Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C-H hydroxylation and amination

scientific article published on 26 September 2016

Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C-H hydroxylation and amination is …
instance of (P31):
scholarly articleQ13442814

External links are
P356DOI10.1039/C6SC03383K
P932PMC publication ID5452263
P698PubMed publication ID28572906

P50authorJin-Quan YuQ27887829
P2093author name stringHui Xu
Qian Shao
Hui-Xiong Dai
Ming Shang
Shang-Zheng Sun
Yan-Qiao Chen
P2860cites workPalladium-Catalyzed Ligand-Directed C−H Functionalization ReactionsQ29012891
Weak coordination as a powerful means for developing broadly useful C-H functionalization reactionsQ30410596
Ligand-enabled reactivity and selectivity in a synthetically versatile aryl C-H olefinationQ33444520
Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activationQ33645846
Pd(II)-catalyzed olefination of sp3 C-H bondsQ33738148
Highly convergent total synthesis of (+)-lithospermic acid via a late-stage intermolecular C-H olefinationQ34173776
Copper-catalyzed trifluoromethylation of unactivated olefinsQ34216544
A solution to the 2-pyridyl organometallic cross-coupling problem: regioselective catalytic direct arylation of pyridine N-oxides.Q34478183
Activation of remote meta-C-H bonds assisted by an end-on templateQ36067509
Copper-promoted sulfenylation of sp2 C-H bondsQ36399655
Ligand-enabled methylene C(sp3)-H bond activation with a Pd(II) catalystQ36405081
Copper-catalyzed, directing group-assisted fluorination of arene and heteroarene C-H bondsQ37069922
Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicalityQ37294999
Pd(0)/PR3-catalyzed intermolecular arylation of sp3 C-H bondsQ37307778
Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivityQ37619282
Natural phenolic compounds from medicinal herbs and dietary plants: potential use for cancer preventionQ37665361
Towards mild metal-catalyzed C-H bond activationQ37888484
Aryl-CF(3) bond-forming reductive elimination from palladium(IV)Q39400915
Ligand-accelerated cross-coupling of C(sp2)-H bonds with arylboron reagentsQ39588170
Ligand-enabled γ-C-H olefination and carbonylation: construction of β-quaternary carbon centersQ40430050
Copper-catalyzed etherification of arene C-H bondsQ41850348
Ligand-Enabled Stereoselective β-C(sp(3))-H Fluorination: Synthesis of Unnatural Enantiopure anti-β-Fluoro-α-amino AcidsQ42015434
Overcoming the limitations of directed C-H functionalizations of heterocyclesQ42100068
Directed amination of non-acidic arene C-H bonds by a copper-silver catalytic systemQ42157831
Ligand-accelerated C-H activation reactions: evidence for a switch of mechanismQ42161197
Room-temperature enantioselective C-H iodination via kinetic resolutionQ42652825
Ligand-controlled C(sp³)-H arylation and olefination in synthesis of unnatural chiral α-amino acidsQ42920887
Copper(II)-catalyzed ortho-acyloxylation of the 2-arylpyridines sp(2) C-H bonds with anhydrides, using O(2) as terminal oxidantQ43135617
Copper-catalyzed electrophilic amination of heteroarenes and arenes by C-H zincationQ43144651
Ruthenium-catalyzed C-H oxygenation on aryl Weinreb amidesQ85934710
N-Acyl Amino Acid Ligands for Ruthenium(II)-Catalyzed meta-C-H tert-Alkylation with Removable AuxiliariesQ86315388
Copper-mediated C-H/C-H biaryl coupling of benzoic acid derivatives and 1,3-azolesQ86433705
β-Arylation of carboxamides via iron-catalyzed C(sp3)-H bond activationQ86586142
Cu-catalyzed mild C(sp2)-H functionalization assisted by carboxylic acids en route to hydroxylated arenesQ86937404
Ortho- and para-selective ruthenium-catalyzed C(sp2)-H oxygenations of phenol derivativesQ87001063
Ligand-Enabled, Copper-Promoted Regio- and Chemoselective Hydroxylation of Arenes, Aryl Halides, and Aryl Methyl EthersQ87070372
Cu(II)-mediated C-H amidation and amination of arenes: exceptional compatibility with heterocyclesQ87292057
Copper-mediated hydroxylation of arenes and heteroarenes directed by a removable bidentate auxiliaryQ87402472
Iron-catalyzed directed alkylation of aromatic and olefinic carboxamides with primary and secondary alkyl tosylates, mesylates, and halidesQ87406050
Copper-catalyzed intramolecular C(sp³)-H and C(sp²)-H amidation by oxidative cyclizationQ87421310
Cu(II)-mediated ortho C-H alkynylation of (hetero)arenes with terminal alkynesQ87492263
Exceedingly fast copper(II)-promoted ortho C-H trifluoromethylation of arenes using TMSCF₃Q87517069
Aldehyde-assisted ruthenium(II)-catalyzed C-H oxygenationsQ87652800
Synthesis of aryl ethers from benzoates through carboxylate-directed C-H-activating alkoxylation with concomitant protodecarboxylationQ43698555
Divergence between organometallic and single-electron-transfer mechanisms in copper(II)-mediated aerobic C-H oxidationQ45192560
Iron-catalyzed ortho-allylation of aromatic carboxamides with allyl ethersQ45784538
PdCl2 and N-hydroxyphthalimide co-catalyzed C(sp2)-H hydroxylation by dioxygen activationQ45839436
Cu(II)-Mediated C(sp(2))-H Hydroxylation.Q46016089
Carboxylate-assisted ruthenium-catalyzed alkyne annulations by C-H/Het-H bond functionalizationsQ46236096
Pd-catalyzed intermolecular C-H amination with alkylaminesQ46376388
Synthesis of 2-arylbenzoxazoles by copper-catalyzed intramolecular oxidative C-O coupling of benzanilidesQ46489689
Copper-catalyzed phosphorylation of sp(2) C-H bondsQ50449835
Copper-mediated tandem oxidative C(sp2)-H/C(sp)-H alkynylation and annulation of arenes with terminal alkynesQ50455909
Ruthenium Oxidase Catalysis for Site-Selective C-H Alkenylations with Ambient O2 as the Sole Oxidant.Q50921429
Pd(II)-catalyzed enantioselective synthesis of P-stereogenic phosphinamides via desymmetric C-H arylation.Q51019477
Synthesis of 2-aminophenols and heterocycles by Ru-catalyzed C-H mono- and dihydroxylation.Q51037913
Palladium-Catalyzed C-H Arylation of Indoles at the C7 Position.Q51588908
Copper-Catalyzed Formal [4 + 1] Cycloaddition of Benzamides and Isonitriles via Directed C-H Cleavage.Q51823706
Copper-mediated direct aryloxylation of benzamides assisted by an N,O-bidentate directing group.Q53625429
Iron-Catalyzed Directed C(sp(2))-H and C(sp(3))-H Functionalization with Trimethylaluminum.Q53659336
Palladium-catalyzed ortho-selective C-H deuteration of arenes: evidence for superior reactivity of weakly coordinated palladacycles.Q54519164
Pd(II)-catalyzed C(sp2)-H hydroxylation with R2(O)P-coordinating group.Q54637116
Intermolecular Amidation of Unactivated sp2and sp3C−H Bonds via Palladium-Catalyzed Cascade C−H Activation/Nitrene InsertionQ56028858
Rh[III]-Catalyzed Direct C–H Amination Using N-Chloroamines at Room TemperatureQ57657274
Ruthenium(II)-Catalyzed CH Activation/Alkyne Annulation by Weak Coordination with O2as the Sole OxidantQ57905650
Efficient activation of aromatic C-H bonds for addition to C-C multiple bondsQ73556201
Palladium-catalyzed alkylation of sp2 and sp3 C-H bonds with methylboroxine and alkylboronic acids: two distinct C-H activation pathwaysQ79141317
The palladium-catalyzed C-H activation of benzylic gem-dialkyl groupsQ79352081
C-H functionalization/C-N bond formation: copper-catalyzed synthesis of benzimidazoles from amidinesQ80568107
Carbon-nitrogen bond formation involving well-defined aryl-copper(III) complexesQ81529911
Copper-mediated C-H bond arylation of arenes with arylboronic acidsQ81609996
Rhodium(III)-catalyzed intermolecular direct amination of aromatic C-H bonds with N-chloroaminesQ82848856
Highly regioselective copper-catalyzed benzylic C-H amination by N-fluorobenzenesulfonimideQ82984781
Palladium-catalyzed intermolecular directed C-H amidation of aromatic ketonesQ83157752
Palladium-catalyzed C-H aminations of anilides with N-fluorobenzenesulfonimideQ83244803
Rhodium-catalyzed oxidative olefination of C-H bonds in acetophenones and benzamidesQ83300505
Copper-catalyzed amidation of 2-phenylpyridine with oxygen as the terminal oxidantQ83605183
Cobalt-catalyzed chemoselective insertion of alkene into the ortho C-H bond of benzamideQ83685766
Phenanthrene synthesis by iron-catalyzed [4+2] benzannulation between alkyne and biaryl or 2-alkenylphenyl Grignard reagentQ83804316
Cu(II)-catalyzed functionalizations of aryl C-H bonds using O2 as an oxidantQ83830369
Ruthenium(II)-catalyzed synthesis of hydroxylated arenes with ester as an effective directing groupQ84124090
Cobalt-catalyzed coupling of alkyl Grignard reagent with benzamide and 2-phenylpyridine derivatives through directed C-H bond activation under airQ84186561
Pd(II)-catalyzed hydroxylation of arenes with 1 atm of O(2) or airQ84594833
Ruthenium-catalyzed oxidative C(sp2)-H bond hydroxylation: site-selective C-O bond formation on benzamidesQ84701474
Pd-catalyzed intermolecular ortho-C-H amidation of anilides by N-nosyloxycarbamateQ84796851
Ruthenium(II)-catalyzed C-H bond activation and functionalizationQ84901619
Copper-mediated direct C(sp3)-H and C(sp2)-H acetoxylationQ85235102
Pd-catalyzed C-H oxygenation with TFA/TFAA: expedient access to oxygen-containing heterocycles and late-stage drug modificationQ85476511
Synthesis of ortho-acylphenols through the palladium-catalyzed ketone-directed hydroxylation of arenesQ85476541
Ruthenium-catalyzed C-H bond oxygenations with weakly coordinating ketonesQ85608814
Iron-catalyzed C(sp(2))-H bond functionalization with organoboron compoundsQ85652319
Cu(OAc)2-catalyzed coupling of aromatic C-H bonds with arylboron reagentsQ85820378
Cu(II)-mediated C-S/N-S bond formation via C-H activation: access to benzoisothiazolones using elemental sulfurQ85820648
Palladium-catalyzed ortho-CH-bond oxygenation of aromatic ketonesQ85862358
P433issue2
P304page(s)1469-1473
P577publication date2016-09-26
P1433published inChemical ScienceQ2962267
P1476titleIdentification of monodentate oxazoline as a ligand for copper-promoted ortho-C-H hydroxylation and amination
P478volume8