Capture-Collapse Heterocyclization: 1,3-Diazepanes by C-N Reductive Elimination from Rhodacyclopentanones

scientific article published on 2 September 2016

Capture-Collapse Heterocyclization: 1,3-Diazepanes by C-N Reductive Elimination from Rhodacyclopentanones is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1021/JACS.6B07046
P932PMC publication ID5025829
P698PubMed publication ID27589060

P2093author name stringJohn F Bower
Niall G McCreanor
Steven Stanton
P2860cites workMonanchorin, a bicyclic alkaloid from the sponge Monanchora ungiculataQ44990666
Directing group enhanced carbonylative ring expansions of amino-substituted cyclopropanes: rhodium-catalyzed multicomponent synthesis of N-heterobicyclic enonesQ46222062
Reversible C-C bond activation enables stereocontrol in Rh-catalyzed carbonylative cycloadditions of aminocyclopropanes.Q51022524
Highly enantioselective rhodium(I)-catalyzed activation of enantiotopic cyclobutanone C-C bonds.Q51753574
A facile synthetic route to diazepinone derivatives via ring closing metathesis and its application for human cytidine deaminase inhibitorsQ59709446
Synthesis of seven-membered ring diazepin-2-ones via palladium-catalyzed highly regioselective cyclization of 2-vinylpyrrolidines with aryl isocyanatesQ73313988
Lactone Formation by Rhodium-Catalyzed C-C Bond Cleavage of Cyclobutanone We thank Dr. T. Tanaka (Kyoto University) for GC analysis of H(2), and Dr. M. Miura (Osaka University) for helpful discussions. Support from Monbusho (Grant-in-Aid for ScientiQ74166222
A concise route to structurally diverse DMP 323 analogues via highly functionalized 1,4-diaminesQ78684219
Rhodium-catalyzed carbonylation of spiropentanesQ81394495
Oxidative 1,4-diamination of dienes using simple urea derivativesQ85300143
Highly enantioselective rhodium(I)-catalyzed carbonyl carboacylations initiated by C-C bond activationQ87418718
Discovery of MK-7655, a β-lactamase inhibitor for combination with Primaxin®Q27688915
Rational design of potent, bioavailable, nonpeptide cyclic ureas as HIV protease inhibitorsQ27731528
1,3-Diazepanes of natural product-like complexity from cyanamide-induced rearrangement of epoxy-delta-lactamsQ33520303
Recent advances in multicomponent reactions for diversity-oriented synthesisQ33555742
Recent advances in the Biginelli dihydropyrimidine synthesis. New tricks from an old dog.Q34109524
Biomimetic diversity-oriented synthesis of benzannulated medium rings via ring expansionQ34480335
Synthesis and applications of rhodacyclopentanones derived from C-C bond activationQ38888292
Cooperative activation of cyclobutanones and olefins leads to bridged ring systems by a catalytic [4 + 2] couplingQ42064818
Modular Access to Substituted Azocanes via a Rhodium-Catalyzed Cycloaddition-Fragmentation StrategyQ42360419
(4+1) vs (4+2): Catalytic Intramolecular Coupling between Cyclobutanones and Trisubstituted Allenes via C-C ActivationQ42753331
Catalytic carbonylation of functionalized diamines: application to the core structure of DMP 323 and DMP 450.Q44314547
P433issue36
P407language of work or nameEnglishQ1860
P304page(s)11465-11468
P577publication date2016-09-02
P1433published inJournal of the American Chemical SocietyQ898902
P1476titleCapture-Collapse Heterocyclization: 1,3-Diazepanes by C-N Reductive Elimination from Rhodacyclopentanones
P478volume138

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cites work (P2860)
Q48156580B(C6 F5 )3 -Catalyzed Ring Opening and Isomerization of Unactivated Cyclopropanes.
Q47979095Mechanism and Origins of the Chemo- and Regioselectivities in Nickel-Catalyzed Intermolecular Cycloadditions of Benzocyclobutenones with 1,3-Dienes
Q49817093Modular Access to Azepines by Directed Carbonylative C-C Bond Activation of Aminocyclopropanes
Q41524161New Initiation Modes for Directed Carbonylative C-C Bond Activation: Rhodium-Catalyzed (3 + 1 + 2) Cycloadditions of Aminomethylcyclopropanes.

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