Hf(OTf)4-Catalyzed highly diastereoselective synthesis of 1,3-disubstituted tetralin derivatives via benzylic C(sp3)-H bond functionalization.

scientific article published on 3 April 2017

Hf(OTf)4-Catalyzed highly diastereoselective synthesis of 1,3-disubstituted tetralin derivatives via benzylic C(sp3)-H bond functionalization. is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1039/C7CC01717K
P698PubMed publication ID28367542

P50authorKeiji MoriQ59555298
P2093author name stringTaira Yoshida
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C-H bond functionalization via hydride transfer: synthesis of dihydrobenzopyrans from ortho-vinylaryl akyl ethersQ34198769
Asymmetric Redox-Annulation of Cyclic AminesQ36142441
Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.Q36702962
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Tunable hydride transfer in the redox amination of indoline with aldehyde: an attractive intramolecular hydrogen-bond effect.Q42835855
Enantioselective organocatalytic C-H bond functionalization via tandem 1,5-hydride transfer/ring closure: asymmetric synthesis of tetrahydroquinolinesQ42940768
Expeditious synthesis of benzopyrans via Lewis acid-catalyzed C-H functionalization: remarkable enhancement of reactivity by an ortho substituentQ43123804
Thermal cyclization of phenylallenes that contain ortho-1,3-dioxolan-2-yl groups: new cascade reactions initiated by 1,5-hydride shifts of acetalic H atoms.Q43523759
Synthesis of (-)-PNU-286607 by asymmetric cyclization of alkylidene barbituratesQ44556801
Scope of palladium-catalyzed alkylative ring openingQ44753462
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Highly enantioselective synthesis of tetrahydroquinolines via cobalt(II)-catalyzed tandem 1,5-hydride transfer/cyclization.Q50528956
Product-selectivity control by the nature of the catalyst: Lewis acid-catalyzed selective formation of ring-fused tetrahydroquinolines and tetrahydroazepines via intramolecular redox reaction.Q50544252
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High Facial Diastereoselectivity in Intra- and Intermolecular Reactions of Chiral Benzylic CationsQ56028492
Chiral α-Branched Benzylic Carbocations: Diastereoselective Intermolecular Reactions with Arene Nucleophiles and NMR Spectroscopic StudiesQ57072612
Organocatalytic Asymmetric Direct C sp 3H Functionalization of Ethers: A Highly Efficient Approach to Chiral SpiroethersQ58374761
Zinc(II)-Catalyzed Redox Cross-Dehydrogenative Coupling of Propargylic Amines and Terminal Alkynes for Synthesis of N-Tethered 1,6-EnynesQ58615253
P433issue31
P407language of work or nameEnglishQ1860
P921main subjectdiastereoselectivityQ64131393
P304page(s)4319-4322
P577publication date2017-04-03
P1433published inChemical CommunicationsQ426303
P1476titleHf(OTf)4-Catalyzed highly diastereoselective synthesis of 1,3-disubstituted tetralin derivatives via benzylic C(sp3)-H bond functionalization.
P478volume53

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cites work (P2860)
Q64916014Highly diastereoselective synthesis of tricyclic fused-pyrans by sequential hydride shift mediated double C(sp3)-H bond functionalization.
Q55054476Intramolecular hydride transfer onto arynes: redox-neutral and transition metal-free C(sp3)-H functionalization of amines.
Q90442481Redox-triggered cascade dearomative cyclizations enabled by hexafluoroisopropanol

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