High-Valent NiIII and NiIV Species Relevant to C-C and C-Heteroatom Cross-Coupling Reactions: State of the Art

scientific article published on 04 March 2020

High-Valent NiIII and NiIV Species Relevant to C-C and C-Heteroatom Cross-Coupling Reactions: State of the Art is …
instance of (P31):
review articleQ7318358
scholarly articleQ13442814

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P356DOI10.3390/MOLECULES25051141
P698PubMed publication ID32143336

P50authorNoel NebraQ79566486
P2860cites workσ-Noninnocence: Masked Phenyl-Cation Transfer at Formal NiIVQ92807085
Accessing Pincer Bis(carbene) Ni(IV) Complexes from Ni(II) via Halogen and Halogen SurrogatesQ46573740
A terminal Ni(III)-imide with diverse reactivity pathwaysQ46642274
Accessing perfluoroalkyl nickel(II), (III), and (IV) complexes bearing a readily attached [C4F8] ligand.Q46715131
Aromatic Methoxylation and Hydroxylation by Organometallic High-Valent Nickel ComplexesQ46718092
Organometallic nickel(III) complexes relevant to cross-coupling and carbon-heteroatom bond formation reactions.Q46908328
Aliphatic C(sp3)-H Bond Activation Using Nickel Catalysis: Mechanistic Insights on Regioselective ArylationQ47326422
Nickel(II)-Catalyzed Site-Selective C-H Bond Trifluoromethylation of Arylamine in Water through a Coordinating Activation Strategy.Q47610681
Carbon-Fluorine Reductive Elimination from Nickel(III) Complexes.Q48158564
Computational Study of Ni-Catalyzed C-H Functionalization: Factors That Control the Competition of Oxidative Addition and Radical PathwaysQ48196528
Phenyltrimethylammonium Salts as Methylation Reagents in the Nickel-Catalyzed Methylation of C-H BondsQ48251858
Oxidatively Induced C-H Activation at High Valent NickelQ48254500
A General Strategy for the Nickel-Catalyzed C-H Alkylation of Anilines.Q50885994
A Bis(µ-oxido)dinickel(III) Complex with a Triplet Ground State.Q52310084
The mechanism of directed Ni(ii)-catalyzed C-H iodination with molecular iodine.Q52575991
Oxidatively-induced aromatic cyanation mediated by Ni(iii).Q52886070
Spectroscopic capture and reactivity of S = 1/2 nickel(III)-oxygen intermediates in the reaction of a Ni(II)-salt with mCPBA.Q52889274
A Ni(iii) complex stabilized by silica nanoparticles as an efficient nanoheterogeneous catalyst for oxidative C-H fluoroalkylation.Q53006986
Recent advances in homogeneous nickel catalysisQ26994718
Fluorine in pharmaceuticals: looking beyond intuitionQ27648640
Catalysis for fluorination and trifluoromethylationQ27687352
Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO2Q28073303
Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel PrizeQ29542886
Bimetallic Reductive Elimination from Dinuclear Pd(III) ComplexesQ34139243
A fluoride-derived electrophilic late-stage fluorination reagent for PET imaging.Q34230071
Carbon-carbon cross-coupling reactions catalyzed by a two-coordinate nickel(II)-bis(amido) complex via observable Ni(I) , Ni(II) , and Ni(III) intermediatesQ34300860
Dual catalysis. Merging photoredox with nickel catalysis: coupling of α-carboxyl sp³-carbons with aryl halidesQ34423208
Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.Q34460497
Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexesQ34466914
A stable tetraalkyl complex of nickel(IV).Q34884701
Transition-metal-catalyzed direct arylation of (hetero)arenes by C-H bond cleavage.Q35016847
A Transmetalation Reaction Enables the Synthesis of [18F]5-Fluorouracil from [18F]Fluoride for Human PET ImagingQ36793355
Introduction of fluorine and fluorine-containing functional groups.Q38123135
Metal-catalyzed activation of ethers via C-O bond cleavage: a new strategy for molecular diversity.Q38243353
Mild metal-catalyzed C-H activation: examples and concepts.Q38806799
Transition metal-catalyzed site- and regio-divergent C-H bond functionalization.Q39326114
Bimetallic redox synergy in oxidative palladium catalysisQ39693368
Dual catalysis. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysisQ39874049
Bimetallic C-C Bond-Forming Reductive Elimination from NickelQ39896456
Mechanism of C-F reductive elimination from palladium(IV) fluoridesQ39973971
Reactivity of a Nickel(II) Bis(amidate) Complex with meta-Chloroperbenzoic Acid: Formation of a Potent Oxidizing SpeciesQ40603825
Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido ComplexQ40994541
Nickel-mediated oxidative fluorination for PET with aqueous [18F] fluorideQ41282938
Highly Regioselective Indoline Synthesis under Nickel/Photoredox Dual CatalysisQ41679346
Oxidation of a cyclometalated Pd(II) dimer with "CF3+": formation and reactivity of a catalytically competent monomeric Pd(IV) aquo complexQ41964675
Synthesis and reactivity of a mono-sigma-aryl palladium(IV) fluoride complexQ42557757
Switching on elusive organometallic mechanisms with photoredox catalysisQ42737431
Mechanism of Electrophilic Fluorination with Pd(IV): Fluoride Capture and Subsequent Oxidative Fluoride Transfer(.)Q42779563
Mononuclear Ni(III)-alkyl complexes (alkyl = Me and Et): relevance to the acetyl-CoA synthase and methyl-CoM reductaseQ43009740
Interactions of aziridines with nickel complexes: oxidative-addition and reductive-elimination reactions that break and make C-N bondsQ43922796
A structurally rigid bis(amido) ligand framework in low-coordinate Ni(I), Ni(II), and Ni(III) analogues provides access to a Ni(III) methyl complex via oxidative additionQ44742033
C-H Bond Trifluoromethylation of Arenes Enabled by a Robust, High-Valent Nickel(IV) ComplexQ46319851
Trifluoromethylation of a Well-Defined Square-Planar Aryl-NiII Complex involving NiIII /CF3. and NiIV -CF3 Intermediate Species.Q46339336
Binuclear, High-Valent Nickel Complexes: Ni-Ni Bonds in Aryl-Halogen Bond FormationQ46418248
Oxidative C-C Bond Formation Reactivity of Organometallic Ni(II), Ni(III), and Ni(IV) ComplexesQ46442806
Mononuclear nickel(III) complexes [Ni(III)(OR)(P(C6H3-3-SiMe3-2-S)3)](-) (R = Me, Ph) containing the terminal alkoxide ligand: relevance to the nickel site of oxidized-form [NiFe] hydrogenasesQ46450753
Isolated Organometallic Nickel(III) and Nickel(IV) Complexes Relevant to Carbon-Carbon Bond Formation ReactionsQ46493066
Rapid Hydrogen and Oxygen Atom Transfer by a High-Valent Nickel-Oxygen SpeciesQ46493171
Aromatic Cyanoalkylation through Double C-H Activation Mediated by Ni(III).Q46557068
Nickel-catalyzed direct arylation of C(sp3)-H bonds in aliphatic amides via bidentate-chelation assistance.Q53646695
Nickel-Alkyl Complexes with a Reactive PNC-Pincer Ligand.Q55395822
Oxidation of Ni(II) to Ni(IV) with Aryl Electrophiles Enables Ni-Mediated Aryl–CF3 CouplingQ57943990
Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond CleavageQ57944258
Palladium-Catalyzed Fluorination of Carbon−Hydrogen BondsQ57944590
Nickel-Catalyzed Electrooxidative C-H Amination: Support for Nickel(IV)Q58087176
A Five-Coordinate Nickel(II) Fluoroalkyl Complex as a Precursor to a Spectroscopically Detectable Ni(III) SpeciesQ61966504
Nickamine and Analogous Nickel Pincer Catalysts for Cross-Coupling of Alkyl Halides and Hydrosilylation of AlkenesQ63973327
The "Dendritic Effect" in Homogeneous Catalysis with Carbosilane-Supported Arylnickel(II) Catalysts: Observation of Active-Site Proximity Effects in Atom-Transfer Radical AdditionQ73388803
A pseudotetrahedral, high-oxidation-state organonickel compound: synthesis and structure of bromotris(1-norbornyl)nickel(IV)Q73545065
Green chemistry: science and politics of changeQ74572605
Mononuclear Ni(III) complexes [NiIII(L)(P(C6H3-3-SiMe3-2-S)3)]0/1- (L = thiolate, selenolate, CH2CN, Cl, PPh3): relevance to the nickel site of [NiFe] hydrogenasesQ79437159
New pincer-type diphosphinito (POCOP) complexes of NiII and NiIIIQ79801375
Reaction of [2-(SiH3)C6H4]2SiH2 with Ni(Et2PCH2CH2PEt2)(PEt3)2: characterization of eta2-(Si-H)Ni and NiIV-H complexesQ80259745
Fluorine in medicinal chemistryQ80497522
Carbon-fluorine reductive elimination from a high-valent palladium fluorideQ81615269
Redox-controlled, reversible rearrangement of a tris(2-pyridylthio)methyl ligand on nickel to an isomer with an “N,S-confused” 2-pyridylthiolate armQ82050021
Unexpected formation of a molecular tetraalkyl nickel complex from an olefin/nickel(0) systemQ83082066
Aromatic trifluoromethylation with metal complexesQ83762957
Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formationQ83890537
Shuttling of nickel oxidation states in N4S2 coordination geometry versus donor strength of tridentate N2S donor ligandsQ84496945
Organonickel(IV) chemistry: a new catalyst?Q85271083
Stable bis(trifluoromethyl)nickel(III) complexesQ86552748
Organometallic Chemistry. Catalysis by nickel in its high oxidation stateQ86917500
Ligand effects on the properties of Ni(iii) complexes: aerobically-induced aromatic cyanation at room temperatureQ87730302
Carbon-Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) ComplexesQ88966902
N-N Bond Forming Reductive Elimination via a Mixed-Valent Nickel(II)-Nickel(III) IntermediateQ89367560
Aerobic C-C and C-O bond formation reactions mediated by high-valent nickel speciesQ89940874
Catalytically Relevant Intermediates in the Ni-Catalyzed C(sp2)-H and C(sp3)-H Functionalization of Aminoquinoline SubstratesQ90743548
Nickela-electrocatalyzed C-H Alkoxylation with Secondary Alcohols: Oxidation-Induced Reductive Elimination at Nickel(III)Q91293436
Nickel(II/IV) Manifold Enables Room-Temperature C(sp3)-H FunctionalizationQ91461007
Impact of Oxidation State on Reactivity and Selectivity Differences between Nickel(III) and Nickel(IV) Alkyl ComplexesQ91730365
C-O and C-N Functionalization of Cationic, NCN-Type Pincer Complexes of Trivalent Nickel: Mechanism, Selectivity, and Kinetic Isotope EffectQ92031746
Connecting Organometallic Ni(III) and Ni(IV): Reactions of Carbon-Centered Radicals with High-Valent Organonickel ComplexesQ92340651
Nickel(IV)-Catalyzed C-H Trifluoromethylation of (Hetero)arenesQ92400116
Aryl-Fluoride Bond-Forming Reductive Elimination from Nickel(IV) CentersQ92592118
P275copyright licenseCreative Commons Attribution 4.0 InternationalQ20007257
P6216copyright statuscopyrightedQ50423863
P433issue5
P577publication date2020-03-04
P1433published inMoleculesQ151332
P1476titleHigh-Valent NiIII and NiIV Species Relevant to C-C and C-Heteroatom Cross-Coupling Reactions: State of the Art
P478volume25