed ortho-selective C-H deuteration of arenes: evidence for superior reactivity of weakly coordinated palladacycles.
Q50520576	Palladium-catalyzed oxidative C-H/C-H cross-coupling of indoles and pyrroles with heteroarenes.
Q51009755	Palladium-catalyzed oxidative carbamoylation of isoquinoline N-oxides with formylamides by means of dual C-H oxidative coupling.
Q42367139	Palladium-catalyzed picolinamide-directed iodination of remote ortho-C-H bonds of arenes: Synthesis of tetrahydroquinolines
Q48132804	Palladium-catalyzed regioselective C-H fluoroalkylation of indoles at the C4-position.
Q33461327	Palladium-catalyzed regioselective azidation of allylic C-H bonds under atmospheric pressure of dioxygen.
Q43864057	Palladium-catalyzed regioselective synthesis of 2(2'-biphenyl)benzimidazoles through C-H activation
Q43089289	Palladium-catalyzed ring-expansion reaction of indoles with alkynes: from indoles to tetrahydroquinoline derivatives under mild reaction conditions.
Q51556501	Palladium-catalyzed β-C(sp(3))-H arylation of phthaloyl alanine with hindered aryl iodides: synthesis of complex β-aryl α-amino acids.
Q42592149	Pd loaded amphiphilic COF as catalyst for multi-fold Heck reactions, C-C couplings and CO oxidation
Q36802674	Pd(II)-Catalyzed Cross-Coupling of C(sp(2) )-H Bonds and Alkyl-, Aryl- and Vinyl-Boron Reagents via Pd(II)/Pd(0) Catalysis
Q52951677	Pd(II)-catalyzed C(sp(3))-H arylation of amino acid derivatives with click-triazoles as removable directing groups.
Q40657921	Pd(II)-catalyzed C-H functionalizations directed by distal weakly coordinating functional groups
Q36628264	Pd(II)-catalyzed enantioselective C-H activation/C-O bond formation: synthesis of chiral benzofuranones
Q43167637	Pd(II)-catalyzed highly selective arylation of allyl esters via C-H functionalization of unreactive arenes with retention of the traditional leaving group
Q33899813	Pd(II)-catalyzed hydroxyl-directed C-H olefination enabled by monoprotected amino acid ligands
Q33738148	Pd(II)-catalyzed olefination of sp3 C-H bonds
Q35997559	Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C-H activation
Q36936524	Pd(II)-catalyzed ortho- or meta-C-H olefination of phenol derivatives
Q35938651	Pd(II)-catalyzed para-selective C-H arylation of monosubstituted arenes
Q82226479	Pd(OAc)2-Catalyzed Oxidative C−H/C−H Cross-Coupling of Electron-Deficient Polyfluoroarenes with Simple Arenes
Q40479529	Pd(OAc)2-catalyzed dehydrogenative C-H activation: An expedient synthesis of uracil-annulated β-carbolinones.
Q55029039	Pd(ii)-catalyzed remote regiodivergent ortho- and meta-C-H functionalizations of phenylethylamines.
Q48210165	Pd-Catalyzed C-H Alkylation of Arenes Using PyrDipSi, a Transformable and Removable Silicon-Tethered Directing Group.
Q59071165	Pd-Catalyzed Trifluoromethylthiolation of Unsaturated Compounds: A General Approach
Q48326148	Pd-Catalyzed oxidative annulation of enamides with diazabicyclic olefins: rapid access to cyclopentene fused 2-pyrrolines.
Q48135135	Pd-Catalyzed regioselective C-H halogenation of quinazolinones and benzoxazinones.
Q50849481	Pd-Catalyzed regioselective sequential meta-, ortho-C-H functionalization of arenes: a predictable approach to the synthesis of polysubstituted β-arylethylamines.
Q48048725	Pd-Catalyzed β-C(sp3 )-H Arylation of Propionic Acid and Related Aliphatic Acids
Q43980973	Pd-Catalyzed γ-C(sp3)-H Arylation of Free Amines Using a Transient Directing Group
Q37741356	Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids
Q51010139	Pd-catalyzed Csp(2) -H functionalization of heteroarenes via isocyanide insertion: concise synthesis of di-(hetero)aryl ketones and di-(hetero)aryl alkylamines.
Q42921433	Pd-catalyzed aryl C-H imidation with arene as the limiting reagent
Q47161851	Pd-catalyzed asymmetric allylic alkylations via C-H activation of N-allyl imines with glycinates
Q36452868	Pd-catalyzed modifiable silanol-directed aromatic C-H oxygenation
Q33867816	Pd0/PR3-catalyzed arylation of nicotinic and isonicotinic acid derivatives
Q50935693	Pd2+ fluorescent sensors based on amino and imino derivatives of rhodamine and improvement of water solubility by the formation of inclusion complexes with β-cyclodextrin.
Q45839436	PdCl2 and N-hydroxyphthalimide co-catalyzed C(sp2)-H hydroxylation by dioxygen activation
Q33636198	Peptide-templated noble metal catalysts: syntheses and applications
Q40479623	Phenanthroline-based metal-organic frameworks for Fe-catalyzed Csp3-H amination.
Q59009577	Phosphine-Free Palladium-Catalyzed Direct C-3 Arylation of 2-Phenylimidazo[1,2-a]pyridine Using Silver(I) Carboxylate
Q48133821	Phosphinic Amide as Directing Group Enabling Palladium(II)-Catalyzed ortho C-H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom
Q33545287	Phosphoramidites: privileged ligands in asymmetric catalysis
Q42322150	Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid
Q61336738	Photocatalytic Phenol-Arene C-C and C-O Cross-Dehydrogenative Coupling
Q41365748	Photochemical Nickel-Catalyzed C-H Arylation: Synthetic Scope and Mechanistic Investigations
Q43512892	Photochemically induced radical alkynylation of C(sp3)-H bonds
Q50950651	Pioneering Metal-Free Oxidative Coupling Strategy of Aromatic Compounds Using Hypervalent Iodine Reagents.
Q48191916	Polycyclization Enabled by Relay Catalysis: One-Pot Manganese-Catalyzed C-H Allylation and Silver-Catalyzed Povarov Reaction
Q37522542	Polymerization or cyclic dimerization: solvent dependent homo-coupling of terminal alkynes at HOPG surface
Q53394071	Post-synthetic modification of tryptophan containing peptides via NIS mediation.
Q38482524	Practical C-H functionalization of quinones with boronic acids
Q50447605	Practical synthesis of pyrazoles via a copper-catalyzed relay oxidation strategy
Q92485985	Practical, metal-free remote heteroarylation of amides via unactivated C(sp3)-H bond functionalization
Q40136454	Preparation of a Trp-BODIPY fluorogenic amino acid to label peptides for enhanced live-cell fluorescence imaging
Q59721643	Protodepalladation as a Strategic Elementary Step in Catalysis
Q37673934	Purinyl N1-directed aromatic C-H oxidation in 6-arylpurines and 6-arylpurine nucleosides
Q33940348	PyDipSi: a general and easily modifiable/traceless Si-tethered directing group for C-H acyloxylation of arenes
Q55267115	Pyridine-enabled copper-promoted cross dehydrogenative coupling of C(sp2)-H and unactivated C(sp3)-H bonds.
Q28468198	Radicals: Reactive Intermediates with Translational Potential
Q53970030	Rapid Construction of a Benzo-Fused Indoxamycin Core Enabled by Site-Selective C-H Functionalizations.
Q52940554	Rapid Synthesis of Thiophene-Based, Organic Dyes for Dye-Sensitized Solar Cells (DSSCs) by a One-Pot, Four-Component Coupling Approach.
Q51058880	Rational design of model Pd(ii)-catalysts for C-H activation involving ligands with charge-shift bonding characteristics.
Q34788592	Rational perturbation of the fluorescence quantum yield in emission-tunable and predictable fluorophores (Seoul-Fluors) by a facile synthetic method involving C-H activation.
Q38936904	Reaching the south: metal-catalyzed transformation of the aromatic para-position
Q39665245	Recent advances in direct C-H arylation: Methodology, selectivity and mechanism in oxazole series
Q38234765	Recent advances in heterobimetallic palladium(II)/copper(II) catalyzed domino difunctionalization of carbon-carbon multiple bonds
Q38588930	Recent advances in the ruthenium-catalyzed hydroarylation of alkynes with aromatics: synthesis of trisubstituted alkenes.
Q53189208	Recent advances using [Cp*Co(CO)I2] catalysts as a powerful tool for C-H functionalisation.
Q38165003	Recent trends in Pd-catalyzed remote functionalization of carbonyl compounds
Q39143244	Redox trends in cyclometalated palladium(ii) complexes.
Q48252414	Reductive Eliminations from Diarylpalladium(II) Complexes: A Combined Experimental and Computational Investigation
Q39526994	Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands
Q59287869	Regioselective Access to Sultam Motifs through Cobalt-Catalyzed Annulation of Aryl Sulfonamides and Alkynes using an 8-Aminoquinoline Directing Group
Q90432068	Regioselective C-H Functionalization of Naphthalenes: Reactivity and Mechanistic Insights
Q35136414	Regioselective C-H bond amination by aminoiodanes
Q39391359	Regioselective Direct C-Alkenylation of Indoles.
Q57376723	Regioselective Metalations of Pyrimidines and Pyrazines by Using Frustrated Lewis Pairs of BF3⋅OEt2and Hindered Magnesium- and Zinc-Amide Bases
Q34195420	Regioselective oxidative arylation of indoles bearing N-alkyl protecting groups: dual C-H functionalization via a concerted metalation-deprotonation mechanism
Q84794017	Regioselective syntheses of fully-substituted 1,2,3-triazoles: the CuAAC/C–H bond functionalization nexus
Q50535530	Regiospecific Synthesis of Nitroarenes by Palladium‐Catalyzed Nitrogen‐Donor‐Directed Aromatic CH Nitration
Q48808722	Remote C-H alkylation and C-C bond cleavage enabled by an in situ generated palladacycle
Q53550489	Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation.
Q38428371	Rh(III)-catalyzed direct C-H/C-H cross-coupling of quinones with arenes assisted by a directing group: identification of carbazole quinones as GSKβ inhibitors
Q34543120	Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation
Q50438273	Rh(III)-catalyzed oxime ether-directed heteroarylation of arene through oxidative C-H/C-H cross-coupling
Q54319958	Rh(iii)-catalyzed C-H activation reactions forming 1H-isoindoles containing a quaternary carbon center from aryl ketones or benzylamines.
Q59274266	Rh(iii)-catalyzed synthesis of 1-substituted isoquinolinium salts via a C–H bond activation reaction of ketimines with alkynes
Q45912722	Rh-catalyzed sulfonic acid group directed ortho C-H olefination of arenes.
Q57998092	Rhenium-Catalyzed Annulation Reactions
Q35840435	Rhodium catalyzed chelation-assisted C-H bond functionalization reactions
Q42269950	Rhodium catalyzed synthesis of isoindolinones via C-H activation of N-benzoylsulfonamides
Q93135816	Rhodium catalyzed template-assisted distal para-C-H olefination
Q43717873	Rhodium(I)-catalyzed redox-economic cross-coupling of carboxylic acids with arenes directed by N-containing groups
Q41846584	Rhodium(III)-Catalyzed Allylic C(sp(3))-H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles
Q35786911	Rhodium(III)-Catalyzed ortho-Heteroarylation of Phenols through Internal Oxidative C-H Activation: Rapid Screening of Single-Molecular White-Light-Emitting Materials
Q37165304	Rhodium(III)-catalyzed alkenyl C-H bond functionalization: convergent synthesis of furans and pyrroles
Q53599788	Rhodium(III)-catalyzed alkenylation reactions of 8-methylquinolines with alkynes by C(sp3)-H activation.
Q44369251	Rhodium(III)-catalyzed amidation of aryl ketone O-methyl oximes with isocyanates by C-H activation: convergent synthesis of 3-methyleneisoindolin-1-ones
Q34608941	Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization
Q46747147	Rhodium(III)-catalyzed azidation and nitration of arenes by C-H activation.
Q36851892	Rhodium(III)-catalyzed indazole synthesis by C-H bond functionalization and cyclative capture
Q51067037	Rhodium(III)-catalyzed olefinic C-H alkynylation of enamides at room temperature.
Q45803978	Rhodium(III)-catalyzed synthesis of cyclopenta[b]pyrroles from 1,2-diketones, 2-aminopyridine, and alkynes
Q64099696	Rhodium(iii)-catalyzed diverse [4 + 1] annulation of arenes with 1,3-enynes sp/sp C-H activation and 1,4-rhodium migration
Q36290673	Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes
Q59899117	Rhodium-Catalysed Enantioselective C-H Functionalization in Asymmetric Synthesis
Q51653595	Rhodium-Catalyzed Intramolecular C-H Bond Activation with Triazoles: Preparation of Stereodefined Pyrrolidines and Other Related Cyclic Compounds.
Q57404773	Rhodium-Catalyzed Oxidative Annulation of Sulfoximines and Alkynes as an Approach to 1,2-Benzothiazines
Q50946483	Rhodium-catalyzed C-H activation of hydrazines leads to isoquinolones with tunable aggregation-induced emission properties.
Q42042310	Rhodium-catalyzed annulation of N-benzoylsulfonamide with isocyanide through C-H activation
Q53663229	Rhodium-catalyzed annulative coupling of 3-phenylthiophenes with alkynes involving double C-H bond cleavages.
Q50526191	Rhodium-catalyzed direct addition of aryl C-H bonds to N-sulfonyl aldimines.
Q53450186	Rhodium-catalyzed olefination of aryl tetrazoles via direct C-H bond activation.
Q43447542	Rhodium-catalyzed ortho acylation of aromatic carboxylic acids.
Q43467594	Rhodium-catalyzed spirocyclic sultam synthesis by [3+2] annulation with cyclic N-sulfonyl ketimines and alkynes
Q35936059	Rhodium-catalyzed synthesis of branched amines by direct addition of benzamides to imines
Q42168610	Room temperature C-H activation and cross-coupling of aryl ureas in water
Q34509995	Room-Temperature Direct β-Arylation of Thiophenes and Benzo[b]thiophenes and Kinetic Evidence for a Heck-type Pathway
Q39331995	Room-temperature C-H arylation: merger of Pd-catalyzed C-H functionalization and visible-light photocatalysis
Q82476615	Ru-catalyzed aerobic oxidative coupling of arylboronic acids with arenes
Q50921429	Ruthenium Oxidase Catalysis for Site-Selective C-H Alkenylations with Ambient O2 as the Sole Oxidant.
Q49823810	Ruthenium catalyzed remote C4-selective C-H functionalisation of carbazoles via σ-activation.
Q59274269	Ruthenium(II)-Catalyzed CH Bond Activation: An Efficient Route toward Indenamines
Q48330567	Ruthenium(II)-Catalyzed meta C-H Mono- and Difluoromethylations by Phosphine/Carboxylate Cooperation
Q57905598	Ruthenium(II)-Catalyzed meta C−H Mono- and Difluoromethylations by Phosphine/Carboxylate Cooperation
Q42200049	Ruthenium(II)-catalysed remote C-H alkylations as a versatile platform to meta-decorated arenes
Q47892077	Ruthenium(II)-catalyzed synthesis of isochromenes by C-H activation with weakly coordinating aliphatic hydroxyl groups
Q35026649	Ruthenium(II)/N-heterocyclic carbene catalyzed [3+2] carbocyclization with aromatic N-H ketimines and internal alkynes
Q58656121	Ruthenium(ii) oxidase catalysis for C–H alkenylations in biomass-derived γ-valerolactone
Q52357426	Ruthenium(η⁶,η¹-arene-CH₂-NHC) Catalysts for Direct Arylation of 2-Phenylpyridine with (Hetero)Aryl Chlorides in Water.
Q44918335	Ruthenium- and rhodium-catalyzed oxidative alkylation of C-H bonds: efficient access to β-aryl ketones
Q52933558	Ruthenium-Catalyzed Monoalkenylation of Aromatic Ketones by Cleavage of Carbon-Heteroatom Bonds with Unconventional Chemoselectivity.
Q44011588	Ruthenium-catalyzed C-H/O-H and C-H/N-H bond functionalizations: oxidative annulations of cyclopropyl-substituted alkynes
Q53151698	Ruthenium-catalyzed hydroarylation of methylenecyclopropanes through C-H bond cleavage: scope and mechanism.
Q44207702	Ruthenium-catalyzed α-(hetero)arylation of saturated cyclic amines: reaction scope and mechanism
Q34989553	Ruthenium-catalyzed γ-carbolinium ion formation from aryl azides; synthesis of dimebolin
Q42175339	Scope and limitations of auxiliary-assisted, palladium-catalyzed arylation and alkylation of sp2 and sp3 C-H bonds.
Q38366711	Selective Aromatic C-H Hydroxylation Enabled by η(6)-Coordination to Iridium(III).
Q48253475	Selective Palladium-Catalyzed Allenic C-H Bond Oxidation for the Synthesis of [3]Dendralenes.
Q42633474	Selective sp3 C-H alkylation via polarity-match-based cross-coupling
Q42741143	Sequential allylic C-H amination/vinylic C-H arylation: a strategy for unnatural amino acid synthesis from α-olefins
Q43124422	Sequential decarboxylative azide-alkyne cycloaddition and dehydrogenative coupling reactions: one-pot synthesis of polycyclic fused triazoles
Q35166668	Silanol: a traceless directing group for Pd-catalyzed o-alkenylation of phenols
Q52816511	Silver-catalyzed C2-selective direct alkylation of heteroarenes with tertiary cycloalkanols.
Q55510039	Silver-catalyzed remote Csp3-H functionalization of aliphatic alcohols.
Q41671104	Single operation palladium catalysed C(sp3)-H functionalisation of tertiary aldehydes: investigations into transient imine directing groups
Q52897856	Single-Component Phosphinous Acid Ruthenium(II) Catalysts for Versatile C-H Activation by Metal-Ligand Cooperation.
Q64214490	Site-selective C–H arylation of primary aliphatic amines enabled by a catalytic transient directing group
Q48042933	Sn- and Pd-Free Synthesis of D-π-A Organic Sensitizers for Dye-Sensitized Solar Cells by Cu-Catalyzed Direct Arylation.
Q49832053	Solvent-Driven Iodine-Mediated Oxidative Strategies for the Synthesis of Bis(imidazo[1,2-a]pyridin-3-yl)sulfanes and Disulfanes
Q42866090	Solvent-free aromatic C–H functionalisation/halogenation reactions
Q33583746	Sonogashira diversification of unprotected halotryptophans, halotryptophan containing tripeptides; and generation of a new to nature bromo-natural product and its diversification in water.
Q27324625	Spacer-free BODIPY fluorogens in antimicrobial peptides for direct imaging of fungal infection in human tissue
Q43861749	Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation: formal synthesis of aspergillide A.
Q51697271	Stereospecific Pd-Catalyzed Intermolecular C(sp(3))-C(sp) Cross-Coupling of Diarylmethyl Carbonates and Terminal Alkynes Under Base-Free Conditions.
Q40832116	Strain release in C-H bond activation?
Q45891819	Substituent-guided switch between C-H activation and decarboxylative cross-coupling during palladium/copper-catalyzed cascade reactions of 2-aminobenzoates with 2-haloarylaldehydes
Q36953400	Substituted 2,2'-bipyrroles and pyrrolylfurans via intermediate isoxazolylpyrroles
Q51054649	Sulfonamide-promoted palladium(II)-catalyzed alkylation of unactivated methylene C(sp3)-H bonds with alkyl iodides.
Q55224665	Sulfoxide-directed metal-free cross-couplings in the expedient synthesis of benzothiophene-based components of materials.
Q50911128	Synchronous double C-N bond formation via C-H activation for a novel synthetic route to phenazine.
Q53735595	Syntheses via a direct arylation method of push-pull molecules based on triphenylamine and 3-cyano-4-hexyloxythiophene moieties.
Q57749485	Synthesis and Application of Tetrahydro-2H-fluorenes by a Pd(0)-Catalyzed Benzylic C(sp3)−H Functionalization
Q43837571	Synthesis and X-ray characterization of novel palladium(II) complexes with tunable chiral anionic counterions
Q58035068	Synthesis and biological evaluation of a post-synthetically modified Trp-based diketopiperazine
Q50225097	Synthesis and photophysics of extended π-conjugated systems of substituted 10-aryl-pyrenoimidazoles
Q36675411	Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp(3))-H bonds
Q48225251	Synthesis of Bicyclo[n.1.0]alkanes by a Cobalt-Catalyzed Multiple C(sp3 )-H Activation Strategy
Q57657288	Synthesis of Olefin-Oxazoline Ligands (OlefOx) by Rhodium(III)-Catalyzed Oxidative Olefination
Q44545915	Synthesis of Phenanthridinones from N-methoxybenzamides and aryltriethoxysilanes through Rh(III)-catalyzed C-H and N-H bond activation.
Q57404811	Synthesis of Planar Chiral Carbazole Derivatives Bearing a [2.2]Paracyclophane Skeleton
Q57905729	Synthesis of Tetrasubstituted Alkenes through a Palladium-Catalyzed Domino Carbopalladation/CH-Activation Reaction
Q48249421	Synthesis of Triarylpyridines in Thiopeptide Antibiotics by Using a C-H Arylation/Ring-Transformation Strategy
Q40124799	Synthesis of a Bicyclic Azetidine with In Vivo Antimalarial Activity Enabled by Stereospecific, Directed C(sp3)-H Arylation
Q52881826	Synthesis of asymmetrically substituted terpyridines by palladium-catalyzed direct C-H arylation of pyridine N-oxides.
Q43601100	Synthesis of azahelicene N-oxide by palladium-catalyzed direct C-H annulation of a pendant (Z)-bromovinyl side chain
Q42211858	Synthesis of complex allylic esters via C-H oxidation vs C-C bond formation
Q38433859	Synthesis of cyclic enones via direct palladium-catalyzed aerobic dehydrogenation of ketones
Q38917475	Synthesis of esters via sp(3) C-H functionalisation
Q43122362	Synthesis of fluorene and indenofluorene compounds: tandem palladium-catalyzed suzuki cross-coupling and cyclization
Q57657240	Synthesis of fluorenones viaquaternary ammonium salt-promoted intramolecular dehydrogenative arylation of aldehydes
Q38439206	Synthesis of heterocyclic-fused benzopyrans via the Pd(II)-catalyzed C-H alkenylation/C-O cyclization of flavones and coumarins
Q39187395	Synthesis of imidazo[1,2-a]pyridines: C-H functionalization in the direction of C-S bond formation
Q53208539	Synthesis of isoindolinones via palladium-catalyzed C-H activation of N-methoxybenzamides.
Q51567649	Synthesis of isoquinolines from α-aryl vinyl azides and internal alkynes by Rh-Cu bimetallic cooperation.
Q51015603	Synthesis of novel azole-fused quinazolines via one-pot, sequential Ullmann-type coupling and intramolecular dehydrogenative C-N bonding.
Q46864000	Synthesis of pyrrolophenanthridine alkaloids based on C(sp³)-H and C(sp²)-H functionalization reactions.
Q51281296	Synthesis of β-acetoxy alcohols by PhI(OAc)2-mediated metal-free diastereoselective β-acetoxylation of alcohols.
Q26747345	Synthetic Organic Electrochemistry: An Enabling and Innately Sustainable Method
Q35825220	TADDOL-based phosphorus(III)-ligands in enantioselective Pd(0)-catalysed C-H functionalisations
Q51819984	TIPS-TTF as a precursor of low-symmetry TTF derivatives: steric protection strategy in the regioselective C-H modification of TTF.
Q39308428	TPGS-750-M: a second-generation amphiphile for metal-catalyzed cross-couplings in water at room temperature.
Q50482036	Tandem oxidation-oxidative C-H/C-H cross-coupling: synthesis of arylquinones from hydroquinones.
Q48292790	Teaching Old Compounds New Tricks: DDQ-Photocatalyzed C-H Amination of Arenes with Carbamates, Urea, and N-Heterocycles
Q89703150	Tertiary amine-directed and involved carbonylative cyclizations through Pd/Cu-cocatalyzed multiple C-X (X = H or N) bond cleavage
Q48350596	Tertiary-Alcohol-Directed Functionalization of Remote C(sp3 )-H Bonds by Sequential Hydrogen Atom and Heteroaryl Migrations.
Q88510163	Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions
Q40852763	The Mechanism of N-O Bond Cleavage in Rhodium-Catalyzed C-H Bond Functionalization of Quinoline N-oxides with Alkynes: A Computational Study.
Q37400739	The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes.
Q50526196	The catalytic ability of various transition metals in the direct functionalization of aromatic C-H bonds.
Q38161496	The cross-dehydrogenative coupling of C(sp3)-H bonds: a versatile strategy for C-C bond formations
Q55077095	The design of a readily attachable and cleavable molecular scaffold for ortho-selective C–H alkenylation of arene alcohols† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc03948g.
Q48152516	The first palladium(iv) aryldiazenido complex: relevance for C-C coupling.
Q52575991	The mechanism of directed Ni(ii)-catalyzed C-H iodination with molecular iodine.
Q59721761	The mechanism of palladium(II)-mediated C–H cleavage with mono-N-protected amino acid (MPAA) ligands: origins of rate acceleration
Q33814105	The total synthesis of K-252c (staurosporinone) via a sequential C-H functionalisation strategy
Q47937781	The underlying factors controlling the Pd-catalyzed site-selective alkenylation of aliphatic amines
Q39297866	The use of carboxylic acids as traceless directing groups for regioselective C-H bond functionalisation.
Q37737101	Theoretical aspects of palladium-catalysed carbon-carbon cross-coupling reactions
Q86006589	Theoretical studies of palladium-catalyzed cycloaddition of alkynyl aryl ethers and alkynes
Q45090035	Toluene derivatives as simple coupling precursors for cascade palladium-catalyzed oxidative C-H bond acylation of acetanilides.
Q90434417	Total Synthesis and Stereochemical Assignment of Streptide
Q48272880	Total Synthesis of Aurofusarin: Studies on the Atropisomeric Stability of Bis-Naphthoquinones
Q50928739	Total Synthesis of Codeine.
Q42843279	Total Synthesis of Diptoindonesin G via a Highly Efficient Domino Cyclodehydration/Intramolecular Friedel−Crafts Acylation/Regioselective Demethylation Sequence
Q53182266	Total Synthesis of cis-Clavicipitic Acid from Asparagine via Ir-Catalyzed C-H bond Activation as a Key Step.
Q34339731	Total synthesis of (+)-linoxepin by utilizing the Catellani reaction
Q51430583	Total synthesis of protosappanin A and its derivatives via palladium catalyzed ortho C-H activation/C-C cyclization under microwave irradiation.
Q46472332	Towards ideal synthesis: alkenylation of aryl C-H bonds by a Fujiwara-Moritani reaction.
Q92929440	Transient Ligand-Enabled Transition Metal-Catalyzed C-H Functionalization
Q38293386	Transition metal catalyzed meta-C-H functionalization of aromatic compounds
Q37867002	Transition metal-catalyzed arylation of unactivated C(sp3)-H bonds
Q35049991	Transition metal-catalyzed decarboxylative allylation and benzylation reactions
Q38549312	Transition metal-catalyzed ketone-directed or mediated C-H functionalization.
Q36517170	Transition metal-free intramolecular regioselective couplings of aliphatic and aromatic C-H bonds
Q50226719	Transition-Metal-Catalyzed Redox-Neutral and Redox-Green C-H Bond Functionalization.
Q52744311	Transition-metal-free atropo-selective synthesis of biaryl compounds based on arynes.
Q44051653	Trifluoromethanesulfonic acid catalyzed synergetic oxidative/[3+2] cyclization of quinones with olefins
Q39329176	Triiodide-Mediated δ-Amination of Secondary C-H Bonds.
Q46908517	Trinuclear Pd₃O₂ intermediate in aerobic oxidation catalysis
Q35233781	Tuning reactivity and site selectivity of simple arenes in C-H activation: ortho-arylation of anisoles via arene-metal π-complexation.
Q42875614	Umpolung Direct Arylation Reactions: Facile Process Requiring Only Catalytic Palladium and Substoichiometric Amount of Silver Salts
Q57657290	Undirected Arene and Chelate-Assisted Olefin C-H Bond Activation: [RhIIICp*]-Catalyzed Dehydrogenative Alkene-Arene Coupling as a New Pathway for the Selective Synthesis of Highly SubstitutedZOlefins
Q64936711	Unraveling innate substrate control in site-selective palladium-catalyzed C-H heterocycle functionalization.
Q36651992	Unstabilized azomethine ylides for the stereoselective synthesis of substituted piperidines, tropanes, and azabicyclo[3.1.0] systems
Q44981550	Use of a readily removable auxiliary group for the synthesis of pyrrolidones by the palladium-catalyzed intramolecular amination of unactivated γ C(sp(3))-H bonds
Q58169581	Use of dimethyl carbonate as a solvent greatly enhances the biaryl coupling of aryl iodides and organoboron reagents without adding any transition metal catalysts
Q50449602	Use of the Wilkinson catalyst for the ortho-C-H heteroarylation of aromatic amines: facile access to highly extended π-conjugated heteroacenes for organic semiconductors
Q38195732	Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization
Q47430115	Visible-Light-Driven Palladium-Catalyzed Radical Alkylation of C-H Bonds with Unactivated Alkyl Bromides.
Q92298783	Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp3)-H Bond Allylation
Q41883293	Visible-light-driven oxidation of primary C-H bonds over CdS with dual co-catalysts graphene and TiO2.
Q41903948	[1,2-Bis(diphenyl-phosphan-yl)ethane-κP,P']{2-[(4-nitro-benzoyl-meth-yl)diphenyl-phosphan-yl]phenyl-κC,C'}palladium(II) trifluoro-methane-sulfonate-dichloro-methane-n-hexane (1/1/0.5).
Q31101298	[N,P]-pyrrole PdCl2 complexes catalyzed the formation of dibenzo-α-pyrone and lactam analogues
Q46583562	[RuCl₂(η⁶-p-cymene)] complexes bearing phosphinous acid ligands: preparation, application in C-H bond functionalization and mechanistic investigations
Q48284951	ortho-C-H Arylation of Benzoic Acids with Aryl Bromides and Chlorides Catalyzed by Ruthenium
Q45309453	ortho-Phenylene bridged palladium bis-N-heterocyclic carbene complexes: synthesis, structure and catalysis
Q64107629	para-Selective C-H Olefination of Aniline Derivatives via Pd/S,O-Ligand Catalysis
Q49011763	para-Selective C-H bond functionalization of iodobenzenes
Q85075996	syn‐Selective Rhodium(I)‐Catalyzed Allylations of Ketimines Proceeding through a Directed CH Activation/Allene Addition Sequence
Q51028801	β-Functionalization of carboxylic anhydrides with β-alkyl substituents through carbene organocatalysis.

review article	Q7318358
scholarly article	Q13442814

P356	DOI	10.1002/ANIE.200806273
P932	PMC publication ID	2722958
P698	PubMed publication ID	19557755
P5875	ResearchGate publication ID	26322014

P50	author	Dong-Hui Wang	Q48355999
		Keary M Engle	Q49956200
P2093	author name string	Xiao Chen
		Jin-Quan Yu
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		A solution to the 2-pyridyl organometallic cross-coupling problem: regioselective catalytic direct arylation of pyridine N-oxides.	Q34478183
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		Perspective on dirhodium carboxamidates as catalysts	Q36853338
		Copper-catalyzed arylation and alkenylation of polyfluoroarene C-H bonds	Q36876264
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		Versatile Pd(II)-catalyzed C-H activation/aryl-aryl coupling of benzoic and phenyl acetic acids	Q37071814
		Remarkably selective iridium catalysts for the elaboration of aromatic C-H bonds	Q77221357
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		The palladium-catalyzed C-H activation of benzylic gem-dialkyl groups	Q79352081
		Molecular recognition in the selective oxygenation of saturated C-H bonds by a dimanganese catalyst	Q79816001
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		Direct C-H arylation of (hetero)arenes with aryl iodides via rhodium catalysis	Q80214812
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		Intramolecular C-H amination reactions: exploitation of the Rh(2)(II)-catalyzed decomposition of azidoacrylates	Q80378798
		The catalytic cross-coupling of unactivated arenes	Q80382134
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		Suzuki-Miyaura coupling reaction by PdII-catalyzed aromatic C-H bond activation directed by an N-alkyl acetamino group	Q80501745
		C-H functionalization/C-N bond formation: copper-catalyzed synthesis of benzimidazoles from amidines	Q80568107
		FeCl2-catalyzed selective C--C bond formation by oxidative activation of a benzylic C--H bond	Q80678463
		Synthesis of rhazinicine by a metal-catalyzed C-H bond functionalization strategy	Q80865640
		Palladium-catalyzed benzylic C-H insertion of 2-substituted N-iminopyridinium ylides	Q80930033
		Ortho alkylation of aromatic ketimine with functionalized alkene by Rh(I) catalyst	Q81087337
		Intramolecular palladium-catalyzed direct arylation of alkenyl triflates	Q81238064
		Pd(II)-catalyzed enantioselective activation of C(sp2)-H and C(sp3)-H bonds using monoprotected amino acids as chiral ligands	Q81289986
		Pd-catalyzed stereoselective oxidation of methyl groups by inexpensive oxidants under mild conditions: a dual role for carboxylic anhydrides in catalytic C--H bond oxidation	Q81399579
		Consecutive vinylic to aryl to allylic palladium migration and multiple C-H activation processes	Q81403665
		Palladium-catalyzed asymmetric iodination of unactivated C-H bonds under mild conditions	Q81437346
		Copper-catalyzed "click" reaction/direct arylation sequence: modular syntheses of 1,2,3-triazoles	Q81444655
		Palladium-catalyzed C-H functionalization of pyridine N-oxides: highly selective alkenylation and direct arylation with unactivated arenes	Q81529850
		Catalytic coupling of haloolefins with anilides	Q81556786
		Multiple C-H activations to construct biologically active molecules in a process completely free of organohalogen and organometallic components	Q81557742
		High-yielding palladium-catalyzed intramolecular alkane arylation: reaction development and mechanistic studies	Q81559366
		Palladium-catalyzed intermolecular alkenylation of indoles by solvent-controlled regioselective C-H functionalization	Q81645699
		Enantioselective C-H amination using cationic ruthenium(II)-pybox catalysts	Q81672732
		Iron-catalyzed C-C bond formation by direct functionalization of C-H bonds adjacent to heteroatoms	Q81775261
		Anilide ortho-arylation by using C-H activation methodology	Q81778955
		Intermolecular hydroarylation of unactivated olefins catalyzed by homogeneous platinum complexes	Q81827188
		Synthesis of 3,4-dihydroisoquinolines by a C(sp3)-H activation/electrocyclization strategy: total synthesis of coralydine	Q82735825
		Palladium-catalyzed direct arylations of heteroarenes with tosylates and mesylates	Q82757701
		Aryl transfer between Pd(II) centers or Pd(IV) intermediates in Pd-catalyzed domino reactions	Q83142122
		Chemoselective benzylic C-H activations for the preparation of condensed N-heterocycles	Q83198901
		Catalytic C-H arylation of SEM-protected azoles with palladium complexes of NHCs and phosphines	Q83280664
		Cu(II)-catalyzed functionalizations of aryl C-H bonds using O2 as an oxidant	Q83830369
		A Convenient and General Method for Pd-Catalyzed Suzuki Cross-Couplings of Aryl Chlorides and Arylboronic Acids	Q88520152
		Unusual Palladium-Catalyzed Cascade Arylation of alpha,beta-Unsaturated Phenyl Sulfones under Heck Reaction Conditions Financial support for this work by the Ministerio de Educación y Cultura (DGES, project PB96-0021), Ministerio de Ciencia y Tecnol	Q95350204
		Enantioselective silyl protection of alcohols catalysed by an amino-acid-based small molecule	Q48664821
		Ru-catalyzed oxidative coupling of arenes with olefins using O(2).	Q49298679
		Indirect ortho functionalization of substituted toluenes through ortho olefination of N,N-dimethylbenzylamines tuned by the acidity of reaction conditions.	Q50682203
		Ortho arylation of acetanilides via Pd(II)-catalyzed C-H functionalization.	Q50687735
		Organometallic chemistry: C-H activation.	Q53199987
		Two methods for direct ortho-arylation of benzoic acids.	Q53538805
		Activation of C−H Bonds by Metal Complexes	Q55933283
		Thermal, Catalytic, Regiospecific Functionalization of Alkanes	Q55951778
		Palladium-Catalyzed sp3CH Activation of Simple Alkyl Groups: Direct Preparation of Indoline Derivatives fromN-Alkyl-2-bromoanilines	Q57261602
		Site-Selective Derivatization and Remodeling of Erythromycin A by Using Simple Peptide-Based Chiral Catalysts	Q57581213
		Catalytic and Highly Regioselective Cross-Coupling of Aromatic C−H Substrates	Q57944544
		Room Temperature Palladium-Catalyzed 2-Arylation of Indoles	Q57944596
		Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights	Q57944603
		Transition Metal-Catalyzed Activation of Aliphatic C−X Bonds in Carbon−Carbon Bond Formation	Q59222212
		Palladium-Catalyzed Methylation and Arylation of sp2and sp3C−H Bonds in Simple Carboxylic Acids	Q59350168
		Efficient activation of aromatic C-H bonds for addition to C-C multiple bonds	Q73556201
		Toward waste-free production of Heck products with a catalytic palladium system under oxygen	Q73758730
		Enantioselective catalytic aziridinations and asymmetric nitrene insertions into CH bonds	Q73800405
		Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis	Q73800409
		Enantioselective oxidative biaryl coupling reactions catalyzed by 1,5-diazadecalin metal complexes	Q73868058
		Palladium-catalyzed enantioselective oxidations of alcohols using molecular oxygen	Q74263069
		Palladium-catalyzed cross-coupling reactions of organosilanols and their salts: practical alternatives to boron- and tin-based methods	Q37110928
		Pd(II)-catalyzed olefination of electron-deficient arenes using 2,6-dialkylpyridine ligands	Q37154137
		A general method for copper-catalyzed arylation of arene C-H bonds	Q37339126
		A chiral rhodium carboxamidate catalyst for enantioselective C-H amination	Q41142047
		Aspartate-catalyzed asymmetric epoxidation reactions	Q41766170
		Insights into directing group ability in palladium-catalyzed C-H bond functionalization	Q42537260
		A chiral Lewis acid strategy for enantioselective allylic C-H oxidation	Q43078980
		Distinct reactivity of Pd(OTs)2: the intermolecular Pd(II)-catalyzed 1,2-carboamination of dienes	Q43139123
		C-C bond formation via double C-H functionalization: aerobic oxidative coupling as a method for synthesizing heterocoupled biaryls	Q43203010
		Highly efficient and enantioselective cyclization of aromatic imines via directed C-H bond activation	Q43511804
		The Pd-catalyzed coupling of allyl halides and tin aryls: why the catalytic reaction works and the stoichiometric reaction does not.	Q43669141
		A short synthetic route to (+)-austamide, (+)-deoxyisoaustamide, and (+)-hydratoaustamide from a common precursor by a novel palladium-mediated indole --> dihydroindoloazocine cyclization	Q44048696
		Structural and mechanistic investigations of the oxidation of dimethylplatinum(II) complexes by dioxygen.	Q44051546
		The palladium-catalyzed oxidative kinetic resolution of secondary alcohols with molecular oxygen	Q44152693
		C-C bond formation via C-H bond activation: synthesis of the core of teleocidin B4.	Q44162878
		Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation	Q44284577
		Direct coupling of benzene with olefin catalyzed by Pd(OAc)(2) combined with heteropolyoxometalate under dioxygen	Q44303362
		A ruthenium-catalyzed reaction of aromatic ketones with arylboronates: a new method for the arylation of aromatic compounds via C-H bond cleavage	Q44311256
		Application of chiral mixed phosphorus/sulfur ligands to enantioselective rhodium-catalyzed dehydroamino acid hydrogenation and ketone hydrosilylation processes	Q44366366
		Homogeneous catalysis with methane. A strategy for the hydromethylation of olefins based on the nondegenerate exchange of alkyl groups and sigma-bond metathesis at scandium	Q44488805
		Catalytic C-H bond functionalization with palladiumII: aerobic oxidative annulations of indoles	Q44540120
		Synthesis of Substituted Oxindoles from α-Chloroacetanilides via Palladium-Catalyzed C−H Functionalization	Q44602269
		Dehydroabietic acid derivatives as a novel scaffold for large-conductance calcium-activated K+ channel openers.	Q44638668
		A highly selective catalytic method for the oxidative functionalization of C-H bonds	Q44775636
		New ligands for a general palladium-catalyzed amination of aryl and heteroaryl chlorides	Q44949664
		Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds	Q45005364
		Palladium-catalyzed cyclization/carboalkoxylation of alkenyl indoles	Q45021310
		Selective Pd-catalyzed oxidative coupling of anilides with olefins through C-H bond activation at room temperature	Q45712253
		The norbornene shuttle: multicomponent domino synthesis of tetrasubstituted helical alkenes through multiple C--H functionalization	Q46161955
		Synthesis of benzocyclobutenes by palladium-catalyzed C-H activation of methyl groups: method and mechanistic study	Q46312045
		Synthesis of 1,2- and 1,3-dicarboxylic acids via Pd(II)-catalyzed carboxylation of aryl and vinyl C-H bonds	Q46333063
		Directed palladation: fine tuning permits the catalytic 2-alkenylation of indoles	Q46408590
		Palladium-catalyzed direct C-2 arylation of indoles with potassium aryltrifluoroborate salts	Q46430237
		Serial ligand catalysis: a highly selective allylic C-H oxidation	Q46482828
		Synthesis of indolines and tetrahydroisoquinolines from arylethylamines by Pd(II)-catalyzed C-H activation reactions	Q46485952
		Cu(II)-catalyzed direct and site-selective arylation of indoles under mild conditions	Q46548054
		Enantioselective alkyl-alkyl Suzuki cross-couplings of unactivated homobenzylic halides	Q46618656
		Iron-catalyzed direct arylation through directed C-H bond activation	Q46646482
		Alkane coordination selectivity in hydrocarbon activation by [Tp'Rh(CNneopentyl)]: the role of alkane complexes	Q46677328
		Unusually stable palladium(IV) complexes: detailed mechanistic investigation of C-O bond-forming reductive elimination	Q46700504
		Highly regioselective arylation of sp3 C-H bonds catalyzed by palladium acetate	Q46712613
		Palladium(II)-catalyzed direct arylation of enaminones using organotrifluoroborates	Q46718004
		Computational study of the mechanism of cyclometalation by palladium acetate	Q46733183
		Pd(II)-catalyzed cross-coupling of sp3 C-H Bonds with sp2 and sp3 boronic acids using air as the oxidant	Q46745147
		Palladium-catalyzed direct arylation of (hetero)arenes with aryl boronic acids	Q46788234
		Aryl triflates: useful coupling partners for the direct arylation of heteroaryl derivatives via Pd-catalyzed C-H activation-functionalization	Q46853868
		Palladium-catalyzed alkylation of aryl C-H bonds with sp3 organotin reagents using benzoquinone as a crucial promoter	Q46877074
		A convergent synthesis of polysubstituted aromatic nitriles via palladium-catalyzed C-H functionalization.	Q46895176
		Mild aerobic oxidative palladium (II) catalyzed C-H bond functionalization: regioselective and switchable C-H alkenylation and annulation of pyrroles	Q46955376
		Annulative tandem reactions based on Pd0/tBu3P-catalyzed cross-coupling and C(sp3)-H bond activation	Q46976710
		Direct C-H bond arylation of arenes with aryltin reagents catalysed by palladium complexes	Q47848285
P433	issue	28
P407	language of work or name	English	Q1860
P921	main subject	palladium	Q1089
P304	page(s)	5094-5115
P577	publication date	2009-01-01
P1433	published in	Angewandte Chemie International Edition	Q62023953
P1476	title	Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality
P478	volume	48

Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality

scientific article published on January 2009

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