Active template rotaxane synthesis through the Ni-catalyzed cross-coupling of alkylzinc reagents with redox-active esters

scientific article published on 19 June 2019

Active template rotaxane synthesis through the Ni-catalyzed cross-coupling of alkylzinc reagents with redox-active esters is …
instance of (P31):
scholarly articleQ13442814

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P356DOI10.1039/C9SC02457C
P932PMC publication ID6686731
P698PubMed publication ID31588296

P50authorDavid LeighQ15120121
Daniel J TetlowQ64018304
Adrian HaertschQ90534581
P2093author name stringVanesa Marcos
Malcolm A Y Gall
Javier Echavarren
P2860cites workRecent advances in homogeneous nickel catalysisQ26994718
A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagentsQ28834226
Chemical consequences of mechanical bonding in catenanes and rotaxanes: isomerism, modification, catalysis and molecular machines for synthesisQ29040277
Macrocycle Size Matters: “Small” Functionalized Rotaxanes in Excellent Yield Using the CuAAC Active Template ApproachQ29040928
Sequence-specific peptide synthesis by an artificial small-molecule machineQ34322067
Practical Ni-Catalyzed Aryl-Alkyl Cross-Coupling of Secondary Redox-Active Esters.Q34511919
Catalytic "active-metal" template synthesis of [2]rotaxanes, [3]rotaxanes, and molecular shuttles, and some observations on the mechanism of the cu(i)-catalyzed azide-alkyne 1,3-cycloaddition.Q34685306
Redox-Active Esters in Fe-Catalyzed C-C CouplingQ37243448
Active metal template synthesis of rotaxanes, catenanes and molecular shuttlesQ37545389
Strategies and tactics for the metal-directed synthesis of rotaxanes, knots, catenanes, and higher order linksQ37934797
Polyyne Rotaxanes: Stabilization by EncapsulationQ38688197
Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistryQ39241610
Metal ions in the synthesis of interlocked molecules and materials.Q39266551
Formation of C(sp(3) )-C(sp(3) ) Bonds through Nickel-Catalyzed Decarboxylative Olefin Hydroalkylation ReactionsQ40378618
Synthesis of triazolium-based mono- and tris-branched [1]rotaxanes using a molecular transporter of dibenzo-24-crown-8Q40964583
Nickel-Catalyzed Cross-Coupling of Redox-Active Esters with Boronic Acids.Q41828474
Decarboxylative alkenylation.Q42336176
Active-Metal Template Synthesis of a Halogen-Bonding Rotaxane for Anion RecognitionQ42542945
Active metal template synthesis of [2]catenanesQ43266482
Metallaphotoredox-catalysed sp(3)-sp(3) cross-coupling of carboxylic acids with alkyl halides.Q45966319
Organometallic nickel(III) complexes relevant to cross-coupling and carbon-heteroatom bond formation reactions.Q46908328
Catalytic "click" rotaxanes: a substoichiometric metal-template pathway to mechanically interlocked architecturesQ46944301
Sequence-Specific β-Peptide Synthesis by a Rotaxane-Based Molecular MachineQ47199367
Transition-Metal-Free, Visible-Light-Enabled Decarboxylative Borylation of Aryl N-Hydroxyphthalimide EstersQ48131372
Decarboxylative Alkynylation.Q48245463
[2]Rotaxane Formation by Transition State StabilizationQ48265862
Photoinduced decarboxylative borylation of carboxylic acids.Q48270528
Decarboxylative borylationQ48276344
Active metal template synthesis of a neutral indolocarbazole-containing [2]rotaxane host system for selective oxoanion recognitionQ48798879
Iterative Synthesis of Oligo[n]rotaxanes in Excellent YieldQ49015146
A strategy utilizing a recyclable macrocycle transporter for the efficient synthesis of a triazolium-based [2]rotaxane.Q51075938
An artificial molecular machine that builds an asymmetric catalyst.Q52333965
Efficient Multicomponent Active Template Synthesis of Catenanes.Q55012058
Divergent Synthesis of Pyrone Diterpenes via Radical Cross Coupling.Q55360957
Active-Metal Template Synthesis of a Molecular Trefoil KnotQ55883368
Spontaneous Assembly of Rotaxanes from a Primary Amine, Crown Ether and ElectrophileQ57384118
Goldberg Active Template Synthesis of a [2]Rotaxane Ligand for Asymmetric Transition-Metal CatalysisQ57384128
En Route to a Molecular Sheaf: Active Metal Template Synthesis of a [3]Rotaxane with Two Axles Threaded through One RingQ57384147
An Unusual Nickel−Copper-Mediated Alkyne Homocoupling Reaction for the Active-Template Synthesis of [2]RotaxanesQ57384153
Active Template Synthesis of Rotaxanes and Molecular Shuttles with Switchable Dynamics by Four-Component PdII-Promoted Michael AdditionsQ57384178
Cadiot–Chodkiewicz Active Template Synthesis of Rotaxanes and Switchable Molecular Shuttles with Weak Intercomponent InteractionsQ57384184
A Catalytic Palladium Active-Metal Template Pathway to [2]RotaxanesQ57384189
[2]Rotaxanes through Palladium Active-Template Oxidative Heck Cross-CouplingsQ57384203
Controlled Submolecular Translational Motion in Synthesis: A Mechanically Interlocking AuxiliaryQ57384226
CuAAC “click” active-template synthesis of functionalised [2]rotaxanes using small exo-substituted macrocycles: how small is too small?Q58242803
Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical SwitchingQ58732552
Building C(sp)-rich complexity by combining cycloaddition and C-C cross-coupling reactionsQ59064328
Stereoselective Synthesis of Mechanically Planar Chiral RotaxanesQ59133076
Triply Threaded [4]RotaxanesQ59767969
Combining coordination chemistry and catalysis to tie a knot by an active-metal template strategyQ83215677
Carbon-Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) ComplexesQ88966902
The Importance of Length and Flexibility of Macrocycle-Containing Molecular Translocators for the Synthesis of Improbable [2]RotaxanesQ89405409
Cu-Catalyzed Decarboxylative BorylationQ90042292
Chemical Consequences of the Mechanical Bond: A Tandem Active Template-Rearrangement ReactionQ90845910
An Auxiliary Approach for the Stereoselective Synthesis of Topologically Chiral CatenanesQ91787509
P275copyright licenseCreative Commons Attribution 3.0 UnportedQ14947546
P6216copyright statuscopyrightedQ50423863
P433issue30
P304page(s)7269-7273
P577publication date2019-06-19
P1433published inChemical ScienceQ2962267
P1476titleActive template rotaxane synthesis through the Ni-catalyzed cross-coupling of alkylzinc reagents with redox-active esters
P478volume10

Reverse relations

Q89582384Weak functional group interactions revealed through metal-free active template rotaxane synthesiscites workP2860

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