Recent Advances in Multinuclear Metal Nitrosyl Complexes

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Recent Advances in Multinuclear Metal Nitrosyl Complexes is …
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scholarly articleQ13442814

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P356DOI10.1016/J.CCR.2015.03.026
P932PMC publication ID4698915
P698PubMed publication ID26744544

P2093author name stringLinlin Li
Lijuan Li
P2860cites workModeling Structures and Vibrational Frequencies for Dinitrosyl Iron Complexes (DNICs) with Density Functional TheoryQ59618731
cis-Dithiolatonickel as metalloligand to dinitrosyl iron units: the di-metallic structure of Ni(μ-SR)[Fe(NO)2] and an unexpected, abbreviated metalloadamantyl cluster, Ni2(μ-SR)4[Fe(NO)2]3Q59618736
N2S2Ni Metallothiolates as a Class of Ligands that Support Organometallic and Bioorganometallic ReactivityQ59618788
Heterobimetallics of Nickel−Iron Dinitrosyl: Electronic Control by Chelate and Diatomic LigandsQ59618825
Synthesis and characterization of {Ni(NO)}10 and {Co(NO)2}10 complexes supported by thiolate ligands.Q64914885
The bacteriocidal effects of transition metal complexes containing the NO+ group on the food-spoilage bacterium Clostridium sporogenesQ67599781
Nitrite Inhibition of Clostridium botulinum : Electron Spin Resonance Detection of Iron-Nitric Oxide ComplexesQ70155453
A Carboxylate-Bridged Non-Heme Diiron Dinitrosyl ComplexQ74822123
The 2.03 signal as an indicator of dinitrosyl-iron complexes with thiol-containing ligandsQ77675198
Synthesis and reactivity of a new octanuclear iron-sulfur nitrosyl clusterQ79212383
New members of a class of iron-thiolate-nitrosyl compounds: trinuclear iron-thiolate-nitrosyl complexes containing Fe(3)S(6) coreQ79689547
NO-disproportionation, promoted by Pd-cluster: formation and X-ray structure of Pd8(micro-CO)4(micro-OOCCMe3)8[micro-N(=O)O-]4Q79837442
Theoretical study of the reduction of nitric oxide in an A-type flavoproteinQ80224793
Developing iron nitrosyl complexes as NO donor prodrugsQ80751208
Synthesis and characterization of nitrosyl diruthenium complexes. Interaction between NO and CO across the metal-metal bondQ81035436
Nitrosylated iron-thiolate-sulfinate complexes with {Fe(NO)}6/7 electronic cores: relevance to the transformation between the active and inactive NO-bound forms of iron-containing nitrile hydratasesQ81200600
EPR, UV-Vis, IR, and X-ray demonstration of the anionic dimeric dinitrosyl iron complex [(NO)(2)Fe(micro-S(t)Bu)(2)Fe(NO)(2)](-): relevance to the products of nitrosylation of cytosolic and mitochondrial aconitases, and high-potential iron proteinsQ81362286
Homodinuclear iron thiolate nitrosyl compounds [(ON)Fe(S,S-C6H4)2 Fe(NO)2]- and [(ON)Fe(SO2,S-C6H4)(S,S-C6H4)Fe(NO)2]- with {Fe(NO)}7-{Fe(NO)2}9 electronic coupling: new members of a class of dinitrosyl iron complexesQ81678769
Dinuclear [{Fe(NO)2}(10)-{Fe(NO)2}(10)] dinitrosyl iron complex with thiolate-CO-bridged ligandsQ82766267
Discrimination of mononuclear and dinuclear dinitrosyl iron complexes (DNICs) by S K-edge X-ray absorption spectroscopy: insight into the electronic structure and reactivity of DNICsQ84209232
Structural and electronic characterization of non-heme Fe(II)-nitrosyls as biomimetic models of the Fe(B) center of bacterial nitric oxide reductaseQ84241398
New members of a class of dinitrosyliron complexes (DNICs): the characteristic EPR signal of the six-coordinate and five-coordinate {Fe(NO)2}9 DNICsQ84401285
Influence of tetraazamacrocyclic ligands on the nitric oxide reactivity of their cobalt(II) complexesQ84483454
Reactivity of polynuclear palladium carboxylate complexes towards acetonitrile: synthesis and X-ray study of Pd2(C6H4-o-C(=NH)CH3)2(CH3CO2)2 and Pd5(CH3C(=N)OC(=N)CH3)(NO)(NO2)x(RCO2)7-xQ85875958
The functional model complex [Fe2(BPMP)(OPr)(NO)2](BPh4)2 provides insight into the mechanism of flavodiiron NO reductasesQ86319972
The dinitrosyliron complex [Fe₄(μ₃-S)₂(μ₂-NO)₂(NO)₆]²⁻ containing bridging nitroxyls: ¹⁵N (NO) NMR analysis of the bridging and terminal NO-coordinate ligandsQ87861687
A combined experimental and theoretical study of dinitrosyl iron complexes containing chelating bis(diphenyl)phosphinoX (X = benzene, propane and ethylene): X-ray crystal structures and properties influenced by the presence or absence of π-bonds inQ87948868
Nitric oxide: physiology, pathophysiology, and pharmacologyQ26778243
Nitrogenase MoFe-protein at 1.16 A resolution: a central ligand in the FeMo-cofactorQ27639599
Crystal structure of the nickel-iron hydrogenase from Desulfovibrio gigasQ27730367
Crystal structure of nitrile hydratase reveals a novel iron centre in a novel foldQ27739663
Novel non-heme iron center of nitrile hydratase with a claw setting of oxygen atomsQ27757495
X-ray crystal structure of the Fe-only hydrogenase (CpI) from Clostridium pasteurianum to 1.8 angstrom resolutionQ27766099
Guanylate cyclase and the .NO/cGMP signaling pathwayQ28143751
Nitric oxide release accounts for the biological activity of endothelium-derived relaxing factorQ28299224
Endothelium-derived relaxing factor produced and released from artery and vein is nitric oxideQ29619956
Infrared spectra and density functional theory calculations on transition metal nitrosyls. Vibrational frequencies of unsaturated transition metal nitrosylsQ30309199
A two-photon antenna for photochemical delivery of nitric oxide from a water-soluble, dye-derivatized iron nitrosyl complex using NIR lightQ33236442
Polychromophoric metal complexes for generating the bioregulatory agent nitric oxide by single- and two-photon excitationQ33313614
All-trans-[ClRu(II)(py)4(NC)Ru(II)(py)4(CN)Ru(II)(py)4(NO)](PF6)4: a redox-active 2-donor/1-acceptor system based on the electrophilic {RuNO}6 motifQ33394316
Electrochemical and chemical oxidation of [Pt2(mu-pyrophosphite)4]4- revisited: characterization of a nitrosyl derivative, [Pt2(mu-pyrophosphite)4(NO)]3-.Q33410322
S-nitrosylation of proteinsQ33708021
Transcription Factor NsrR from Bacillus subtilis Senses Nitric Oxide with a 4Fe-4S Cluster (†)Q33936719
Identification of protein-bound dinitrosyl iron complexes by nuclear resonance vibrational spectroscopyQ33943868
Nitric oxide donors: chemical activities and biological applicationsQ33958494
Non-heme iron nitrosyls in biologyQ33958501
A new hexanuclear iron-selenium nitrosyl cluster: primary exploration of the preparation methods, structure, and spectroscopic and electrochemical propertiesQ33994474
Synthesis, characterization and crystal structure of a dinuclear iron nitrosyl complex with 2-mercapto-1-[2-(4-pyridyl)-ethyl]-benzimidazolyl.Q33999275
Detecting and Understanding the Roles of Nitric Oxide in BiologyQ34067402
Insights into the Nitric Oxide Reductase Mechanism of Flavodiiron Proteins from a Flavin-Free EnzymeQ34071881
NO news is good newsQ34245390
Characterization of iron dinitrosyl species formed in the reaction of nitric oxide with a biological Rieske centerQ34440627
Spin coupling in Roussin's red and black saltsQ34537503
Cloned and expressed nitric oxide synthase structurally resembles cytochrome P-450 reductaseQ34583665
Photoinduced linkage isomers of transition-metal nitrosyl compounds and related complexes.Q34593703
Mechanistic aspects of the reactions of nitric oxide with transition-metal complexesQ34593711
Structure and properties of binuclear nitrosyl iron complex with benzimidazole-2-thiolyl.Q46110357
Unusual role of solvents in the syntheses of {Fe-NO}6,7 nitrosyls derived from a ligand with carboxamido nitrogen and thiolato sulfur donorsQ46128603
Transformation of dinitrosyl iron complexes [(NO)2Fe(SR)2]- (R = Et, Ph) into [4Fe-4S] Clusters [Fe4S4(SPh)4]2-: relevance to the repair of the nitric oxide-modified ferredoxin [4Fe-4S] clustersQ46216451
Reactions of synthetic [2Fe-2S] and [4Fe-4S] clusters with nitric oxide and nitrosothiolsQ46306219
Photochemical investigation of Roussin's red salt esters: Fe2(mu-SR)2(NO)4.Q46414674
X-ray crystal structures of Moorella thermoacetica FprA. Novel diiron site structure and mechanistic insights into a scavenging nitric oxide reductaseQ46454385
Electronic effects of (N2S2)M(NO) complexes (M = Fe, Co) as metallodithiolate ligandsQ46764310
Characterization of steric and electronic properties of NiN2S2 complexes as S-donor metallodithiolate ligandsQ46838888
Photochemistry of the [Fe4(mu3-S)3(NO)7]- complex in the presence of S-nucleophiles: a spectroscopic studyQ46842749
Metallodithiolates as ligands to dinitrosyl iron complexes: toward the understanding of structures, equilibria, and spin couplingQ46849559
A tetranitrosyl [4Fe-4S] cluster forms en route to Roussin's black anion: nitric oxide reactivity of [Fe4S4(LS3)L'](2-).Q46900643
Interaction of nitric oxide with tetrathiolato iron(II) complexes: relevance to the reaction pathways of iron nitrosyls in sulfur-rich biological coordination environmentsQ46989784
The Preparation, Structural Characteristics, and Physical Chemical Properties of Metal-Nitrosyl Complexes.Q49338890
Infrared spectroscopy provides insight into the role of dioxygen in the nitrosylation pathway of a [2Fe2S] cluster iron-sulfur protein.Q50463899
Insight into the dinuclear {Fe(NO)2}10{Fe(NO)2}10 and mononuclear {Fe(NO)2}10 dinitrosyliron complexes.Q50515469
Peptide-bound dinitrosyliron complexes (DNICs) and neutral/reduced-form Roussin's red esters (RREs/rRREs): understanding nitrosylation of [Fe-S] clusters leading to the formation of DNICs and RREs using a de novo design strategy.Q50525814
Anionic mixed thiolate-sulfide-bridged Roussin's red esters [(NO)2Fe(mu-SR)(mu-S)Fe(NO)2]- (R = Et, Me, Ph): a key intermediate for transformation of dinitrosyl iron complexes (DNICs) to [2Fe-2S] clusters.Q50599076
The water-soluble Roussin's red ester acting as a potential photochemical NO-delivery agent: photolysis reactions, DNA cleavage and anticancer activity.Q50601045
Anionic Roussin's red esters (RREs) syn-/anti-[Fe(mu-SEt)(NO)2]2(-): the critical role of thiolate ligands in regulating the transformation of RREs into dinitrosyl iron complexes and the anionic RREs.Q50647226
Reactivity pathways for nitric oxide and nitrosonium with iron complexes in biologically relevant sulfur coordination spheres.Q50688666
Dinitrosyl iron complexes (DNICs) containing S/N/O ligation: transformation of Roussin's red ester into the neutral {Fe(NO)2}10 DNICs.Q50698157
Mononitrosyl tris(thiolate) iron complex [Fe(NO)(SPh)3]- and dinitrosyl iron complex [(EtS)2Fe(NO)2]-: formation pathway of dinitrosyl iron complexes (DNICs) from nitrosylation of biomimetic rubredoxin [Fe(SR)4]2-/1- (R = Ph, Et).Q50718922
Neutral {Fe(NO)2}9 dinitrosyliron complex (DNIC) [(SC6H4-o-NHCOPh)(Im)Fe(NO)2] (Im = imidazole): interconversion among the anionic/neutral {Fe(NO)2}9 DNICs and Roussin's red ester.Q50725168
Activation and cleavage of the N-O bond in dinuclear mixed-metal nitrosyl systems and comparative analysis of carbon monoxide, dinitrogen, and nitric oxide activation.Q53420091
The effects of nitric oxide on electron transport complexes.Q54586652
Structural, Spectroscopic, and Computational Study of an Octahedral, Non-Heme {Fe−NO}6-8Series: [Fe(NO)(cyclam-ac)]2+/+/0Q57900108
Structural and Spectroscopic Features of Mixed Valent FeIIFeI Complexes and Factors Related to the Rotated Configuration of Diiron HydrogenaseQ59618726
Nitric oxide in biological denitrification: Fe/Cu metalloenzyme and metal complex NO(x) redox chemistryQ34593764
Iron-sulfur proteins are the major source of protein-bound dinitrosyl iron complexes formed in Escherichia coli cells under nitric oxide stress.Q34958579
Mechanistic insight into the nitrosylation of the [4Fe-4S] cluster of WhiB-like proteinsQ35051820
Iron regulatory protein 1 outcompetes iron regulatory protein 2 in regulating cellular iron homeostasis in response to nitric oxideQ35067691
Iron(III) bound by hydrosulfide anion ligands: NO-promoted stabilization of the [Fe(III)-SH] motifQ35185237
Self-assembly of dinitrosyl iron units into imidazolate-edge-bridged molecular squares: characterization including Mössbauer spectroscopyQ35621553
Vibrational analysis of mononitrosyl complexes in hemerythrin and flavodiiron proteins: relevance to detoxifying NO reductase.Q35911051
The basics about nitric oxideQ36049486
Nitrosyl derivatives of diiron(I) dithiolates mimic the structure and Lewis acidity of the [FeFe]-hydrogenase active site.Q36952611
Direct nitric oxide signal transduction via nitrosylation of iron-sulfur centers in the SoxR transcription activatorQ36964785
Nitric oxide-induced bacteriostasis and modification of iron-sulphur proteins in Escherichia coliQ37143232
Antimicrobial activity of the iron-sulfur nitroso compound Roussin's black salt [Fe4S3(NO)7] on the hyperthermophilic archaeon Pyrococcus furiosusQ37145138
New nitrosyl derivatives of diiron dithiolates related to the active site of the [FeFe]-hydrogenases.Q37329226
Neutral and reduced Roussin's red salt ester [Fe(2)(mu-RS)(2)(NO)(4)] (R = n-Pr, t-Bu, 6-methyl-2-pyridyl and 4,6-dimethyl-2-pyrimidyl): synthesis, X-ray crystal structures, spectroscopic, electrochemical and density functional theoretical investigaQ37386979
Dinitrosyl iron complexes with thiolate ligands: physico-chemistry, biochemistry and physiologyQ37444346
EPR demonstration of iron-nitrosyl complex formation by cytotoxic activated macrophagesQ37691488
Electronic structure of heme-nitrosyls and its significance for nitric oxide reactivity, sensing, transport, and toxicity in biological systemsQ37776256
Nitric oxide: a guardian for vascular grafts?Q37887771
Generation, translocation, and action of nitric oxide in living systems.Q37950597
Bacterial iron-sulfur regulatory proteins as biological sensor-switchesQ37975225
Iron-sulfur clusters as biological sensors: the chemistry of reactions with molecular oxygen and nitric oxideQ38254959
NO-dependent phototoxicity of Roussin's black salt against cancer cells.Q40572368
Evidence for mutagenesis by nitric oxide during nitrate metabolism in Escherichia coliQ42089149
Synthesis, structures, and properties of group 9- and group 10-group 6 heterodinuclear nitrosyl complexesQ42163827
Evidence for N-acetylcysteine-sensitive nitric oxide storage as dinitrosyl-iron complexes in lipopolysaccharide-treated rat aortaQ42251794
Photon pharmacology of an iron-sulphur cluster nitrosyl compound acting on smooth muscleQ42368798
Binuclear [2Fe-2S] clusters in the Escherichia coli SoxR protein and role of the metal centers in transcriptionQ42681962
A {Fe(NO)3}10 trinitrosyliron complex stabilized by an n-heterocyclic carbene and the cationic and neutral {Fe(NO)2}(9/10) products of its NO releaseQ42881127
Polynuclear water-soluble dinitrosyl iron complexes with cysteine or glutathione ligands: electron paramagnetic resonance and optical studiesQ43017842
Production of 3-nitrosoindole derivatives by Escherichia coli during anaerobic growthQ43071817
Binding of nitric oxide to a synthetic model of iron-containing nitrile hydratase (Fe-NHase) and its photorelease: relevance to photoregulation of Fe-NHase by NO.Q43196521
Formation pathway of Roussin's red ester (RRE) via the reaction of a {Fe(NO)2}(10) dinitrosyliron complex (DNIC) and thiol: facile synthetic route for synthesizing cysteine-containing DNIC.Q43512239
Metallonitrosyl fragment as electron acceptor: intramolecular charge transfer, long range electronic coupling, and electrophilic reactivity in the trans-[NCRu(py)(4)(CN)Ru(py)(4)NO](3+) ion.Q43941399
Toward development of water soluble dye derivatized nitrosyl compounds for photochemical delivery of NO.Q44012826
A structure-based analysis of the vibrational spectra of nitrosyl ligands in transition-metal coordination complexes and clustersQ44055596
Effect of axial ligands on the spectroscopic and electrochemical properties of diruthenium compounds.Q44577211
Mechanism of p21Ras S-nitrosylation and kinetics of nitric oxide-mediated guanine nucleotide exchangeQ44773784
Synthesis and photochemical properties of a novel iron-sulfur-nitrosyl cluster derivatized with the pendant chromophore protoporphyrin IX.Q45033492
Bismercaptoethanediazacyclooctane as a N2S2 chelating agent and Cys-X-Cys mimic for Fe(NO) and Fe(NO)2.Q45038057
A cyclic tetra-nuclear dinitrosyl iron complex [Fe(NO)2(imidazolate)]4: synthesis, structure and stability.Q45227078
Single- and two-photon properties of a dye-derivatized Roussin's red salt ester (Fe2(mu-RS)2(NO)4) with a large TPA cross section.Q46015510
Photochemical production of nitric oxide via two-photon excitation with NIR lightQ46072687
P433issuePt 2
P304page(s)678-700
P577publication date2015-04-16
P1433published inCoordination Chemistry ReviewsQ2996636
P1476titleRecent Advances in Multinuclear Metal Nitrosyl Complexes
P478volume306

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cites work (P2860)
Q52562406A cobalt-nitrosyl complex with a hindered hydrotris(pyrazolyl)borate coligand: detailed electronic structure, and reactivity towards dioxygen.
Q53050184Redox-Sensing Iron-Sulfur Cluster Regulators.

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